Abstract
In this paper, we report a new approach for deposition of nanocrystalline MoBi2Se5 thin films using vacuum evaporation employing single source precursor synthesized by arrested precipitation technique. As deposited and vacuum annealed MoBi2Se5 thin films were characterized for opto-structural, morphological, compositional and electrochemical analysis. It was observed that optical band gap decreases from 2.07 eV to 1.87 eV with vacuum annealing. X-ray diffraction studies confirm rhombohedral crystal structure of MoBi2Se5 thin films. Scanning electron microscopy images show compact arrangement of spherical grains without pin holes. Transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HRTEM) results reveal nanocrystalline nature having particle size ~100 nm and selected area electron diffraction (SAED) pattern confirms rhombohedral crystal structure. The compositional analysis done by XPS shows presence of Mo4+, Bi3+ and Se2− oxidation states confirming stoichiometric MoBi2Se5 thin film material. The photoelectrochemical (PEC) parameters of as deposited and vacuum annealed thin films were recorded in 0.5 M aqueous polysulfide electrolyte. Our PEC results show that 0.57 and 0.70 % conversion efficiency for as-deposited and vacuum annealed samples respectively.
Similar content being viewed by others
References
V.A. Akhavan, B.W. Goodfellow, M.G. Panthani, C. Steinhagen, T.B. Harvey, C.J. Stolle, B.K. Korgel, Colloidal CIGS and CZTS nanocrystals: a precursor route to printed photovoltaics. J. Solid State Chem. 189, 2–12 (2012)
M. Afzaal, P. O’Brien, Recent developments in II–VI and III–VI semiconductors and their applications in solar cells. J. Mater. Chem. 16, 1597–1602 (2006)
Y.F. Sun, H. Cheng, S. Gao, Q.H. Liu, Z.H. Sun, C. Xiao, C.Z. Wu, S.P. Wei, Y. Xie, Atomically thick bismuth selenide freestanding single layers achieving enhanced thermoelectric energy harvesting. J. Am. Chem. Soc. 134, 20294 (2012)
X. Huang, Z. Zeng, H. Zhang, Metal dichalcogenide nanosheets: preparation, properties and applications. Chem. Soc. Rev. 42, 1934–1946 (2013)
Z. Sun, S. Liufu, R. Liu, X. Chen, A general strategy to bismuth chalcogenide films by chemical vapor transport. J. Mater. Chem. 21, 2351–2355 (2011)
G. Han, Z.G. Chen, D. Ye, L. Yang, L. Wang, J. Drennan, J. Zou, In-doped Bi2Se3 hierarchical nanostructures as anode materials for Li-ion batteries. J. Mater. Chem. A 2, 7109–7116 (2014)
J. Yang, H.S. Shin, Recent advances in layered transition metal dichalcogenides for hydrogen evolution reaction. J. Mater. Chem. A 2, 5979–5985 (2014)
Y. Min, G.D. Moon, C.E. Kim, J.H. Lee, H. Yang, A. Soon, U. Jeong, Solution-based synthesis of anisotropic metal chalcogenide nanocrystals and their applications. J. Mater. Chem. C 2, 6222–6248 (2014)
N.T. Mai, D. Mott, N.T.B. Thuy, I. Ossaka, S. Maenosono, Study on formation mechanism and ligand-directed architectural control of nanoparticles composed of Bi, Sb and Te: towards one-pot synthesis of ternary (Bi, Sb)2Te3 nanobuilding blocks. RSC Adv. 1, 1089–1098 (2011)
R. Harpeness, A. Gedanken, A.M. Weiss, M.A. Slifkin, Microwave-assisted synthesis of nanosized MoSe2. J. Mater. Chem. 13, 2603–2606 (2003)
N.B. Pawar, S.S. Mali, S.D. Kharade, M.G. Gang, P.S. Patil, J.H. Kim, C.K. Hong, P.N. Bhosale, Influence of vacuum annealing on the structural and photoelectrochemical properties of nanocrystalline MoBi2S5 thin films. Curr. Appl. Phys. 14, 508–515 (2014)
