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Facile synthesis of molybdenum multisulfide composite nanorod arrays from single-source precursor for photoelectrochemical hydrogen generation

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Abstract

The deposition of molybdenum multisulfide thin-film photoanodes from the metal–organic precursor [CpMo(SMe)2]2 (1), at different deposition time has been investigated. Four different films were deposited at 550 °C under constant argon gas flow for 10, 15, 20, and 25 min, respectively. The surface morphology of these films analyzed with FE-SEM and AFM showed the presence of compact 1D rod-like structure of MoS2/Mo2S3in a homogeneous form. The average diameter of the 1D compact MoS2/Mo2S3 composite nanorod arrays was found in the range of 155–298 nm deposited for different time durations. EDX analysis showed a consistency where the Mo-to-S ratio was approximately 3:4.5 and demonstrated the overall composition of the 1D MoS2/Mo2S3 composite nanorod arrays. The XRD analysis of the thin film indicated the presence of monoclinic Mo2S3 and rhombohedral MoS2composite system. Moreover, the photocurrent density of 20 min deposited thin film is observed to be 4 mA/cm2 with highest photosensitivity of 6.78 at the overpotential of 0.3 V vs Ag/AgCl under the simulated light intensity of 100 mW/cm2 (AM 1.5G). The electrochemical impedance spectroscopy (EIS) also showed improved charge transportation with highest lifetime of the photoexcited charges in 20 min deposited thin film in comparison to the other deposition time durations. This study provides the optimized synthesis conditions for producing molybdenum-based multisulfide nanostructures and the deposition duration for their deployment in solar-based devices.

Graphical abstract

Complex [CpMo(SMe)2]2 (1) has been used as a single source precursor for fabrication of MoS2/Mo2S3 composite nanorod arrays on FTO glass substrate and tested for photoelectrochemical hydrogen generation.

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Acknowledgements

The presented work is supported by Funding from Universiti Tunku Abdul Rahman (UTARRF 6200/O10) and FRGS FP038-2016. Technical support from Mr. Ooh Keng Fai and Mr. Goh Wee Sheng is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemical Science, Universiti of Tunku Abdul Rahman, 31900, Kampar, Perak, Malaysia

    Chu Er Lim, Mei Lee Ooi & Kian Eang Neo

  2. Department of Chemistry, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Richard C. S. Wong

  3. School of Natural Sciences, National University of Sciences and Technology, H-12, Islamabad, Pakistan

    Asad Mumtaz & Muhammad Mazhar

  4. Department of Environmental Sciences, Fatima Jinnah Women University, The Mall, Rawalpindi, Pakistan

    Muhammad Mazhar

  5. Centre of Innovative Nanostructures and Nanodevices (COINN), Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak, Malaysia

    Asad Mumtaz, Norani Muti Mohamed & Mohamed Shuaib Mohamed Saheed

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  1. Chu Er Lim
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Lim, C.E., Ooi, M.L., Wong, R.C.S. et al. Facile synthesis of molybdenum multisulfide composite nanorod arrays from single-source precursor for photoelectrochemical hydrogen generation. Appl Nanosci 9, 1281–1292 (2019). https://doi.org/10.1007/s13204-019-00957-y

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