Abstract
A novel alluaudite framework K0.4Na3.6Co(MoO4)3 photocatalyst has been synthesized by a solid-state reaction for degradation of both methylene blue (MB) and green diamine B (GDB) organic pollutants under sunlight. The sample was characterized using X-ray diffraction (XRD), transmission electron microscope, infrared spectroscopy and Raman spectroscopy, as well as by means of photoluminescence probing, impedance spectroscopy and UV–vis–NIR spectrophotometry. The XRD analysis reveals that such alluaudite type structure crystallizes in the monoclinic system with space group C2/c. Emissions of this material have been observed in a visible region at 290 nm excitation with a broad long-wave luminescence band from oxygen vacancies. UV–vis absorption spectrum measurements showed an efficient optical absorption in UV–vis region with a direct band gap of 3.37 eV. The complex impedance spectra suggested that the ac conductivity is a power law (Aωs) derived by the correlated barrier hopping conduction mechanism. The efficiency of the dyes removal in the presence of K0.4Na3.6Co(MoO4)3 particles reaches 83% for MB and 53% for GDB under sunlight irradiation. The current studies establish interesting possibilities for investigating catalytic cycles of these solar light activated photocatalysts.
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N.I. Sorokin, Phys. Solid State 51(6), 1128–1130 (2009)
M. Chakir, A.E. Jazouli, D. Waal, Mater. Res. Bull. 38, 1773–1779 (2003)
J.A. Ibers, G.W. Smith, Acta Crystallogr. 17, 190–197 (1964)
H. Bensaid, A. El Bouari, S. Benmokhtar, B. Manoun, L. Bih, P. Lazor, J. Mol. Struct. 1031, 152–159 (2013)
W. Paragassu, A.G. Souza Filho, M. Maczka, P.T.C. Freire, F.E.A. Melo, J. Mendes Filho, J. Hanuza, J. Phys. Condens. Matter 16, 5151–5161 (2004)
A.P.A. Marques, V.M. Longo, D.M.A. De Melo, P.S. Pizani, E.R. Leite, J.A. Varela, E. Lango, J. Solid State Chem. 181, 1249–1257 (2008)
R. Nasri, N. Fakhar Bourguiba, M.F. Zid, Acta Crystallogr. E 71, 4–7 (2015)
R. Nasri, N. Fakhar Bourguiba, M.F. Zid, A. Driss, Acta Crystallogr. E70, i47–i48 (2014)
A.A. Savina, S.F. Solodovnikov, D.A. Belov, O.M. Basovich, Z.A. Solodovnikova, K.V. Pokholok, S.Y. Stefanovich, B.I. Lazoryak, E.G. Khaikina, J. Solid State Chem. 220, 217–220 (2014)
J. Gao, P. Zhao, K. Feng, Chem. Mater. 29(3), 940–944 (2017)
A.A. Savina, S.F. Solodovnikov, D.A. Belov, Z.A. Solodovnikova, S.Yu. Stefanovich, B.I. Lazoryak, E.G. Khaikina, N. J. Chem. 41, 5450–5457 (2017)
Y. Lua, L. Chen, Y. Huang, C. Chen, S. Kim, H.J. Seo, Appl. Surf. Sci. 331, 72–78 (2015)
K. Eddahaoui, G. Mele, S. Benmokhtar, I. Pio, A. Scarlino, R. Essehli, M.A. Deyab, Int. J. Adv. Res. Chem. Sci. 2, 21–32 (2015)
T.T. Basiev, A.A. Sobol, P.G. Zverev, L.I. Ivleva, V.V. Osiko, R.C. Powell, Opt. Mater. 11, 307–314 (1999)
J. Hanuza, L. Macalik, K. Hermanowicz, J. Mol. Struct. 319, 17–30 (1994)
H. Hu, I.E. Wachs, S.R. Bare, J. Phys. Chem. 99, 10897–10910 (1995)
