Skip to main content

Advertisement

SpringerLink
Log in

Dielectric properties of diblock copolymers containing a polyarylene ether nitrile block and a polyarylene ether ketone block

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The block copolymers poly(arylene ether nitrile ketone) (PENK) composed of a poly(arylene ether nitrile)s block and a poly(arylene ether ketone) block were prepared from biphenol, 2,6-dichlorobenzonitrile and 4,4′-difluorobenzophenone (DFBP) by the nucleophilic aromatic substitution reaction. The molecular structure of PENK was characterized by the Fourier transform infrared spectrum (FT-IR) testing. The properties of the PENK polymers were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) characterization, mechanical testing, dielectric and breakdown strength measurement. According to the DSC characterization, only one glass transition temperature (~ 216 °C) of all the polymers is observed and remained even treated at a temperature of 360 °C, indicating that the block polymer PENK has a homogeneous morphology. In addition, PENK polymers exhibit excellent thermal stability and mechanical strength, the thermal decomposition temperature of the polymers ranges from 530 to 535 °C, and the tensile strength of them ranges from 100 to 117 MPa. The energy storage density of PENK films is closely related to the molecular structure of them. The results show that with the increase of DFBP, the energy storage density increases from 0.62 to 1.11 J/cm3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. S. Shen, Z. Pu, P. Zheng, X. Liu, K. Jia, High Perform. Polym. 28, 562 (2016)

