Abstract
We investigate the influence of polymer molecular weight on the properties of silver–methylcellulose (Ag–MC) nanocomposite films synthesized by the irradiation of a CO2 laser. Although the reduction power of MC with a smaller molecular weight turns out to be stronger than that with a larger molecular weight in the solution phase, we do not see such a clear difference when MC is in the matrix phase. For the 30 s irradiation at the laser power of 0.8 W, the size of Ag nanoparticles (NPs) in the two types of MC matrix is similar, and it is about 30 nm. However, for the longer irradiation time at the same laser power, aggregation of Ag NPs set in, and it is more serious for the Ag–MC film with MC of larger molecular weight. We also carry out the antibacterial test with the Ag–MC films, and find that the Ag–MC film synthesized at the lower laser power and shorter irradiation time generally exhibits a stronger antibacterial effect.
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Sih BC, Wolf MO (2005) Metal nanoparticle—conjugated polymer nanocomposites. Chem Commun 27:3375–3384. https://doi.org/10.1039/b501448d
Ramesh GV, Porel S, Radhakrishnan TP (2009) Polymer thin films embedded with in situ grown metal nanoparticles. Chem Soc Rev 38:2646–2656. https://doi.org/10.1039/b815242j
Faupel F, Zaporojtchenko V, Strunskus T, Elbahri M (2010) Metal-polymer nanocomposites for functional applications. Adv Eng Mater 12:1177–1190. https://doi.org/10.1002/adem.201000231
Mbhele ZH, Salemane MG, Van Sittert CGCE et al (2003) Fabrication and characterization of silver—polyvinyl alcohol nanocomposites. Chem Mater 15:5019–5024
Khanna PK, Singh N, Charan S et al (2005) Synthesis and characterization of Ag/PVA nanocomposite by chemical reduction method. Mater Chem Phys 93:117–121. https://doi.org/10.1016/j.matchemphys.2005.02.029
Xu P, Han X, Zhang B et al (2014) Multifunctional polymer—metal nanocomposites via direct chemical reduction by conjugated polymers. Chem Soc Rev 43:1349–1360. https://doi.org/10.1039/c3cs60380f
Pucci A, Bernabo M, Elvati P et al (2006) Photoinduced formation of gold nanoparticles into vinyl alcohol based polymers. J Mater Chem 16:1058–1066. https://doi.org/10.1039/b511198f
Sakamoto M, Tachikawa T, Fujitsuka M, Majima T (2006) Acceleration of laser-induced formation of gold nanoparticles in a poly (vinyl alcohol) film. Langmuir 22:6361–6366
Lee CJ, Karim MR, Lee MS (2007) Synthesis and characterization of silver/thiophene nanocomposites by UV-irradiation method. Mater Lett 61:2675–2678. https://doi.org/10.1016/j.matlet.2006.10.021
Sakamoto M, Fujistuka M, Majima T (2009) Light as a construction tool of metal nanoparticles: synthesis and mechanism. J Photochem Photobiol C Photochem Rev 10:33–56. https://doi.org/10.1016/j.jphotochemrev.2008.11.002
Jiang T, Li J, Zhang L et al (2014) Microwave assisted in situ synthesis of Ag-NaCMC films and their reproducible surface-enhanced Raman scattering signals. J Alloys Compd 602:94–100
Porel S, Singh S, Harsha SS et al (2005) Nanoparticle-embedded polymer. in situ synthesis, free-standing films with highly monodisperse silver nanoparticles and optical limiting. Chem Mater 17:9–12
Kashihara K, Uto Y, Nakajima T (2018) Rapid in situ synthesis of polymer-metal nanocomposite films in several seconds using a CO2 laser. Sci Rep 8:14719. https://doi.org/10.1038/s41598-018-33006-9
Moon RJ, Martini A, Nairn J et al (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994. https://doi.org/10.1039/c0cs00108b
Hoeng F, Denneulin A, Bras J (2016) Use of nanocellulose in printed electronics: a review. Nanoscale 8:13131–13154. https://doi.org/10.1039/c6nr03054h
Van Rie J, Thielemans W (2017) Cellulose–gold nanoparticle hybrid materials. Nanoscale 9:8525–8554. https://doi.org/10.1039/c7nr00400a
Zhang BT, Wang W, Zhang D et al (2010) Biotemplated synthesis of gold nanoparticle—bacteria cellulose nanofiber nanocomposites and their application in biosensing. Adv Funct Mater 20:1152–1160. https://doi.org/10.1002/adfm.200902104
Yan W, Chen C, Wang L et al (2016) Facile and green synthesis of cellulose nanocrystal-supported gold nanoparticles with superior catalytic activity. Carbohydr Polym 140:66–73
Koga H, Tokunaga E, Hidaka M et al (2010) Topochemical synthesis and catalysis of metal nanoparticles exposed on crystalline cellulose nanofibers. Chem Commun 46:8567–8569. https://doi.org/10.1039/c0cc02754e
Li X, Chen S, Hu W et al (2009) In situ synthesis of CdS nanoparticles on bacterial cellulose nanofibers. Carbohydr Polym 76:509–512. https://doi.org/10.1016/j.carbpol.2008.11.014
Li R, He M, Li T, Zhang L (2015) Preparation and properties of cellulose/silver nanocomposite fibers. Carbohydr Polym 115:269–275. https://doi.org/10.1016/j.carbpol.2014.08.046
Liou P, Xavier F, Kong F et al (2017) Cellulose nanofibers coated with silver nanoparticles as a SERS platform for detection of pesticides in apples. Carbohydr Polym 157:643–650. https://doi.org/10.1016/j.carbpol.2016.10.031
