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Effect of NH4Cl flux used to synthesize double perovskite BaLaMgSbO6:Eu3+ phosphor by solid-state reaction method

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Abstract

Eu3+ ions activated BaLaMgSbO6 phosphors were successfully synthesized by the solid-state reaction method using NH4Cl as the flux. The influence of NH4Cl, structure, morphology and photoluminescent properties of as-prepared powders were investigated in detail. Long-range ordering of B-site cations existed in this double perovskite. With increasing the amount of NH4Cl, the morphology of phosphors changed from regular polyhedron shape to globoid shape. Broad and strong A 1g mode existed in the Raman spectrum. The absorption intensity of charge transfer band was higher than the intensity of characteristic f–f absorption of Eu3+. The luminescence intensity of 5D0–7F2 (electric dipole transition) was much higher than that of 5D0–7F1 (magnetic dipole transition). The optimum adding amount of NH4Cl was 10.0 wt% while excited by the CTB and the phosphor emitted intense red light. The CIE chromaticity coordinates indicated that the phosphors showed good color purity. Therefore the synthesized phosphor is a potential light conversion red material for light emitting diode.

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Acknowledgements

The authors acknowledge the generous financial support from Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and National Natural Science Foundation of China (51402133, 51202111).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 210009, China

    Quan Liu, Xibing Li, Lixi Wang & Qitu Zhang

  2. Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing, 210009, China

    Quan Liu, Xibing Li, Lixi Wang & Qitu Zhang

  3. AVIC Aerospace Life-support Industries, Ltd, Xiangyang, 441003, China

    Qi Zhang & Haibin Jiang

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  1. Quan Liu
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  2. Qi Zhang
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  3. Xibing Li
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Correspondence to Qitu Zhang.

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Liu, Q., Zhang, Q., Li, X. et al. Effect of NH4Cl flux used to synthesize double perovskite BaLaMgSbO6:Eu3+ phosphor by solid-state reaction method. J Mater Sci: Mater Electron 28, 3373–3379 (2017). https://doi.org/10.1007/s10854-016-5931-1

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  • DOI: https://doi.org/10.1007/s10854-016-5931-1

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