Abstract
In this experimental work, different conductive polymer nanocomposites were synthesized using polypyrrole as conductive polymer and CoFe2O4, NiFe2O4, CNT and graphene as fillers. X-ray diffraction pattern was used to study the crystallinity of the products and it was found CoFe2O4, NiFe2O4, CNT, and graphene were successfully embedded in the polymer matrix. To further approve the synthesis of the nanocomposites, energy dispersive X-ray spectroscopy was served. Surface groups of the synthesized nanocomposites were studied by Fourier transform infrared and Raman spectroscopy. The morphology of the products was examined by scanning electron microscopy and transmission electron microscopy. It was found the fillers were successfully embedded in the polymer matrix and they were in nanometer scales. To investigate the magnetic properties and conductivity of the polymer nanocomposites, alternating gradient force magnetometer and four-point probe were used, respectively. Finally, the microwave absorption properties of the polymer nanocomposites were studied and it was found the fillers have different effects on the polymer microwave absorption value.
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M. Sabet, M. Salavati-Niasari, M. Ashjari, D. Ghanbari, M. Dadkhah, CuInS2/CuS nanocomposite: synthesis via simple microwave approach and investigation its behavior in solar cell. J. Inorg. Organomet. Polym. Mater. 22(5), 1139–1145 (2012)
M. Sabet, M. Salavati-Niasari, D. Ghanbari, O. Amiri, N. Mir, M. Dadkhah, Synthesis and characterization of CuInSe2 nanocrystals via facile microwave approach and study of their behavior in solar cell. Mater. Sci. Semicond. Process. 25, 98–105 (2014)
M. Sabet, M. Salavati-Niasari, Deposition of lead sulfide nanostructure films on TiO2 surface via different chemical methods due to improving dye-sensitized solar cells efficiency. Electrochim. Acta 169, 168–179 (2015)
C. Wang, R. Lv, Z. Huang, F. Kang, J. Gu, Synthesis and microwave absorbing properties of FeCo alloy particles/graphite nanoflake composites. J. Alloys Compd. 509(2), 494–498 (2011)
F. Tabatabaie, M. Fathi, A. Saatchi, A. Ghasemi, Effect of Mn–Co and Co–Ti substituted ions on doped strontium ferrites microwave absorption. J. Alloys Compd. 474(1), 206–209 (2009)
X. Dong, X. Zhang, H. Huang, F. Zuo, Enhanced microwave absorption in Ni/polyaniline nanocomposites by dual dielectric relaxations. Appl. Phys. Lett. 92(1), 013127 (2008)
P. Jana, A. Mallick, S. De, Effects of sample thickness and fiber aspect ratio on EMI shielding effectiveness of carbon fiber filled polychloroprene composites in the X-band frequency range. IEEE Trans. Electromagn. Compat. 34(4), 478–481 (1992)
M. Soloman, P. Kurian, M. Anantharaman, P. Joy, Evaluation of the magnetic and mechanical properties of rubber ferrite composites containing strontium ferrite. Polym.-Plast. Technol. Eng. 43(4), 1013–1028 (2004)
J. Jin, J. Song, S. Deng, G. Li, Synthesis and microwave absorbing characteristics of flake-like polypyrrole filled composites in X-band. Polym. Compos. 37(2), 532–538 (2016)
C. Zhang, Q. Li, Y. Ye, Preparation and characterization of polypyrrole/nano-SrFe12O19 composites by in situ polymerization method. Synth. Met. 159(11), 1008–1013 (2009)
H. Yang, W. Jiang, Y. Lu, Fabrication and characteristic of conductive and ferromagnetic hollow composite microcapsules. Mater. Lett. 61(13), 2789–2793 (2007)
K. Suri, S. Annapoorni, A. Sarkar, R. Tandon, Gas and humidity sensors based on iron oxide–polypyrrole nanocomposites. Sens. Actuators B 81(2), 277–282 (2002)
