Abstract
The cadmium sulfide (CdS) quantum dots (QDs) were deposited on the commercial (Degussa-P25) TiO2 nanostructures by successive ionic layer adsorption and reaction (SILAR) method. Three types of films were prepared with CdS 9, 12 and 15 cycles. The PXRD, UV–Vis–NIR absorption and J–V measurements were taken for the CdS QDs deposited for 9, 12 and 15 cycles and the results were compared. The CdS sensitized electrode prepared using 12 cycles of SILAR produces an efficiency of 1.45% on using a liquid (I−/I3−) electrolyte and platinum counter electrode under the illumination of 100 mW/cm2 which shows the best power conversion efficiency compared with CdS 9 and 15 cycles respectively. Total charge collection efficiency was increased upto 12 deposition cycles and it started to decrease beyond 12 cycles. This might be due to the changes in the photo adsorption behavior of CdS QD as a function of deposition cycles.
Similar content being viewed by others
References
B. O’Regan, M. Gratzel, Nature 353, 737 (1991)
J.M. Luther, M.C. Beard, Q. Song, M. Law, R.J. Ellingson, A.J. Nozik, Nano Lett. 7, 1779 (2007)
M.C. Beard, J. Phys. Chem. Lett. 2, 1282 (2011)
Y. Yang, W. Rodríguez-Co, T. Rdoba, Lian, Nano Lett. 12, 4235 (2012)
L. Wei, F. Li, S. Hu, H. Li, B. Chi, J. Pu, L. Jian, J. Am. Ceram. Soc. 98, 3173 (2015)
T. Toyoda, Q. Shen, J. Phys. Chem. Lett. 3, 1885 (2012)
K. Fan, M. Liu, T. Peng, L. Ma, K. Dai, Renew. Energy 35, 555–561 (2010)
S.K. Dhungel, J.G. Park, Renew. Energy 35, 2776–2780 (2010)
M. Atif, W.A. Farooq, A. Fatehmulla, M. Aslam, S. Mansoor Ali, Materials 8, 355–367 (2015)
H. Choi, P.V. Kamat, J. Phys. Chem. Lett. 4, 3983 (2013)
Y. Hu, B. Wang, J. Zhang, T. Wang, R. Liu, J. Zhang, X. Wang, H. Wang, Nanoscale Res. Lett. 8, 1 (2013)
J. Yang, L. Pan, G. Zhu, X. Liu, H. Sun, Z. Sun, J. Electroanal. Chem. 677, 101 (2012)
R. Zhou, Q. Zhang, J. Tian, D. Myers, M. Yin, G. Cao, J. Phys. Chem. Lett. C 117, 26948 (2013)
H. Lee, M. Wang, P. Chen, D.R. Gamelin, S.M. Zakeeruddin, M. Gratzel, Md.K. Nazeeruddin, Nano Lett. 9, 4221 (2009)
X. Song, M. Wang, H. Zhang, J. Deng, Z. Yang, C. Ran, X. Yao, Electrochim. Acta 108, 449 (2013)
K.S. Leschkies, R. Divakar, J. Basu, E. Enache-Pommer, J.E. Boercker, C. Barry Carter, U.R. Kortshagen, D.J. Norris, E.S. Aydil, Nano Lett. 7, 1793 (2007)
E. Talgorn, M.A. de Vries, L.D.A. Siebbeles, A.J. Houtepen, ACS Nano 5, 3552 (2011)
C. Ratanatawanate, C. Xiong, K.J. Balkus, ACS Nano 2, 1682 (2008)
P.R. Brown, R.R. Lunt, N. Zhao, T.P. Osedach, D.D. Wanger, L.-Y. Chang, M.G. Bawendi, V. Bulovi, Nano Lett. 11, 2955 (2011)
N. Guijarro, T. Lana-Villarreal, T. Lutz, S.A. Haque, R. Gómez, J. Phys. Chem. Lett. 3, 3367 (2012)
S. Mostafa Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, S. Afr. J. Chem. 70, 44–48 (2017)
M. Ramezani, A. Sobhani-Nasab, A. Davoodi, J. Mater. Sci.: Mater. Electron. 26, 5440–5445 (2015)
A. Sobhani-Nasab, M. Rangraz-Jeddy, A. Avanes, M. Salavati-Niasari, J. Mater. Sci.: Mater. Electron. 26, 9552–9560 (2015)
M. Salavati-Niasari, F. Soofivand, A. Sobhani-Nasab, M. Shakouri-Arani, A. Yeganeh, S. Faal, Bagheri, Adv. Powder Technol. 27, 2066 (2016)
H.M. Pathan, C.D. Lokhande, Bull. Mater. Sci. 27, 85–111 (2004)
V. Senthamilselvi, K. Saravanakumar, N. Jabena Begum, R. Anandhi, A.T. Ravichandran, B. Sakthivel, K. Ravichandran, J. Mater. Sci.: Mater. Electron. 23, 302 (2012)
G. Zhu, L. Pan, T. Xu, Z. Sun, ACS Appl. Mater. Interfaces 3, 3146 (2011)
Y. Choi, M. Seol, W. Kim, K. Yong, J. Phys. Chem. 118, 5664 (2014)
S. Corer, G. Hodes, J. Phys. Chem. 98, 5338 (1994)
S. Mathews, P.S. Mukerjeeb, K.P. Vijayakumar, Thin Solid Films 254, 278–284 (1995)
K. Ravichandran, P. Philominathan, Appl. Surf. Sci. 255, 5736 (2009)
A. Hartley, S.J.C. Irvine, J. Mater. Sci.: Mater. Electron. 11, 569 (2000)
G. Sasikala, R. Dhanasekaran, C. Subramanian, Thin Solid Films 302, 71–76 (1997)
G.S. Paul, J.H. Kim, M.-S. Kim, K. Do, J. Ko, J.-S. Yu, ACS Appl. Mater. Interfaces 4, 375–381 (2012)
Md.A. Hossain, J.R. Jennings, C. Shen, J.H. Pan, Z.Y. Koh, N. Mathews, Q. Wang, J. Mater. Chem. 22, 16235–16242 (2012)
A. Ranjitha, N. Muthukumarasamy, M. Thambidurai, D. Velauthapillai, R. Balasundaraprabhu, S. Agilan, J. Mater. Sci.: Mater. Electron. 24, 3014–3020 (2013)
A. Ranjitha, N. Muthukumarasamy, M. Thambidurai, D. Velauthapillai, J. Mater. Sci.: Mater. Electron. 25, 2724–2729 (2014)
Acknowledgements
The authors acknowledge the Department of Science and Technology (DST), Govt. of India under research Grant No. DST/TM/SERI/2k12/40(G) for financial support.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Veerathangam, K., Senthil Pandian, M. & Ramasamy, P. Influence of SILAR deposition cycles in CdS quantum dot-sensitized solar cells. J Mater Sci: Mater Electron 29, 7318–7324 (2018). https://doi.org/10.1007/s10854-018-8721-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-8721-0