Abstract
Lanthanum doped ZnO flower-like structured nanoparticles were synthesized through microwave assisted sol–gel technique. X-ray diffraction, scanning electron microscopy, transmission electron microscopy analysis confirmed the size, structural morphology and successful compound formation of the samples. The band gap was calculated from Tauc’s plot using UV–Vis spectroscopy data. Lanthanum doped ZnO nanoparticles were used for the photocatalytic degradation of methylene blue dye under UV light irradiation. Compared to pure ZnO sample, La-doped samples exhibited higher photocatalytic dye degradation under UV light irradiation with short time duration. Among the different amounts of dopant, 3 mol% La-doped ZnO nano rods showed the highest degradation with short time UV light irradiation (60 min). Other factors such as particle size, morphology and defects also affect the photocatalytic activity. In our study, the main factor that influence photocatalytic activity is the separation of photo induced electron–hole pair due to defects formation in the sample. The 3 mol% sample has the appropriate electron–hole separation due to defects compared to pure ZnO. The influence of defects on the photocatalytic activity of all samples has been revealed using photoluminescence spectroscopy analysis. Furthermore, the effect of various operational parameters such as photocatalyst quantity, dye concentration and dopant concentrations were also optimized.
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H. Gulce, V. Eskizeybek, B. Haspulat, F. Sarl, A. Gulce, A. Avci, Ind. Eng. Chem. Res. 52, 10924 (2013)
K. Tanaka, K. Padermpole, T. Hisanaga, Water Res. 34, 327 (2000)
G.H. Chen, L.C. Lei, P.L. Yue, Ind. Eng. Chem. Res. 38, 1837 (1999)
A. Alinasafi, F. Evenou, E.M. Abdulkarim, M.N. Pons, O. Zahraa, A. Benhammou, A. Yaacoubi, A. Nejmeddine, Dyes Pigm. 74, 439 (2007)
T. Aathi, P. Narahari, G. Madras, J. Hazard. Mater. 149, 725 (2007)
J. Peller, O. Wiest, P.V. Kamat, Environ. Sci. Technol. 37, 1926 (2003)
M. Cristina Yeber, J. Rodriguez, J. Freer, N. Duran, H.D. Mansilla, Chemosphere 41, 1193 (2000)
M. Stylidi, D.I. Kondarides, X.E. Verykios, Appl. Catal. B 40, 271 (2003)
S. Suwanboon, P. Amornpitoksuk, A. Sukolrat, N. Nuensit, Ceram. Int. 39, 2811 (2013)
H. Cao, Y.G. Zhao, S.T. Ho, E.W. Seeling, Q.H. Wang, R.P.H. Chang, Phys. Rev. Lett. 82, 2278 (1999)
A.J. Hoffman, E.R. Carraway, M.R. Hoffmann, Environ. Sci. Technol. 28, 776 (1994)
J. Zhao, L. Wang, X. Yan, Y. Yang, Y. Lei, J. Zhou, Y. Huang, Y. Gu, Y. Zhang, Mater. Res. Bull. 46, 1207 (2011)
J.B. Zhong, J.Z. Li, Y. Lu, X.Y. He, J. Zeng, W. Hu, J.C. Shen, Appl. Surf. Sci. 258, 4929 (2012)
K.T. Ranjit, I. Willner, S.H. Bossmann, A.M. Braun, J. Catal. 204, 305 (2001)
A. Khataee, R.D. CheshmehSoltani, Y. Hanifehpour, M. Safarpour, H. Gholipour Ranjbar, S. Woo Joo, Ind. Eng. Chem. Res. 53, 1924 (2014)
S. Senthilvelan, V.L. Chandraboss, B. Karthikeyan, M. Murugavelu, B. Loganathan, L. Natanapatham, AIP Conf. Proc. 1461, 395 (2012)
K.C. Hsiao, S.C. Liao, Y.J. Chen, Mater. Sci. Eng. A 447, 71 (2007)
T. Jia, W. Wang, F. Long, Z. Fu, H. Wang, Q. Zhang, J. Alloys Compd. 484, 410 (2009)
