Abstract
In this work, for the first time a highly conductive ceramic composite was made by incorporating multi-walled carbon nanotubes (MWCNT) in aluminum (Al)/alumina (Al2O3) matrix by a simple mechanical mixing technique. The different weight percentage (wt%) of MWCNT incorporated with Al/Al2O3 and their role on the electrical and electromagnetic interference shielding effectiveness (EMI SE) of ceramic composites were investigated. The high electrical conductivity of 280 S/m was achieved for MWCNT@Al/Al2O3 composites with 8 wt% MWCNT content which is 280 times higher than MWCNT@Al/Al2O3 composites (1 S/m) with 1 wt% MWCNT. In addition, MWCNT@Al/Al2O3 sample showed a high EMI SE value of 46 dB for the X-band which is capable to block more than 99.9% of incident electromagnetic radiation. The high electrical conductivity and EMI SE properties of MWCNTs embedded ceramic composite system has originated from the homogenous distribution of conducting carbon nanotubes to form a percolated network at low filler loading. This work presents a strategy to develop a conductive ceramic composites for the excellent EMI shielding and electrical properties by a simple mechanical mixing approach.
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References
F. Shahzad, M. Alhabeb, C.B. Hatter, B. Anasori, S.M. Hong, C.M. Koo, Y. Gogotsi, Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353(6304), 1137–1140 (2016)
D.H. Park, Y.K. Lee, S.S. Park, C.S. Lee, S.H. Kim, W.N. Kim, Effects of hybrid fillers on the electrical conductivity and EMI shielding efficiency of polypropylene/conductive filler composites. Macromol. Res. 21(8), 905–910 (2013)
D. Chung, Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39(2), 279–285 (2001)
G.A. Gelves, M.H. Al-Saleh, U. Sundararaj, Highly electrically conductive and high performance EMI shielding nanowire/polymer nanocomposites by miscible mixing and precipitation. J. Mater. Chem. 21(3), 829–836 (2011)
M.H. Al-Saleh, G.A. Gelves, U. Sundararaj, Copper nanowire/polystyrene nanocomposites: lower percolation threshold and higher EMI shielding. Compos. A 42(1), 92–97 (2011)
C. Guo, L. Zhou, J. Lv, Effects of expandable graphite and modified ammonium polyphosphate on the flame-retardant and mechanical properties of wood flour-polypropylene composites. Polym. Polym. Compos. 21(7), 449–456 (2013)
A. Sanmugam, D. Vikraman, K. Karuppasamy, J.Y. Lee, H.-S. Kim, Evaluation of the corrosion resistance properties of electroplated chitosan-Zn1−xCuxO composite thin films. Nanomaterials 7(12), 432 (2017)
X. Yin, Y. Xue, L. Zhang, L. Cheng, Dielectric, electromagnetic absorption and interference shielding properties of porous yttria-stabilized zirconia/silicon carbide composites. Ceram. Int. 38(3), 2421–2427 (2012)
R. Chandramohan, V. Dhanasekaran, R. Arumugam, K. Sundaram, J. Thirumalai, T. Mahalingam, Physical properties evaluation of annealed ZnAl2O4 alloy thin films. Digest J. Nanomater. Biostruct. 7(3), 1315–1325 (2012)
Y. Yang, M.C. Gupta, K.L. Dudley, R.W. Lawrence, Novel carbon nanotube–polystyrene foam composites for electromagnetic interference shielding. Nano Lett. 5(11), 2131–2134 (2005)
H.-B. Zhang, Q. Yan, W.-G. Zheng, Z. He, Z.-Z. Yu, Tough graphene–polymer microcellular foams for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 3(3), 918–924 (2011)
Y. Yang, M.C. Gupta, K.L. Dudley, R.W. Lawrence, Conductive carbon nanofiber–polymer foam structures. Adv. Mater. 17(16), 1999–2003 (2005)
C. Xiang, Y. Pan, J. Guo, Electromagnetic interference shielding effectiveness of multiwalled carbon nanotube reinforced fused silica composites. Ceram. Int. 33(7), 1293–1297 (2007)
