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Photocatalytic disinfection efficiency of 2D structure graphitic carbon nitride-based nanocomposites: a review

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Abstract

Nanostructured carbon-based photocatalysts have gained attention in photocatalytic disinfection of microbial species. With distinctive features of possessing appropriate electronic band gap structure and high chemical and thermal stability, metal-free polymeric 2D stacked structure graphitic carbon nitride (g-C3N4) is an important photocatalytic material for environmental and energy applications. Besides, it has the potential for inactivation of harmful pathogens. Disinfection of microbial species is mainly ascribed to the formation of reactive oxidative species. Further, surface modification of g-C3N4 can remarkably improves photocatalytic disinfection efficiency. In this review, we have discussed the recent advances in photocatalytic disinfection using g-C3N4-based nanocomposites. An overview of metal-free nanostructure g-C3N4, metal (anions) and nonmetal (cations)-doped g-C3N4 and g-C3N4 hybridized with low band gap semiconductor is also presented. Moreover, we have emphasized on the photocatalytic disinfection mechanism associated with g-C3N4-modified composites. Nitrogen-rich g-C3N4 polymeric material can serve as an alternative to metal oxide (TiO2 and ZnO) photocatalysts for photocatalytic disinfection technology. Other applications such as CO2 photoreduction, H2 generation, organic pollutant degradation, and sensing using g-C3N4-based nanocomposites are also summarized.

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References

  1. Kramer A, Schwebke I, Kampf G (2006) How long do nosocomial pathogens persist on inanimate surfaces? A systematic review. BMC Infect Dis 6:1–8

    Google Scholar 

  2. Paul NC, Sullivan TS, Shah DH (2017) Differences in antimicrobial activity of chlorine against twelve most prevalent poultry-associated Salmonella serotypes. Food Microbiol 64:202–209

    Google Scholar 

  3. Feliziani E, Lichter A, Smilanick JL, Ippolito A (2016) Disinfecting agents for controlling fruit and vegetable diseases after harvest. Postharvest Biol Technol 122:53–69

    Google Scholar 

  4. Memarzadeh F, Olmsted RN, Bartley JM (2010) Applications of ultraviolet germicidal irradiation disinfection in health care facilities: effective adjunct, but not stand-alone technology. Am J Infect Control 38:13–24

    Google Scholar 

  5. Guo M, Huang J, Hu H et al (2012) UV inactivation and characteristics after photoreactivation of Escherichia coli with plasmid: health safety concern about UV disinfection. Water Res 46:4031–4036

    Google Scholar 

  6. Visnapuu M, Rosenberg M, Truska E et al (2018) UVA-induced antimicrobial activity of ZnO/Ag nanocomposite covered surfaces. Colloids Surf B Biointerfaces 169:222–232

    Google Scholar 

  7. Wang Y, Wu Y, Yang H et al (2016) Doping TiO2 with boron or/and cerium elements: effects on photocatalytic antimicrobial activity. Vacuum 131:58–64

    Google Scholar 

  8. Wu MJ, Bak T, Moffitt MC et al (2014) Photocatalysis of titanium dioxide for water disinfection: challenges and future perspectives. Int J Photochem 2014:1–9

    Google Scholar 

  9. Dimapilis EAS, Hsu CS, Mendoza RMO, Lu MC (2018) Zinc oxide nanoparticles for water disinfection. Sustain Environ Res 28:47–56

    Google Scholar 

  10. Gondal MA, Khalil A (2008) Rapid disinfection of E-Coliform contaminated water using WO3 semiconductor catalyst by laser-induced photo-catalytic process. J Environ Sci Health Part A Toxic Hazard Subst Environ Eng 43:488–494

    Google Scholar 

  11. Chen M, Zhang F, Oh W (2011) Fabrication and performances of MWCNT/TiO2 composites derived from MWCNTs and titanium (IV) alkoxide precursors. Bull Mater Sci 34:835–841

    Google Scholar 

  12. Fernández-Ibáñez P, Polo-López MI, Malato S et al (2015) Solar photocatalytic disinfection of water using titanium dioxide graphene composites. Chem Eng J 261:36–44

    Google Scholar 

  13. Wang B, Jiang Z, Yu JC (2019) Treated rape pollen: a metal-free visible-light-driven photocatalyst from nature for efficient water disinfection. J Mater Chem A 7:9335–9344