    Article  Google Scholar 

  2. F. Meng, Y. Zhao, Y. Zhan, X. Liu, J. Mater. Chem 21, 16385 (2011)

    Article  Google Scholar 

  3. L. Tong, Z. Pu, X. Huang, Z. Chen, X. Yang, X. Liu, J. Appl. Polym. Sci. 130, 1363 (2013)

    Article  Google Scholar 

  4. Y. You, X. Huang, Z. Pu, K. Jia, X. Liu, J. Polym. Res. 22, 211 (2015)

    Article  Google Scholar 

  5. H. Tang, P. Wang, P. Zheng, X. Liu, Compos. Sci. Technol. 123, 134 (2016)

    Article  Google Scholar 

  6. C. Li, X. Liu, Mater. Lett. 61, 2239 (2007)

    Article  Google Scholar 

  7. M. Feng, F. Jin, X. Huang, K. Jia, X. Liu, J. Mater. Sci. 26, 1 (2015)

    Google Scholar 

  8. Y. You, W. Han, L. Tu, Y. Wang, R. Wei, X. Liu, RSC Adv. 7, 29306 (2017)

    Article  Google Scholar 

  9. R. Chen, G. Li, New J. Chem. 40, 3755 (2016)

    Article  Google Scholar 

  10. F. Wang, M. Hickner, Q. Ji, Macromol. Symp. 175, 387 (2001)

    Article  Google Scholar 

  11. F. Meng, F. Huang, Y. Guo, J. Chen, X. Chen, D. Hui, P. He, X. Zhou, Z. Zhou, Composites Part B 117, 165 (2017)

    Article  Google Scholar 

  12. H. Niu, M. Huang, S. Qi et al., Polymer 54, 1700 (2013)

    Article  Google Scholar 

  13. Y. Watanabe, Y. Shibasaki, S. Ando, M. Ueda, Polymer 46, 5903 (2005)

    Article  Google Scholar 

  14. K. Lim, P. Cross, P. Mills, H. Colquhoun, High Perform. Polym. 28, 984 (2016)

    Article  Google Scholar 

  15. H. Zhao, Q. Xi, M. Cai, Polym. Bull. 67, 1139 (2011)

    Article  Google Scholar 

  16. F. Meng, J. Zhong, Y. Chen, X. Liu, J. Appl. Polym. Sci. 120, 1822 (2011)

    Article  Google Scholar 

  17. Y. Xiong, Q. Liu, Q. Zeng, J. Power Sources 193, 541 (2009)

    Article  Google Scholar 

  18. P. Wen, Z. Zhong, L. Li, F. Shen, X. Li, M. Lee, J. Membr. Sci. 463, 58 (2014)

    Article  Google Scholar 

  19. S. Agarwal, S. Kumar, S. Maken, J. Ind. Eng. Chem. 18, 1489 (2012)

    Article  Google Scholar 

  20. L. Liu, G. Wang, Y. Zhang, S. Zhang, High Perform. Polym. 23, 620 (2011)

    Article  Google Scholar 

  21. F. Meng, H. Ishida, X. Liu, RSC Adv. 4, 9471 (2014)

    Article  Google Scholar 

  22. G. Chen, J. Lin, X. Wang, J. Mater. Sci. Mater. Electron. 1 (2017)

  23. L. Wang, Z. Dang, Appl. Phys. Lett. 87, 042903 (2005)

    Article  Google Scholar 

  24. Y. Rao, C.P. Wong, J. Appl. Polym. Sci 92, 2228 (2004)

    Article  Google Scholar 

  25. Z. Dang, Y. Lin, C. Nan, Adv. Mater. 15, 1625 (2003)

    Article  Google Scholar 

  26. R. Wei, K. Li, J. Ma, H. Zhang, X. Liu., J. Mater. Sci. 27, 9565 (2016)

    Google Scholar 

  27. S. Pothukuchi, Y. Li, C.P. Wong, J. Appl. Polym. Sci. 93, 1531 (2004)

    Article  Google Scholar 

  28. H. Tang, X. Huang, X. Yang, J. Yang, R. Zhao, X. Liu, Mater. Lett. 75, 218 (2012)

    Article  Google Scholar 

  29. W. Harrison, F. Wang, J. Mecham., J. Polym. Sci. Part A 41, 2264 (2003)

    Article  Google Scholar 

  30. M. Feng, X. Huang, H. Tang, X. Liu, Colloids Surf. A 441, 556 (2014)

    Article  Google Scholar 

  31. C. Li, A. Tang, Y. Zou, X. Liu, Mater. Lett. 59, 59 (2005)

    Article  Google Scholar 

  32. F. Yao, S. Sheng, J. Jiang, X. Liu, C. Song, J. Fluorine Chem. 144, 176 (2012)

    Article  Google Scholar 

  33. Z. Pu, L. Chen, Y. Long, L. Tong, X. Huang, X. Liu, J. Polym. Res. 20, 281 (2013)

    Article  Google Scholar 

  34. J. Zhong, H. Tang, Y. Chen, X. Liu, J. Mater. Sci. 21, 1244 (2010)

    Google Scholar 

  35. Y. Chen, B. Lin, X. Zhang, J. Mater. Chem. A 2, 14118 (2014)

    Article  Google Scholar 

Download references

Acknowledgements

The authors wish to thank for financial support of this work from the National Natural Science Foundation (Nos. 51373028, 51773028 and 51603029), National Postdoctoral Program for Innovative Talents (Project No. BX201700044) and University of Electronic Science and Technology of China (A03013023601011).

Author information

Authors and Affiliations

  1. Research Branch of Advanced Functional Materials, School of Microelectronic and Solid-State Electronic, Center for Applied Chemistry, University of Electronic Science and Technology of China, Chengdu, 610054, China

    Hua Mao, Yong You, Lifen Tong, Xiaohe Tang, Renbo Wei & Xiaobo Liu

Authors
  1. Hua Mao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yong You
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lifen Tong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaohe Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Renbo Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Xiaobo Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Renbo Wei or Xiaobo Liu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mao, H., You, Y., Tong, L. et al. Dielectric properties of diblock copolymers containing a polyarylene ether nitrile block and a polyarylene ether ketone block. J Mater Sci: Mater Electron 29, 3127–3134 (2018). https://doi.org/10.1007/s10854-017-8245-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-8245-z

Search

Navigation