W.-L. Song, M.-S. Cao, B. Wen, Z.-L. Hou, J. Cheng, J. Yuan, Synthesis of zinc oxide particles coated multiwalled carbon nanotubes: dielectric properties, electromagnetic interference shielding and microwave absorption. Mater. Res. Bull. 47(7), 1747–1754 (2012)
M.H. Al-Saleh, U. Sundararaj, Electromagnetic interference shielding mechanisms of CNT/polymer composites. Carbon 47(7), 1738–1746 (2009)
X. Luo, D. Chung, Electromagnetic interference shielding using continuous carbon-fiber carbon-matrix and polymer-matrix composites. Compos. B 30(3), 227–231 (1999)
K. Ahmad, W. Pan, Dramatic effect of multiwalled carbon nanotubes on the electrical properties of alumina based ceramic nanocomposites. Compos. Sci. Technol. 69(7–8), 1016–1021 (2009)
M. Mahmoodi, M. Arjmand, U. Sundararaj, S. Park, The electrical conductivity and electromagnetic interference shielding of injection molded multi-walled carbon nanotube/polystyrene composites. Carbon 50(4), 1455–1464 (2012)
S. Varshney, A. Ohlan, V.K. Jain, V.P. Dutta, S.K. Dhawan, In situ synthesis of polypyrrole-γ-Fe2O3-Fly ash nanocomposites for protection against EMI pollution. Ind. Eng. Chem. Res. 53(37), 14282–14290 (2014)
P. Xu, X. Han, C. Wang, H. Zhao, J. Wang, X. Wang, B. Zhang, Synthesis of electromagnetic functionalized barium ferrite nanoparticles embedded in polypyrrole. J. Phys. Chem. B 112(10), 2775–2781 (2008)
L. Liu, Z. Yang, C. Deng, Z. Li, M. Abshinova, L. Kong, High frequency properties of composite membrane with in-plane aligned Sendust flake prepared by infiltration method. J. Magn. Magn. Mater. 324(10), 1786–1790 (2012)
J. Liang, Y. Wang, Y. Huang, Y. Ma, Z. Liu, J. Cai, C. Zhang, H. Gao, Y. Chen, Electromagnetic interference shielding of graphene/epoxy composites. Carbon 47(3), 922–925 (2009)
M.-S. Cao, X.-X. Wang, W.-Q. Cao, J. Yuan, Ultrathin graphene: electrical properties and highly efficient electromagnetic interference shielding. J. Mater. Chem. C 3(26), 6589–6599 (2015)
N. Abbas, H.T. Kim, Multi-walled carbon nanotube/polyethersulfone nanocomposites for enhanced electrical conductivity, dielectric properties and efficient electromagnetic interference shielding at low thickness. Macromol. Res. 24(12), 1084–1090 (2016)
R. Kumar Srivastava, T. Narayanan, A. Reena Mary, M. Anantharaman, A. Srivastava, R. Vajtai, P.M. Ajayan, Ni filled flexible multi-walled carbon nanotube–polystyrene composite films as efficient microwave absorbers. Appl. Phys. Lett. 99(11), 113116 (2011)
S. Bi, X. Su, G. Hou, C. Liu, W.-L. Song, M.-S. Cao, Electrical conductivity and microwave absorption of shortened multi-walled carbon nanotube/alumina ceramic composites. Ceram. Int. 39(5), 5979–5983 (2013)
C. Xiang, Y. Pan, X. Liu, X. Sun, X. Shi, J. Guo, Microwave attenuation of multiwalled carbon nanotube-fused silica composites. Appl. Phys. Lett. 87(12), 123103 (2005)
K. Ahmad, W. Pan, S.-L. Shi, Electrical conductivity and dielectric properties of multiwalled carbon nanotube and alumina composites. Appl. Phys. Lett. 89(13), 133122 (2006)
A. Saib, L. Bednarz, R. Daussin, C. Bailly, X. Lou, J.-M. Thomassin, C. Pagnoulle, C. Detrembleur, R. Jérôme, I. Huynen, Carbon nanotube composites for broadband microwave absorbing materials. IEEE Trans. Microw. Theory Tech. 54(6), 2745–2754 (2006)
D.-X. Yan, P.-G. Ren, H. Pang, Q. Fu, M.-B. Yang, Z.-M. Li, Efficient electromagnetic interference shielding of lightweight graphene/polystyrene composite. J. Mater. Chem. 22(36), 18772–18774 (2012)