P. Christian, P. O’Brien, A general route to nanostructured bismuth chalcogenides. J. Mater. Chem. 15, 3021–3025 (2005)
R.M. Mane, R.R. Kharade, N.S. Patil, P.N. Bhosale, Optical and electrical studies on MoBi2Se5 thin films prepared by Arrested Precipitation Technique (APT). Arch. Appl. Sci. Res. 2(2), 275–283 (2010)
C. Xu, H. Zhang, J. Perry, S. Perera, G. Long, H. Zeng, A single source three-stage evaporation approach to CIGS absorber layer for thin film solar cells. Sol. Energy Mater. Sol. Cells 117, 357–362 (2013)
S.P. Patil, R.M. Mane, R.R. Kharade, S.S. Mali, P.N. Bhosale, Novel synthetic route for quaternary MoBiGaSe5 mixed metal chalcogenide (MMC) thin films. Dig. J. Nanomater. Biostructures 7, 237–245 (2012)
O.C. Monteiro, T. Trindade, F.A.A. Paz, J. Klinowski, J. Waters, P. O’Brien, Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(III) dibutyldiselenocarbamate. J. Mater. Chem. 13, 3006–3010 (2003)
R.A. Wibowo, H. Yoo, A. Holzing, R. Lechner, S. Jost, J. Palm, M. Gowtham, B. Louis, R. Hock, A study of kesterite Cu2ZnSn(Se, S)4 formation from sputtered Cu–Zn–Sn metal precursors by rapid thermal processing sulfo-selenization of the metal thin films. Thin Solid Films 535, 57–61 (2013)
S. Mahboob, S.N. Malik, N. Haider, C.Q. Nguyen, M.A. Malik, P. O’Brien, Deposition of binary, ternary and quaternary metal selenide thin films from diisopropyldiselenophosphinato-metal precursors. J. Cryst. Growth 394, 39–48 (2014)
X. Li, P. Wu, H. Qiu, S. Chen, B. Song, Crystallization behavior and mechanical properties of erbium oxide coatings fabricated by pulsed magnetron sputtering. Thin Solid Films 520, 2316–2320 (2012)
J. Tian, H. Deng, L. Sun, H. Kong, P. Yang, J. Chu, Effects of Co doping on structure and optical properties of TiO2 thin films prepared by sol–gel method. Thin Solid Films 520, 5179–5183 (2012)
J. Tian, H. Gao, H. Deng, L. Sun, H. Kong, P. Yang, J. Chu, Structural, magnetic and optical properties of Ni-doped TiO2 thin films deposited on silicon (100) substrates by sol-gel process. J. Alloys Compds. 581, 318–323 (2013)
T. Todorov, K. Petkov, M. Kincl, E. Cernoskova, M. Vlcek, L. Tichy, Synthesis, structure and optical properties of thin films from GeS2–In2S3 system deposited by thermal co-evaporation. Thin Solid Films 558, 298–305 (2014)
M.M. El-Nahass, A.A.M. Farag, H.S. Soliman, Optical absorption and dispersion characterizations of CuGaSe2 thin films prepared by flash evaporation technique. Opt. Commun. 284, 2515–2522 (2011)
Y. Li, Y. Zhang, Y. Lei, P. Li, H. Jia, H. Hou, Z. Zheng, In situ fabrication of Bi2S3 nanocrystal film for photovoltaic devices. Mater. Sci. Eng. B 177, 1764–1768 (2012)
M.M. Salunkhe, R.R. Kharade, R.M. Mane, P.N. Bhosale, Synthesis and characterization of nanocrystalline MoBi2Te5 thin films for photoelectrode application. Philos. Mag. Lett. 92, 563–571 (2012)
Acknowledgments
Authors are thankful to University Grants Commission (UGC), New Delhi for providing infrastructural facilities. This work was also supported by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2009–0094055).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mohite, S.S., Mali, S.S., Kharade, R.R. et al. Single source precursor for vacuum evaporation of MoBi2Se5 photoactive thin films. J Mater Sci: Mater Electron 26, 2879–2886 (2015). https://doi.org/10.1007/s10854-015-2772-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-015-2772-2