Abstract
ZrO2–TiO2 composite films were fabricated by radio frequency magnetron sputtering and post annealing in O2. It was found the films remained amorphous below the annealing temperature of 500 °C. The as-deposited ZrO2–TiO2 film has a high dielectric constant of 22, and which increases to 34 after annealing at 400 °C. At low electric field, the dominant conduction mechanisms are Schottky emission for both the as-deposited and the annealed thin films. At high electric field, the conduction mechanism changes to space-charge-limited current and then changes to Poole–Frenkel (PF) emission after annealing at 400 °C.
Similar content being viewed by others
References
B. Doyle, R. Arghavani, D. Barlage, S. Datta, M. Doczy, J. Kavalieros, A. Murthy, R. Chau, Intel. Technol. J. 6, 42 (2002)
V.V. Afanas’ev, A. Stesmans, F. Chen, S.A. Campbell, R. Smith, Appl. Phys. Lett. 82, 922 (2003)
V. Mikhelashvili, G. Eisenstein, A. Lahav, Appl. Phys. Lett. 90, 013506 (2007)
H. Wang, Y. Wang, J. Zhang, C. Ye, H.B. Wang, J. Feng, B.Y. Wang, Q. Li, Y. Jiang, Appl. Phys. Lett. 93, 202904 (2008)
G. He, L.D. Zhang, M. Liu, J.P. Zhang, X.J. Wang, C.M. Zhen, J. Appl. Phys. 105, 014109 (2009)
G.K. Dalapati, A. Sridhara, A.S.W. Wong, C.K. Chia, D.Z. Chi, Appl. Phys. Lett. 94, 073502 (2009)
Y. Wang, H. Wang, J. Zhang, H.B. Wang, C. Ye, Y. Jiang, Q. Wang, Appl. Phys. Lett. 95, 032905 (2009)
J.P. Chang, Y.S. Lin, Appl. Phys. Lett. 79, 3666 (2001)
F.C. Chiu, Z.H. Lin, C.W. Chang, C.C. Wang, K.F. Chuang, C.Y. Huang, J.Y. Lee, H.L. Hwang, J. Appl. Phys. 97, 034506 (2005)
M. Zhu, P. Chen, R.K.Y. Fu, W.L. Liu, C.L. Lin, P.K. Chu, Thin Solid Films 476, 312 (2005)
Y.H. Wu, C.K. Kao, B.Y. Chen, Y.S. Lin, M.Y. Li, H.C. Wu, Appl. Phys. Lett. 93, 033511 (2008)
D. Tsoutsou, L. Lamagna, S.N. Volkos, A. Molle, S. Baldovino, S. Schamm, Appl. Phys. Lett. 94, 053504 (2009)
L. Manchanda, M.D. Morris, M.L. Green, R.B. van Dover, F. Klemens, T.W. Sorsch, P.J. Silverman, G. Wilk, B. Busch, S. Aravamudhan. Microelectron. Eng. 59, 351 (2001)
S. Chatterjee, S.K. Samanta, H.D. Banerjee, C.K. Maiti, Thin Solid Film 422, 38 (2002)
A. Paskaleva, A.J. Bauer, M. Lemberger, S. Zürcher, J. Appl. Phys. 95, 5583 (2004)
F. Chen, X. Bin, C. Hella, X. Shi, W.L. Gladfelter, S.A. Campbel, Microelectron. Eng. 72, 263 (2004)
V.V. Afanas’ev, A. Stesmans, F. Chen, M. Li, S.A. Campbell, J. Appl. Phys. 95, 7936 (2004)
K. Honda, A. Sakai, M. Sakashita, H. Ikeda, S. Zaima, Y. Yasuda, Jpn. J. Appl. Phys. 43, 1571 (2004)
C. Ye, H. Wang, J. Zhang, Y. Ye, Y. Wang, B.Y. Wang, Y.C. Jin, J. Appl. Phys. 107, 104103 (2010)
T. Kim, J. Oh, B. Park, K.S. Hong, Appl. Phys. Lett. 76, 3043 (2000)
H. Wang, Y. Wang, J. Feng, C. Ye, B.Y. Wang, H.B. Wang, Q. Li, Y. Jiang, A.P. Huang, Z.S. Xiao, Appl. Phys. A. 93, 681 (2008)
M.-H. Cho, Y.S. Roh, C.N. Whang, K. Jeong, Appl. Phys. Lett. 81, 1071 (2002)
L.M. Terman, Solid State Electron. 5, 285 (1962)
M. Houssa, V.V. Afanas’ev, A. Stesmans, M.M. Heyns, Appl. Phys. Lett. 77, 1885 (2000)
L. Pereira, P. Barquinha, E. Fortunato, R. Martins, Mater. Sci. Semicond. Process. 9, 1125 (2006)
R. Puthenkovilakam, M. Sawkar, J.P. Chang, Appl. Phys. Lett. 86, 202902 (2005)
P.V. Aleskandrova, V.K. Gueorguiev, Tz.E. Ivanov, J.B. Koprinarova, Eur. Phys. J. B. 52, 453 (2006)
M.T. Wang, T.H. Wang, J.Y. Lee, Microelectron. Reliab. 45, 969 (2005)
S. Ramanathan, C.M. Park, P.C. McIntyre, J. Appl. Phys. 91, 4521 (2002)
F.C. Chiu, J. Appl. Phys. 100, 114102 (2006)
S.D. Ganichev, E. Ziemann, W. Prettl, I.N. Yassievich, A.A. Istrarov, E.R. Weber, Phys. Rev. B. 61, 10361 (2000)
Acknowledgments
This work is supported in partial by the National Nature Science Foundation of China (No. 51072049), MOST of China (No.2007CB936202), STD and ED of Hubei Province (Grant Nos. 2009CDA035, 2008BAB010, and Z20091001).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dong, M., Wang, H., Shen, L. et al. Dielectric property and electrical conduction mechanism of ZrO2–TiO2 composite thin films. J Mater Sci: Mater Electron 23, 174–179 (2012). https://doi.org/10.1007/s10854-011-0378-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-011-0378-x