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Submicron size Li(Ni1/3Co1/3Mn1/3)O2 particles prepared by spray pyrolysis from polymeric precursor solution

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Abstract

Submicron-sized Li(Ni1/3Co1/3Mn1/3)O2 particles were prepared by spray pyrolysis. A polymeric precursor solution containing citric acid and ethylene glycol enabled the formation of submicron-sized Li(Ni1/3Co1/3Mn1/3)O2 spherical particles with narrow-sized distribution and non-aggregation characteristics in the spray pyrolysis. The mean sizes of the particles post-treated at temperatures of 800 and 900∘C were 380 and 770 nm. On the other hand, the Li(Ni1/3Co1/3Mn1/3)O2 particles obtained from the aqueous solution had irregular morphology and broad-sized distribution. The discharge capacity of the particles prepared from polymeric precursor solution decreased from 88 mAh/g to 135 mAh/g after 50 cycles. The particles prepared from polymeric precursor solution had high discharge capacity and good cyclic properties than those of the particles prepared from the aqueous solution.

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Authors and Affiliations

  1. Department of Chemical Engineering, Konkuk University, 1 Hwayang-dong, Gwangjin-gu, Seoul, 143-701, Korea

    S. H. Ju, H. Y. Koo, D. Y. Kim, S. K. Hong & Y. C. Kang

  2. Division of Chemistry and Molecular Engineering, Korea University, Seoul, 136-701, Korea

    H. W. Ha & K. Kim

Authors
  1. S. H. Ju
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  2. H. Y. Koo
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  3. D. Y. Kim
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  4. S. K. Hong
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  5. Y. C. Kang
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  6. H. W. Ha
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  7. K. Kim
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Correspondence to Y. C. Kang.

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Ju, S.H., Koo, H.Y., Kim, D.Y. et al. Submicron size Li(Ni1/3Co1/3Mn1/3)O2 particles prepared by spray pyrolysis from polymeric precursor solution. J Mater Sci: Mater Electron 17, 353–359 (2006). https://doi.org/10.1007/s10854-006-7470-7

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  • DOI: https://doi.org/10.1007/s10854-006-7470-7

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