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Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage

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Abstract

We report on the synthesis and electrochemical characterization of nanohybrid polypyrrole (PPy) (PPy/Fe2O3) materials for electrochemical storage applications. We have shown that the incorporation of nanoparticles inside the PPy notably increases the charge storage capability in comparison to the “pure” conducting polymer. Incorporation of large anions, i.e., paratoluenesulfonate, allows a further improvement in the capacity. These charge storage modifications have been attributed to the morphology of the composite in which the particle sizes and the specific surface area are modified with the incorporation of nanoparticles. High capacity and stability have been obtained in PC/NEt4BF4 (at 20 mV/s), i.e., 47 mAh/g, with only a 3% charge loss after one thousand cyles. The kinetics of charge–discharge is also improved by the hybrid nanocomposite morphology modifications, which increase the rate of insertion–expulsion of counter anions in the bulk of the film. A room temperature ionic liquid such as imidazolium trifluoromethanesulfonimide seems to be a promising electrolyte because it further increases the capacity up to 53 mAh/g with a high stability during charge–discharge processes.

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Acknowledgements

The authors would like to thank the Agence de l‘Environnement et de la Maîtrise de l’Energie for its financial support and P. Porte (research engineer) from Villetaneuse university for the BET measurements.

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Authors and Affiliations

  1. Laboratoire de Physicochimie des Polymères et des Interfaces, LPPI, EA 2528 Université de Cergy-Pontoise 5, mail Gay-Lussac, 95031, Cergy-Pontoise Cedex, France

    M. Mallouki, F. Tran-Van, C. Sarrazin & C. Chevrot

  2. Laboratoire d’Electrochimie Industrielle, CNAM, 75003, Paris, France

    J. F. Fauvarque

  3. Université Paul Sabatier, CIRIMAT-LCMIE, UMR 5085, 118 route de Narbonne, 31062, Toulouse, France

    P. Simon & B. Daffos

  4. Saha Institute of Nuclear Physics, 1/AF, Bidhannagar, Calcutta, 700064, India

    A. De

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  1. M. Mallouki
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  2. F. Tran-Van
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  3. C. Sarrazin
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  4. P. Simon
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  5. B. Daffos
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  6. A. De
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  7. C. Chevrot
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  8. J. F. Fauvarque
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Correspondence to C. Chevrot.

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Mallouki, M., Tran-Van, F., Sarrazin, C. et al. Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage. J Solid State Electrochem 11, 398–406 (2007). https://doi.org/10.1007/s10008-006-0161-8

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  • DOI: https://doi.org/10.1007/s10008-006-0161-8

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