Abstract
Dangling bond defects (DBs) in silicon-passivated (1- or 3-nm thick Si cap) strained-(100)Si1−xGex (x = 0.25–0.55) layers at interfaces with 1.8-nm thick HfO2 gate dielectric are studied by means of Electron Spin Resonance (ESR) spectroscopy. The results suggest a dominant contribution of Si DBs (Pb0 centers), a considerable fraction of which is located at the interface between the Si substrate crystal and the pseudomorphic Si1−xGex film. The density of Si DBs in the Ge containing samples is significantly lower than at the reference (100)Si/ HfO2 interface and decreases below the ESR detection limit (≈ 0.8 × 1011cm−2) with increasing thickness and Ge concentration in the Si1−xGex layer. However, the beneficial effect of Ge becomes less pronounced when the thickness of the Si cap is reduced to 1 nm or in the case of direct deposition of HfO2 on top of uncapped Si1−xGex. From these observations we conclude that DBs are eliminated due to in-diffusion of Ge from the Si1−xGex channel into interfacial Si layers, bringing the concentration of Ge to the range in which generation of Si DBs becomes energetically unfavourable, in agreement with previous observations on condensation-grown Si1−xGex layers.
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Madia, O., Kepa, J., Afanas’ev, V.V. et al. Dangling bond defects in silicon-passivated strained-Si1−xGex channel layers. J Mater Sci: Mater Electron 31, 75–79 (2020). https://doi.org/10.1007/s10854-019-01098-2
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DOI: https://doi.org/10.1007/s10854-019-01098-2