C. von Klemperer, G. Langdon, D. Maharaj, D. Shivute, Metallic filler powders to improve the electromagnetic shielding of FRP laminates, in Proceedings of 17th International Conference on Composite Materials (ICCM-17), (Edinburgh, 2009)
H. Hsu, J. Chen, T. Yang, Improvement of electromagnetic interference shielding for anodized aluminum by layered metallic coatings. Ferroelectrics 435(1), 69–77 (2012)
W.A. Curtin, B.W. Sheldon, CNT-reinforced ceramics and metals. Mater. Today 7(11), 44–49 (2004)
D. Vikraman, K. Karuppasamy, S. Hussain, A. Kathalingam, A. Sanmugam, J. Jung, H.S. Kim, One-pot facile methodology to synthesize MoS2-graphene hybrid nanocomposites for supercapacitors with improved electrochemical capacitance. Compos. B 161, 555–563 (2019). https://doi.org/10.1016/j.compositesb.2018.12.143
X. Xu, Y. Ge, M. Wang, Z. Zhang, P. Dong, R. Baines, M. Ye, J. Shen, Cobalt-doped FeSe2-RGO as highly active and stable electrocatalysts for hydrogen evolution reactions. ACS Appl. Mater. Interfaces 8(28), 18036–18042 (2016)
F. Shahzad, S.H. Lee, S.M. Hong, C.M. Koo, Segregated reduced graphene oxide polymer composite as a high performance electromagnetic interference shield. Res. Chem. Intermed. (2018). https://doi.org/10.1007/s11164-018-3274-7
X. Liu, X. Yin, L. Kong, Q. Li, Y. Liu, W. Duan, L. Zhang, L. Cheng, Fabrication and electromagnetic interference shielding effectiveness of carbon nanotube reinforced carbon fiber/pyrolytic carbon composites. Carbon 68, 501–510 (2014)
M.H. Al-Saleh, W.H. Saadeh, U. Sundararaj, EMI shielding effectiveness of carbon based nanostructured polymeric materials: a comparative study. Carbon 60, 146–156 (2013)
K. Nasouri, A.M. Shoushtari, M.R.M. Mojtahedi, Theoretical and experimental studies on EMI shielding mechanisms of multi-walled carbon nanotubes reinforced high performance composite nanofibers. J. Polym. Res. 23(4), 71 (2016)
K. Nasouri, A.M. Shoushtari, Effects of diameter and surface area of electrospun nanocomposite fibers on electromagnetic interference shielding. Polym. Sci. A 59(5), 718–725 (2017)
S.-L. Shi, J. Liang, The effect of multi-wall carbon nanotubes on electromagnetic interference shielding of ceramic composites. Nanotechnology 19(25), 255707 (2008)
H. Kim, K. Kim, C. Lee, J. Joo, S. Cho, H. Yoon, D. Pejaković, J.-W. Yoo, A. Epstein, Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst. Appl. Phys. Lett. 84(4), 589–591 (2004)
J. Wang, C. Xiang, Q. Liu, Y. Pan, J. Guo, Ordered mesoporous carbon/fused silica composites. Adv. Funct. Mater. 18(19), 2995–3002 (2008)
P. Verma, P. Saini, V. Choudhary, Designing of carbon nanotube/polymer composites using melt recirculation approach: effect of aspect ratio on mechanical, electrical and EMI shielding response. Mater. Des. 88, 269–277 (2015)
A.P. Singh, B.K. Gupta, M. Mishra, A. Chandra, R. Mathur, S. Dhawan, Multiwalled carbon nanotube/cement composites with exceptional electromagnetic interference shielding properties. Carbon 56, 86–96 (2013)
Acknowledgements
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2017R1C1B5076952). Dr. Faisal Shahzad is also thankful for financial support of HEC under SRGP project 2182.
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Ul Hassan, R., Shahzad, F., Abbas, N. et al. Ceramic based multi walled carbon nanotubes composites for highly efficient electromagnetic interference shielding. J Mater Sci: Mater Electron 30, 13381–13388 (2019). https://doi.org/10.1007/s10854-019-01705-2
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DOI: https://doi.org/10.1007/s10854-019-01705-2