Size effect on interfacial reactions of Sn–3.0Ag–0.5Cu solder balls on Cu and Ni–P pads

Abstract

The size (volume) effect of solder balls on the interfacial reactions of Sn–3.0Ag–0.5Cu solders on both Cu and Ni–P pads in electronic packaging was systematically investigated. For the interfacial reaction on Cu pad, the smaller the solder ball is, the larger the interfacial Cu₆Sn₅ grains are, the thicker the intermetallic compound (IMC) layer is, and the less the Cu pad consumption is. The Cu concentration approached the solution saturation more rapidly in the smaller solder joints through grain boundary diffusion, resulting in smaller Cu outflux at the interface and consequently coarser interfacial Cu₆Sn₅ grains. For the interfacial reaction on Ni–P pad, the smaller the solder ball is, the earlier the transformation of interfacial IMCs from (Cu,Ni)₆Sn₅ to (Ni,Cu)₃Sn₄ occurs. The faster decreasing rate of Cu concentration in smaller molten solder resulted in the less supplying Cu influx and thus the earlier IMC transition. The Cu flux at the interface determines the growth kinetics and the phase transformation of interfacial IMCs on both Cu and Ni–P pads. Accordingly, the variation of Cu fluxes at the interface caused by solder ball volume results in the size effect.