L. Geng, S. Wang, Y. Zhao, P. Li, S. Zhang, W. Huang, S. Wu, Study of the primary sensitivity of polypyrrole/r–Fe2O3 to toxic gases. Mater. Chem. Phys. 99(1), 15–19 (2006)
L. Flandin, Y. Brechet, J.-Y. Cavaille, Electrically conductive polymer nanocomposites as deformation sensors. Compos. Sci. Technol. 61(6), 895–901 (2001)
Ö Yavuz, M.K. Ram, M. Aldissi, P. Poddar, H. Srikanth, Polypyrrole composites for shielding applications. Synth. Met. 151(3), 211–217 (2005)
M. Mallouki, F. Tran-Van, C. Sarrazin, P. Simon, B. Daffos, A. De, C. Chevrot, J.-F. Fauvarque, Polypyrrole–Fe2O3 nanohybrid materials for electrochemical storage. J. Solid State Electrochem. 11(3), 398–406 (2007)
Y. Yu, C. Ouyang, Y. Gao, Z. Si, W. Chen, Z. Wang, G. Xue, Synthesis and characterization of carbon nanotube/polypyrrole core–shell nanocomposites via in situ inverse microemulsion. J. Polym. Sci. A: 43(23), 6105–6115 (2005)
C.-W. Kwon, A. Poquet, S. Mornet, G. Campet, J. Portier, J.-H. Choy, A new polypyrrole/maghemite hybrid as a lithium insertion electrode. Electrochem. Commun. 4(2), 197–200 (2002)
G.S. Prakash, P. Suresh, F. Viva, G.A. Olah, Novel single step electrochemical route to γ-MnO2 nanoparticle-coated polyaniline nanofibers: thermal stability and formic acid oxidation on the resulting nanocomposites. J. Power Sources 181(1), 79–84 (2008)
Y. Fang, X. Tang, X. Sun, Y. Zhang, J. Zhao, L. Yu, Y. Liu, X. Zhao, Preparation and enhanced microwave absorption properties of Ni–Co attached single-walled carbon nanotubes and CoFe2O4 nanocomposites. J. Appl. Phys. 121(22), 224301 (2017)
I. Gul, A. Maqsood, Structural, magnetic and electrical properties of cobalt ferrites prepared by the sol–gel route. J. Alloys Compd. 465(1), 227–231 (2008)
X. Wang, H. Yan, R. Xue, S. Qi, A polypyrrole/CoFe2O4/hollow glass microspheres three-layer sandwich structure microwave absorbing material with wide absorbing bandwidth and strong absorbing capacity. J. Mater. Sci.: Mater. Electron. 28(1), 519–525 (2017)
K.R. Reddy, W. Park, B.C. Sin, J. Noh, Y. Lee, Synthesis of electrically conductive and superparamagnetic monodispersed iron oxide-conjugated polymer composite nanoparticles by in situ chemical oxidative polymerization. J. Colloid Interface Sci. 335(1), 34–39 (2009)
K.R. Reddy, K.-P. Lee, Y. Lee, A.I. Gopalan, Facile synthesis of conducting polymer–metal hybrid nanocomposite by in situ chemical oxidative polymerization with negatively charged metal nanoparticles. Mater. Lett. 62(12), 1815–1818 (2008)
I. Radja, H. Djelad, E. Morallon, A. Benyoucef, Characterization and electrochemical properties of conducting nanocomposites synthesized from p-anisidine and aniline with titanium carbide by chemical oxidative method. Synth. Met. 202, 25–32 (2015)
S.H. Hosseini, S. Mohseni, A. Asadnia, H. Kerdari, Synthesis and microwave absorbing properties of polyaniline/MnFe2O4 nanocomposite. J. Alloys Compd. 509(14), 4682–4687 (2011)
P. Xu, X. Han, C. Wang, H. Zhao, J. Wang, X. Wang, B. Zhang, Synthesis of electromagnetic functionalized barium ferrite nanoparticles embedded in polypyrrole. J. Phys. Chem. B 112(10), 2775–2781 (2008)
Y. Li, G. Chen, Q. Li, G. Qiu, X. Liu, Facile synthesis, magnetic and microwave absorption properties of Fe3O4/polypyrrole core/shell nanocomposite. J. Alloys Compd. 509(10), 4104–4107 (2011)
J. Jiang, L.-H. Ai, J.-L. Zheng, Preparation and characterization of polypyrrole/ferrospinel nanocomposite by w/o microemulsion pathway. J. Macromol. Sci. B 49(4), 652–657 (2010)
M. Hassan, K.R. Reddy, E. Haque, S.N. Faisal, S. Ghasemi, A.I. Minett, V.G. Gomes, Hierarchical assembly of graphene/polyaniline nanostructures to synthesize free-standing supercapacitor electrode. Compos. Sci. Technol. 98, 1–8 (2014)
