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Bio-adenine-bridged molecular design approach toward non-covalent functionalized graphene by liquid-phase exfoliation

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Abstract

Here, the supramolecular interaction between nucleobase adenine and graphene was strengthened by a novel chemical molecular designing strategy. Based on this approach, the adenine-bridged aromatic phthalonitrile (AAPN) was prepared as stabilizer toward liquid-phase exfoliation for non-covalent functionalized graphene (AAPN-G). A series of experiments were carried out to verify the strong supramolecular interaction between AAPN and graphene. The feasibility of multifunctional application of the AAPN was briefly demonstrated. This work constitutes a feasible strategy in the preparation and functionalization of graphene that could be extended to some other (bio)molecules toward realization of designing multifunctional materials.

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Acknowledgements

We thank the Analytical & Testing Center, Sichuan University, P. R. China, for the molecular simulation (Materials Studio 8.0) support.

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Authors and Affiliations

  1. State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu, 610065, People’s Republic of China

    Yao Liu, Renke Li, Bo Liang, Chengfeng Li, Jiang-huai Hu, Ke Zeng & Gang Yang

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  1. Yao Liu
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  2. Renke Li
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  3. Bo Liang
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  4. Chengfeng Li
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  5. Jiang-huai Hu
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  6. Ke Zeng
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  7. Gang Yang
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Correspondence to Ke Zeng or Gang Yang.

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Liu, Y., Li, R., Liang, B. et al. Bio-adenine-bridged molecular design approach toward non-covalent functionalized graphene by liquid-phase exfoliation. J Mater Sci 55, 140–150 (2020). https://doi.org/10.1007/s10853-019-03931-9

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