W. Lu, G. Liu, Sh Gao, Sh Xing, J. Wang, Nanotechnology 19, 44517 (2008)
F. Li, Y. Yuan, J. Luo, Q. Qin, J. Wu, Zh Li, X. Huang, Appl. Surf. Sci. 256, 6076 (2010)
M.J. Height, S.E. Pratisins, O. Mekasuwandmrong, P. Praserthdam, Appl. Catal. B 63, 305 (2006)
P. Zhu, J. Zhang, Z. Wu, Z. Zhang, Cryst. Growth Des. 8, 3148 (2008)
G. Anandha Babu, G. Ravi, M. Navaneethan, M. Arivanandhan, Y. Hayakava, J. Mater. Sci. Mater. Electron. 25, 5231 (2014)
R. Zamiri, A.F. Lemos, A. Reblo, H.A. Ahangar, J.M.F. Ferreira, Ceram. Int. 40, 523 (2014)
K.N. Harish, H.S. Bhojya Naik, P.N. Prashanthkumar, R. Viswanath, ACS Sustain. Chem. Eng. 1, 1143 (2013)
B.D. Cullity, S.R. Stock, Elements of X-Ray Diffraction, 2nd edn. (Prentice Hall, Upper Saddle River, 2001)
R.N. Yogamalar, A. Chandrabose, Appl. Phys. A 103, 33 (2011)
A. George, S.K. Sharma, S. Chawla, N.M. Naik, M.S. Quresi, J. Alloys Compd. 509, 5942 (2011)
A.J. Reddy, M.K. Kokila, H. Nagabhushana, J.L. Rao, C. Shivakumar, B.M. Nagabhushana, R.P.S. Chakrodhar, Spectrochim. Acta A 81, 53 (2011)
P.R. Potti, V.C. Srivastava, Ind. Eng. Chem. Res. 51, 7948 (2012)
M.P. Proenca, C.T. Sousa, A.M. Pereira, P.B. Tavares, J. Ventura, M. Vazquez, J.P. Aravjo, Phys. Chem. Chem. Phys. 13, 9561 (2011)
J. Xie, Y. Li, W. Zhao, L. Bian, Y. Wei, Powder Technol. 207, 140 (2011)
A. Chittofratti, A.E. Matijevic, Colloids Surf. 48, 65 (1990)
J.M. Bishop, C.E. Wilmer, S. Soh, B.A. Grzybowski, Small 14, 1600 (2009)
X. Liu, D.G. Stroppa, M. Heggen, Y. Ermolenko, A. Offenhausser, Y. Mourzina, J. Phys. Chem. C 119, 10336 (2015)
J.I. Panvoke, Optical Process in Semiconductors (Prentice-Hall, New Jersey, 1971)
X. Qiu, L. Li, J. Zheng, J. Liu, X. Sun, G. Li, J. Phys. Chem. C 112, 12242 (2008)
R. Viswanatha, S. Saptra, B. Satpati, P.V. Satyam, B.N. Dev, D.D. Sama, J. Mater. Chem. 14, 661 (2004)
L. Kumerasan, M. Mahalakshmi, M. Palanichamy, V. Murugesan, Ind. Eng. Chem. Res. 49, 1480 (2010)
D.S. Bohole, C.J. Spira, J. Am. Chem. Soc. 131, 4397 (2009)
B. Choudhury, A. Choudhury, Mater. Chem. Phys. 131, 666 (2012)
M.S. Tomar, R. Melgarejo, P.S. Dobal, R.S. Katiyar, J. Mater. Res. 16, 903 (2001)
D. Li, H. Haneda, H. Chemosphere 51, 129 (2003)
Y. Cao, W.S. Yang, Y.M. Chen, H. Du, P. Yue, Appl. Surf. Sci. 236, 223 (2004)
Y. Liu, Z.H. Kang, Z.H. Chen, I. Shafiq, J.A. Zapien, I. Bello, W.J. Zhang, S.T. Lee, Cryst. Growth Res. 9, 3222 (2009)
Priyanka, V.C. Srivastava, Ind. Eng. Chem. Res. 52, 17790 (2013)
M.S. Lucas, J.A. Peres, Dyes Pigm. 71, 236 (2006)
S.K. Pardeshi, A.B. Patil, J. Mol. Catal. A 308, 32 (2009)
T. Zhang, T. Oyama, A. Aoshima, H. Hidaka, J. Zhao, N. Serpone, J. Photochem. Photobiol. A 140, 163 (2001)
Y. Zheng, C. Chen, Y. Zhan, X. Lin, Q. Zhang, K. Wei, S. Zhu, Y. Zhu, Inorg. Chem. 46, 6675 (2007)
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Hemalatha, P., Karthick, S.N., Hemalatha, K.V. et al. La-doped ZnO nanoflower as photocatalyst for methylene blue dye degradation under UV irradiation. J Mater Sci: Mater Electron 27, 2367–2378 (2016). https://doi.org/10.1007/s10854-015-4034-8
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DOI: https://doi.org/10.1007/s10854-015-4034-8