K.R. Reddy, K.-P. Lee, A.I. Gopalan, Self-assembly directed synthesis of poly(ortho-toluidine)–metal (gold and palladium) composite nanospheres. J. Nanosci. Nanotechnol. 7(9), 3117–3125 (2007)
Y. Min, K. Zhang, L. Chen, Y. Chen, Y. Zhang, Sonochemical assisted synthesis of a novel TiO2/graphene composite for solar energy conversion. Synth. Met. 162(9), 827–833 (2012)
Y.P. Zhang, S.H. Lee, K.R. Reddy, A.I. Gopalan, K.P. Lee, Synthesis and characterization of core–shell SiO2 nanoparticles/poly(3-aminophenylboronic acid) composites. J. Appl. Polym. Sci. 104(4), 2743–2750 (2007)
Z. Li, M. Ye, A. Han, H. Du, Preparation, characterization and microwave absorption properties of NiFe2O4 and its composites with conductive polymer. J. Mater. Sci.: Mater. Electron. 27(1), 1031–1043 (2016)
A. Saib, L. Bednarz, R. Daussin, C. Bailly, X. Lou, J.-M. Thomassin, C. Pagnoulle, C. Detrembleur, R. Jérôme, I. Huynen, Carbon nanotube composites for broadband microwave absorbing materials. IEEE Trans. Microwave Theory Tech. 54(6), 2745–2754 (2006)
Y. Chen, Y. Li, M. Yip, N. Tai, Electromagnetic interference shielding efficiency of polyaniline composites filled with graphene decorated with metallic nanoparticles. Compos. Sci. Technol. 80, 80–86 (2013)
D. Sun, Q. Zou, G. Qian, C. Sun, W. Jiang, F. Li, Controlled synthesis of porous Fe3O4-decorated graphene with extraordinary electromagnetic wave absorption properties. Acta Mater. 61(15), 5829–5834 (2013)
Y. Chen, Z. Lei, H. Wu, C. Zhu, P. Gao, Q. Ouyang, L.-H. Qi, W. Qin, Electromagnetic absorption properties of graphene/Fe nanocomposites. Mater. Res. Bull. 48(9), 3362–3366 (2013)
R. Che, L.M. Peng, X.F. Duan, Q. Chen, X. Liang, Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Adv. Mater. 16(5), 401–405 (2004)
M. Zong, Y. Huang, H. Wu, Y. Zhao, P. Liu, L. Wang, Facile preparation of RGO/Cu2O/Cu composite and its excellent microwave absorption properties. Mater. Lett. 109, 112–115 (2013)
Y. Chen, Q. Wang, C. Zhu, P. Gao, Q. Ouyang, T. Wang, Y. Ma, C. Sun, Graphene/porous cobalt nanocomposite and its noticeable electrochemical hydrogen storage ability at room temperature. J. Mater. Chem. 22(13), 5924–5927 (2012)
P. Liu, Y. Huang, L. Wang, M. Zong, W. Zhang, Hydrothermal synthesis of reduced graphene oxide–Co3O4 composites and the excellent microwave electromagnetic properties. Mater. Lett. 107, 166–169 (2013)
P. Liu, Y. Huang, X. Zhang, Superparamagnetic Fe3O4 nanoparticles on graphene–polyaniline: synthesis, characterization and their excellent electromagnetic absorption properties. J. Alloys Compd. 596, 25–31 (2014)
E.A. Sanches, S.F. Alves, J.C. Soares, A.M.d.. Silva, C.G.d.. Silva, S.M.d.. Souza, H.O.d. Frota, Nanostructured polypyrrole powder: a structural and morphological characterization. J. Nanomater. 16(1), 301 (2015)
H.C. Kang, K. Geckeler, Enhanced electrical conductivity of polypyrrole prepared by chemical oxidative polymerization: effect of the preparation technique and polymer additive. Polymer 41(18), 6931–6934 (2000)
Y.-C. Liu, B.-J. Hwang, Identification of oxidized polypyrrole on Raman spectrum. Synth. Met. 113(1), 203–207 (2000)
T.-M. Wu, Y.-W. Lin, C.-S. Liao, Preparation and characterization of polyaniline/multi-walled carbon nanotube composites. Carbon 43(4), 734–740 (2005)
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Sabet, M., Jahangiri, H. & Ghashghaei, E. Synthesis of carbon nanotube, graphene, CoFe2O4, and NiFe2O4 polypyrrole nanocomposites and study their microwave absorption. J Mater Sci: Mater Electron 29, 10853–10863 (2018). https://doi.org/10.1007/s10854-018-9156-3
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DOI: https://doi.org/10.1007/s10854-018-9156-3