Galland S, Andersson RL, Salajkova M et al (2013) Cellulose nanofibers decorated with magnetic nanoparticles—synthesis, structure and use in magnetized high toughness membranes for a prototype loudspeaker. J Mater Chem C 1:7963–7972. https://doi.org/10.1039/c3tc31748j
Lukach A, Therien-Aubin H, Querejeta-Fernandez A et al (2015) Coassembly of gold nanoparticles and cellulose nanocrystals in composite films. Langmuir 31:5033–5041. https://doi.org/10.1021/acs.langmuir.5b00728
Bhui DK, Pyne S, Sarkar P et al (2011) Temperature controlled synthesis of silver nanostructures of variable morphologies in aqueous methyl cellulose matrix. J Mol Liq 158:170–174. https://doi.org/10.1016/j.molliq.2010.11.014
Mahanta N, Valiyaveettil S (2012) In situ preparation of silver nanoparticles on biocompatible methacrylated poly (vinyl alcohol) and cellulose based polymeric nanofibers. RSC Adv 2:11389–11396. https://doi.org/10.1039/c2ra20637d
Kumar A, Negi YS, Bhardwaj NK, Choudhary V (2012) Synthesis and characterization of methylcellulose/PVA based porous composite. Carbohydr Polym 88:1364–1372. https://doi.org/10.1016/j.carbpol.2012.02.019
Maity D, Mollick MMR, Mondal D et al (2012) Synthesis of methylcellulose-silver nanocomposite and investigation of mechanical and antimicrobial properties. Carbohydr Polym 90:1818–1825. https://doi.org/10.1016/j.carbpol.2012.07.082
Xu W, Xu Q, Huang Q et al (2015) Electrically conductive silver nanowires- filled methylcellulose composite transparent films with high mechanical properties. Mater Lett 152:173–176. https://doi.org/10.1016/j.matlet.2015.03.111
Nasatto PL, Pignon F, Silveira JLM et al (2015) Methylcellulose, a cellulose derivative with original physical properties and extended applications. Polymers (Basel) 7:777–803. https://doi.org/10.3390/polym7050777
Aziz SB, Rasheed MA, Ahmed HM (2017) Synthesis of Polymer Nanocomposites Based on [Methyl Cellulose](1−x):(CuS)x(0.02 M < x<0.08 M) with Desired Optical Band Gaps. Polymers (Basel) 9:194. https://doi.org/10.3390/polym9060194
Kolarova K, Samec D, Kvitek O et al (2017) Preparation and characterization of silver nanoparticles in methyl cellulose matrix and their antibacterial activity. Jpn J Appl Phys. https://doi.org/10.7567/JJAP.56.06GG09
Nunes MR, Castilho MDSM, de Lima Veeck AP et al (2018) Antioxidant and antimicrobial methylcellulose films containing Lippia alba extract and silver nanoparticles. Carbohydr Polym 192:37–43. https://doi.org/10.1016/j.carbpol.2018.03.014
Chen J, Wang J, Zhang X, Jin Y (2008) Microwave-assisted green synthesis of silver nanoparticles by carboxymethyl cellulose sodium and silver nitrate. Mater Chem Phys 108:421–424. https://doi.org/10.1016/j.matchemphys.2007.10.019
Rangelova N, Aleksandrov L, Angelova T et al (2014) Preparation and characterization of SiO2/CMC/Ag hybrids with antibacterial properties. Carbohydr Polym 101:1166–1175
Shi D, Wang F, Lan T et al (2016) Convenient fabrication of carboxymethyl cellulose electrospun nanofibers functionalized with silver nanoparticles. Cellulose 23:1899–1909. https://doi.org/10.1007/s10570-016-0918-x
Park JS, Kim T, Kim WS (2017) Conductive cellulose composites with low percolation threshold for 3D printed electronics. Sci Rep 7:3246. https://doi.org/10.1038/s41598-017-03365-w
Cheng F, Betts JW, Kelly SM et al (2013) Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent. Green Chem 15:989–998. https://doi.org/10.1039/c3gc36831a
Saha NR, Sarkar G, Roy I et al (2016) Nanocomposite films based on cellulose acetate/polyethylene glycol/modified montmorillonite as nontoxic active packaging material. RSC Adv 6:92569–92578. https://doi.org/10.1039/C6RA17300D
Luo C, Zhang Y, Zeng X et al (2005) The role of poly(ethylene glycol) in the formation of silver nanoparticles. J Colloid Interface Sci 288:444–448. https://doi.org/10.1016/j.jcis.2005.03.005
Ruparelia JP, Chatterjee AK, Duttagupta SP, Mukherji S (2008) Strain specificity in antimicrobial activity of silver and copper nanoparticles. Acta Biomater 4:707–716. https://doi.org/10.1016/j.actbio.2007.11.006
Suflet DM, Chitanu GC, Popa VI (2006) Phosphorylation of polysaccharides: new results on synthesis and characterisation of phosphorylated cellulose. React Funct Polym 66:1240–1249. https://doi.org/10.1016/j.reactfunctpolym.2006.03.006
Silverstein RM, Webster FX, Kiemle DJ, Bryce DL (2014) Spectrometric identification of organic compounds. Wiley, Hoboken
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TN acknowledges a financial support from the Amada Foundation.
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Nishikawa, H., Nakata, E., Nakano, S. et al. Influence of polymer molecular weight on the properties of in situ synthesized silver–methylcellulose nanocomposite films with a CO2 laser. J Mater Sci 55, 2090–2100 (2020). https://doi.org/10.1007/s10853-019-04149-5
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DOI: https://doi.org/10.1007/s10853-019-04149-5