Abstract
Aluminoborosilicate glasses with different amounts of La2O3 and Ce2O3 were prepared respectively by the conventional melting-quenching method. The structure, thermal property parameters and dielectric property parameters were investigated by Fourier-Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry and the impedance analyzer. Results from FTIR displayed that the degree of polymerization increased first and then fell down with the addition of La2O3, and reached the maximum value when the amount was 0.5 mol%. Meanwhile, the degree of polymerization of glasses doped with Ce2O3 arrived at the largest as the content of Ce2O3 reached 2.0 mol%. The thermal stability of glasses doped with La2O3 got enhanced first and then deteriorated, and reached the maximum when the content was 0.5 mol%; Meanwhile, the glasses doped with Ce2O3 also fluctuated a little. The dielectric constant (ε) and dielectric loss (tan α) of the samples fell down as the frequency increased. The ε and tan α of the samples doped with La2O3 reached the minimum value when the amount got to 0.5 mol%; The ε of the glasses doped with Ce2O3 turned minimum when the amount was zero, but the tan α was the smallest when the amount reached 1.0 mol%.
Similar content being viewed by others
References
I.J. Choi, S.C. Yong, J. Electroceram. 23, 185 (2009)
S. Kerisit, J.V. Ryan, E.M. Pierce, J. Non-Cryst. Solids 378, 273 (2013)
P. Lin, G. Zhao, Y. Hao, J. Wang, W. Weng, G. Han, J. Chin. Ceram. Soc. 35, 856 (2007)
N. Ollier, T. Charpentier, B. Boizot, G. Wallez, D. Ghaleb, J. Non-Cryst. Solids 341, 26 (2004)
J. Wu, J.F. Stebbins, J. Non-Cryst. Solids 356, 2097 (2010)
X. Zhang, Y. Yue, H. Wu, J. Mater. Sci. Mater. Electron. 24, 2755 (2013)
M. Bengisu, R.K. Brow, E. Yilmaz, S.T. Reis, J. Non-Cryst. Solids 352, 3668 (2006)
J.G. Wood, S. Prabakar, K.T. Mueller, C.G. Pantano, J. Non-Cryst. Solids 349, 276 (2004)
M. Piotrowicz, D. Cianciara XXIst International Congress on Glass (ICG 2007), vol 49 (2011, p. 192)
A. Quintas, O. Majérus, D. Caurant, J.L. Dussossoy, P. Vermaut, J. Am. Ceram. Soc. 90, 712 (2007)
J. Marchi, D.S. Morais, J. Schneider, J.C. Bressiani, A.H.A. Bressiani, J. Non-Cryst. Solids 87, 863 (2005)
D. Caurant, A. Quintas, O. Majérus, T. Charpentier, I. Bardez, Adv. Mater. Res. 39–40, 19 (2008)
S.V. Smiljanić, S.R. Grujić, M.B. Tošić et al., Ceram. Int. 40, 297 (2014)
P. Lu, Y. Zheng, J. Cheng, D. Guo, Ceram. Int. 39, 8207 (2013)
N.S. Rao, L.S. Rao, Y. Gandhi, N. Veeraiah, V. Ravikumar, Phys. B 405, 4092 (2010)
S.M. Lu, X.M. Yuan, X.H. Zhang, Y.J. Cui, H.T. Wu, Y.L. Yue, Adv. Mater. Res. 710, 127 (2013)
X.H. Zhang, Y.L. Yue, H.T. Wu, Surf. Rev. Lett. 19, 1250062 (2012)
Y. Ni, C. Lu, Y. Zhang, Q. Zhang, Z. Xu, J. Rare Earths 25, 94 (2007)
J. Wu, J.F. Stebbins, J. Non-Cryst. Solids 362, 73 (2013)
W. Mozgawa, M. Król, J. Dyczek, J. Deja, Spectrochim. Acta A 132, 889 (2014)
Q. Zheng, M. Potuzak, J.C. Mauro, M.M. Smedskjaer, R.E. Youngman, Y. Yue, J. Non-Cryst. Solids 358, 993 (2012)
N.I. Ya-Ru, L.U. Chun-Hua, Y. Zhang, Q.T. Zhang, X.U. Zhong-Zi, J. Mater. Sci. Eng. 24, 858 (2006)
A. Quintas, O. Majérus, M. Lenoir, D. Caurant, K. Klementiev, A. Webb, J. Non-Cryst. Solids 354, 98 (2008)
E. Malchukova, B. Boizot, G. Petite, D. Ghaleb, J. Non-Cryst. Solids 354, 3592 (2008)
Q. Zheng, M. Potuzak, J.C. Mauro, M.M. Smedskjaer, R.E. Youngman, Y. Yue, J. Non-Cryst. Solids 358, 993 (2012)
A.A. Alemi, H. Sedghi, A.R. Mirmohseni, V. Golsanamlu, Bull. Mater. Sci. 29, 55 (2006)
W. Soppe, C.V.D. Marel, W.F.V. Gunsteren, H.W.D. Hartog, J. Non-Cryst. Solids 103, 201 (1988)
W.W. Wang, Y.L. Yue, H.T. Zhang, Mater. Technol. 28, 370 (2013)
I. Dyamant, E. Korin, J. Hormadaly, J. Non-Cryst. Solids 354, 3135 (2008)
F. He, Q. Zhou, J. Xie, Q. Zhang, Ceram. Int. 41, 3449 (2015)
P.A. Bingham, R.J. Hand, S.D. Forder, Mater. Res. Bull. 41, 1622 (2006)
H.A. Abo-Mosallam, H.C. Park, Mater. Lett. 72, 137 (2012)
A. Arora, K. Singh, O.P. Pandey, Int. J. Hydrogen Energy 36, 14948 (2011)
A. Arora, A. Goel, E.R. Shaaban, K. Singh, O.P. Pandey, J.M.F. Ferreira, Phys. B 403, 1738 (2008)
N.O. Dantas, W.E.F. Ayta, A.C.A. Silva, N.F. Cano, S.W. Silva, P.C. Morais, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 81, 140 (2011)
S. Nakayama, T. Watanabe, T. Asahi, Ceram. Int. 36, 2323 (2010)
B.S. Prakash, K.B.R. Varma, J. Solid State Chem. 180, 1918 (2007)
X. Zhang, Z. Du, H. Wu, Y. Yue, Surf. Rev. Lett. 20, 1350030 (2013)
Acknowledgments
This work is supported by Natural Science Foundation of Shandong Province (No. ZR2012EMM019), Natural Science Foundation (Nos. 51172093, 51042009).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lu, Y., Liu, H., Qu, Y. et al. Influence of La2O3 and Ce2O3 additions on structure and properties of aluminoborosilicate glasses. J Mater Sci: Mater Electron 28, 2716–2722 (2017). https://doi.org/10.1007/s10854-016-5850-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-016-5850-1