V. Jeseentharani, B. Jeyaraj, A. Dayalan, K.S. Nagaraja, J. Mater. Sci. Mater. Electron. 28, 3548–3559 (2017)
A.P. de Moura, L.H. de Oliveira, P.F.S. Pereira, I.L.V. Rosa, M.S. Li, E. Longo, J.A. Varela, Adv. Chem. Eng. Sci. 2, 465–473 (2012)
T. Thongtem, A. Phuruangrat, S. Thongtem, J. Nanopart. Res. 12, 2287–2294 (2010)
K. Hermanowicz, M. Maczka, M. Wolcyrz, P.E. Tomaszewski, M. Pasciak, J. Hanuza, J. Solid State Chem. 179, 685–695 (2006)
N.M. Rasdi, Y.W. Fen, R.S. Azis, N.A.S. Omar, Optik 149, 409–415 (2017)
S.J. Xiao, X.J. Zhao, P.P. Hu, Z.J. Chu, C.Z. Huang, L. Zhang, ACS Appl. Mater. Interfaces 8(12), 8184–8191 (2016)
L.Z. Liu, J.Q. Xu, X.L. Wu, T.H. Li, J.C. Shen, P.K. Chu, Appl. Phys. Lett. 102, 031916–031919 (2013)
F.H. Bo, Y.S. Yan, Z.P. Feng, W.H. Yuan, L.X. Lin, J.C. Mei, Z.Q. Sheng, C.Y. Hai, W.Z. Guo, Chin. Phys. Lett. 24(7), 2108–2111 (2007)
D. Madhan, M. Parthibavarman, P. Rajkumar, M. Sangeetha, J. Mater. Sci. Mater. Electron. 26, 6823–6830 (2015)
B. Sreedhar, Ch. Sumalatha, H. Yamada, K. Kojima, J. Noncryst. Solids 203, 172–175 (1996)
J. Singh, J. Mater. Sci. Mater. Electron. 14, 171–186 (2003)
R. Nasri, T. Larbi, M. Amlouk, M.F. Zid, J. Mater. Sci. Mater. Electron. 29, 18372–18379 (2018)
J. Liu, R. Wei, J. Hu, L. Li, J. Li, J. Alloys Compd 580, 475–480 (2013)
Z.Q. Li, X.T. Chen, Z.I. Xue, Sci. China Chem. 56, 443–450 (2013)
J. Bi, L. Wu, Y. Zhang, Z. Li, J. Li, X. Fu, Appl. Catal. B 91, 135–143 (2009)
J.V. Kumar, Sci. Rep. 6, 34149–34160 (2016)
K. Nakamura, K. Shimokita, Y. Sakamoto, H. Hirano, Y. Michihiro, T. Moriga, Solid State Ion. 225, 538–541 (2012)
Y. Ben Taher, A. Oueslati, N.K. Maaloul, K. Khirouni, M. Gargouri, Appl. Phys. A. 120, 1537–1543 (2015)
Y.S. Song, N.I. Cho, M.H. Lee, B.Y. Kim, D.Y. Lee, J. Nanosci. Nanotechnol. 16, 1831–1833 (2016)
M.N. Zulfiqar Ahmed, K.B. Chandrasekhar, A.A. Jahagirdar, H. Nagabhushana, B.M. Nagabhushana, Appl. Nanosci. 5, 961–968 (2015)
T. Larbi, M.A. Amara, B. Ouni, M. Amlouk, Mater. Res. Bull. 95, 152–156 (2017)
H. Jie, M. Jie, M. Jiahua, H. Hao, J. Rare Earths 32, 1126–1134 (2014)
A. Sahmi, K. Bensadok, M. Trari, J. Photochem. Photobiol. A 349, 36–41 (2017)
Mol. Phys. (2019). https://doi.org/10.1080/00268976.2019.1567854
T. Larbi, L. Ben Said, A. Ben Daly, B. Ouni, A. Labidi, M. Amlouk, J. Alloys Compd 686, 168–175 (2016)
R. Singh, M. Kumar, H. Khajuria, L. Tashi, H.N. Sheikh, J. Chin. Chem. Soc. (2018). https://doi.org/10.1002/jccs.201800317
T. Larbi, K. Doll, M. Amlouk, Spectrochim. Acta A. 216, 117–124 (2019)
M. Kumar, R. Singh, H. Khajuria, H.N. Sheikh, J. Mater. Sci. Mater. Electron. 28, 9423–9434 (2017)
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Nasri, R., Larbi, T., Amlouk, M. et al. Highly efficient K0.4Na3.6Co(MoO4)3 new alluaudite type structure for photocatalytic degradation of methylene blue and green diamine B dyes. J Mater Sci: Mater Electron 30, 9642–9651 (2019). https://doi.org/10.1007/s10854-019-01298-w
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DOI: https://doi.org/10.1007/s10854-019-01298-w