Abstract
Ga-doped ZnO (GZO) thin films with different Ga contents (1, 2, 4, 3, and 5 at.%) were successfully deposited on glass substrates using a spin-coating process. The temperature dependent electrical conductivity and room-temperature Hall effect measurements were performed for the films. The variation of electrical conductivity with Ga content was well explained by considering the change in the inelastic diffusion length of electrons. The critical value of carrier concentration for the metal–insulator transition was estimated as 1.77 × 1018 cm−3 for GZO. The critical value of Ga content, where Ga as a donor source becomes ineffective, on the order of 5.25 at.% was obtained.
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A. Yildiz, S. Uzun, N. Serin, T. Serin, Influence of grain boundaries on the figure of merit of undoped, Al, In, and Sn doped ZnO thin films for photovoltaic applications. Scr. Mater. 113, 23–25 (2016)
T.-W. Kang, S.H. Kim, C.H. Kim, S.-M. Lee, H.-K. Kim, J.S. Park, J.H. Lee, Y.S. Yang, S.-J. Lee, Flexible polymer/metal/polymer and polymer/metal/inorganic trilayer transparent conducting thin film heaters with highly hydrophobic surface. ACS Appl. Mater. Interfaces 9, 33129–33136 (2017)
H. Cheng, H. Deng, Y. Wang, M. Wei, In fluence of ZnO buffer layer on the electrical, optical and surface properties of Ga-doped ZnO films. J. Alloys Compd. 705, 598–601 (2017)
A. Yildiz, E. Ozturk, A. Atilgan, M. Sbeta, A. Atli, T. Serin, An understanding of the band gap shrinkage in Sn-doped ZnO for dye-sensitized solar cells. J. Electron. Mater. 46, 6739–6744 (2017)
C.-S. Lee, C.-H. Jeon, B.-T. Lee, S.-H. Jeong, Abrupt conversion of the conductivity and band-gap in the sputter grown Ga-doped ZnO films by a change in growth ambient: effects of oxygen partial pressure. J. Alloys Compd. 742, 977–985 (2018)
R.V.M. Naidu, A. Subrahmanyam, A. Verger, M.K. Jain, S.V.N. Bhaskara Rao, S.N. Jha, D.M. Phase, Electron–electron interactions-based metal-insulator transition in Ga doped ZnO thin films. Electron. Mater. Lett. 8, 457–462 (2012)
J. Mukherjee, B.R.K. Nanda, M.S. Ramachandra Rao, Metal–insulator transition in Ga doped ZnO via controlled thickness. arXiv preprint arXiv:1704.03846 (2017)
S. Brochen, G. Feuillet, J.-L. Santailler, R. Obrecht, M. Lafossas, P. Ferret, J.-M. Chauveau, J. Pernot, Non-metal to metal transition in n-type ZnO single crystal materials. J. Appl. Phys. 121, 095704 (2017)
A.G. Zabrodskii, K.N. Zinoveva, Metallic conductivity near the metal-insulator transition in Cd12xMnxTe. Eksp. Teor. Fiz. 86, 727–742 (1984)
T.G. Castner, N.K. Lee, G.S. Cieloszyk, G.L. Salinger, Dielectric anomaly and the metal-insulator transition in n-type silicon. Phys. Rev. Lett. 34, 1627–1630 (1975)
T. Serin, A. Yildiz, S. Uzun, E. Çam, N. Serin, Electrical conduction properties of In-doped ZnO thin films. Phys. Scr. 84, 065703 (2011)
A.T. Vai, V.L. Kuznetsov, H. Jain, D. Slocombe, N. Rashidi, M. Pepper, P.P. Edwards, The transition to the metallic state in polycrystalline n-type doped ZnO thin films. Anorg. Allg. Chem. 640, 1054–1062 (2014)
J. Hu, R.G. Gordon, Atmospheric pressure chemical vapor deposition of gallium doped zinc oxide thin films from diethyl zinc, water, and triethyl gallium. J. Appl. Phys. 72, 5381 (1992)
M. Kaveh, D.J. Newson, D.B. Zimra, M. Pepper, The smallest length scale near the metal-insulator transition. J. Phys. C 20, L19 (1987)
V. Bhosle, A. Tiwari, J. Narayan, Electrical properties of transparent and conducting Ga doped ZnO. J. Appl. Phys. 100, 033713 (2006)
M. Kaveh, N.F. Mott, The metal–insulator transition in disordered 3d systems: a new view. J. Phys. C 15, L697 (1982)
C. Leighton, I. Terry, P. Becla, Metallic conductivity near the metal–insulator transition in Cd12xMnxTe. Phys. Rev. B 58, 9773–9782 (1998)
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This work was supported by the Ankara Yıldırım Beyazıt University BAP under Project Number 4042.
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Sbeta, M., Serin, T. & Yildiz, A. Determination of the critical carrier concentration for the metal–insulator transition in Ga-doped ZnO. J Mater Sci: Mater Electron 29, 14111–14115 (2018). https://doi.org/10.1007/s10854-018-9543-9
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DOI: https://doi.org/10.1007/s10854-018-9543-9