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Multi-dimensional CuO nanorods supported CoMoO4 nanosheets heterostructure as binder free and high stable electrode for supercapacitor

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Abstract

A two-step synthetic method is developed for the preparation of ternary CoMoO4/CuO heterostructure on Cu foam as binder-free and high-performance supercapacitor electrode. The synthesis approach involves a simple chemical bath deposition and hydrothermal reaction. CuO nanorods are obtained on Cu foam with chemical bath deposition, and CoMoO4 nanosheets are subsequently grown on as-prepared CuO nanorods to form multi-dimensional CoMoO4/CuO heterostructure by the hydrothermal procedure. The in situ grown CoMoO4/CuO heterostructure could be used as a binder-free supercapacitor electrode. The CoMoO4/CuO heterostructure delivers a significant specific capacitance of 1176 F g−1 under the scan rate of 1 mV s−1, which is distinctly higher than that of the bare CoMoO4 electrode. The galvanostatic charge and discharge tests reveal the CoMoO4/CuO heterostructure electrode has excellent cycle stability, maintaining 95.1% capacitance retention under 2.5 A g−1 after 5000 cycles. These superior performances could be original from the unique multi-dimensional CoMoO4/CuO heterostructure which provides more active sites and additional electron transport channels. These results have promoted the potential implementation of multi-dimensional heterostructure for advanced electrochemical capacitors.

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Acknowledgements

This work was partially funded by the Education Department of Hubei Province, and the National Natural Science Foundation of China Grant 11504436 & 11704418.

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Authors and Affiliations

  1. School of Electronic and Electrical Engineering, Wuhan Textile University, Wuhan, 430200, People’s Republic of China

    Feng Liu, Yanqin Yang, Songzhan Li & Min Liu

  2. School of Physics and Technology, Wuhan University, Wuhan, 430072, People’s Republic of China

    Songzhan Li & Tian Chen

  3. School of Electronics and Information Engineering, South-Central University for Nationalities, Wuhan, 430074, People’s Republic of China

    Hao Long & Haoning Wang

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  1. Feng Liu
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  2. Yanqin Yang
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  3. Songzhan Li
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  4. Tian Chen
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  7. Min Liu
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Correspondence to Yanqin Yang or Songzhan Li.

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Liu, F., Yang, Y., Li, S. et al. Multi-dimensional CuO nanorods supported CoMoO4 nanosheets heterostructure as binder free and high stable electrode for supercapacitor. J Mater Sci: Mater Electron 29, 10353–10361 (2018). https://doi.org/10.1007/s10854-018-9092-2

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