    Google Scholar 

  14. Ren Y, Zeng D, Ong W (2019) Interfacial engineering of graphitic carbon nitride (g-C3N4)-based metal sulfide heterojunction photocatalysts for energy conversion: a review. Chin J Catal 40:289–319

    Google Scholar 

  15. Wu WS, Wu FG (2018) Two-dimensional materials for antimicrobial applications: graphene materials and beyond. Chem Asian J 13:3378–3410

    Google Scholar 

  16. Wang X, Maeda K, Thomas A et al (2008) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80

    Google Scholar 

  17. Dong G, Zhang Y, Pan Q, Qiu J (2014) A fantastic graphitic carbon nitride (g-C3N4) material: electronic structure, photocatalytic and photoelectronic properties. J Photochem Photobiol C Photochem Rev 20:33–50

    Google Scholar 

  18. Naseri A, Samadi M, Pourjavadi A et al (2017) Graphitic carbon nitride (g-C3N4)-based photocatalysts for solar hydrogen generation: recent advances and future development directions. J Mater Chem A 5:23406–23433

    Google Scholar 

  19. Li Y, Sun Y, Ho W et al (2018) Highly enhanced visible-light photocatalytic NOx purification and conversion pathway on self-structurally modified g-C3N4 nanosheets. Sci Bull 63:609–620

    Google Scholar 

  20. Yu K, Hu X, Yao K et al (2017) Preparation of an ultrathin 2D/2D rGO/g-C3 N4 nanocomposite with enhanced visible-light-driven photocatalytic performance. RSC Adv 7:36793–36799

    Google Scholar 

  21. Das D, Shinde SL, Nanda KK (2015) Temperature-dependent photoluminescence of g-C3N4: implication for temperature sensing. ACS Appl Mater Interfaces 8:2181–2186

    Google Scholar 

  22. Zhang C, Li Y, Shuai D et al (2018) Graphitic carbon nitride (g-C N)-based photocatalysts for water disinfection and microbial control: a review. Chemosphere 214:462–479

    Google Scholar 

  23. Zimbone M, Buccheri MA, Cacciato G et al (2015) Photocatalytical and antibacterial activity of TiO2 nanoparticles obtained by laser ablation in water. Appl Catal B Environ 165:487–494

    Google Scholar 

  24. Ehtisham Khan M, Hiep Han T, Mansoob Khan M et al (2018) Environmentally sustainable fabrication of Ag@g-C3N4 nanostructures and their multifunctional efficacy as antibacterial agents and photocatalysts. ACS Appl Nano Mater 1(6):2912–2922

    Google Scholar 

  25. Tao Y, Ni Q, Wei M et al (2015) Metal-free activation of peroxymonosulfate by g-C3N4 under visible light irradiation for the degradation of organic dyes. RSC Adv 5:44128–44136

    Google Scholar 

  26. Shanmugam V, Lakshmi A, Jayavel S, Sundar K (2018) Construction of high efficient g-C3N4 nanosheets combined with Bi2MoO6–Ag photocatalysts for visible-light-driven photocatalytic activity and inactivation of bacterias. Arab J Chem. https://doi.org/10.1016/j.arabjc.2018.05.009

    Google Scholar 

  27. Thurston JH, Hunter NM, Wayment LJ, Cornell KA (2017) Urea-derived graphitic carbon nitride (u-g-C3N4) films with highly enhanced antimicrobial and sporicidal activity. J Colloid Interface Sci 505:910–918

    Google Scholar 

  28. Thurston JH, Hunter NM, Cornell KA (2016) Preparation and characterization of photoactive antimicrobial graphitic carbon nitride (g-C3N4) films. RSC Adv 6:42240–42248

    Google Scholar 

  29. Fu J, Yu J, Jiang C, Cheng B (2018) g-C3N4-based heterostructured photocatalysts. Adv Energy Mater 8:1–31

    Google Scholar 

  30. Liebig J (1834) Uber einige Stickstoff—Verbindungen. Annalen der Pharmacie. Eur J Organ Chem 10:1–47

    Google Scholar 

  31. Zhou Z, Zhang Y, Shen Y et al (2018) Molecular engineering of polymeric carbon nitride: advancing applications from photocatalysis to biosensing and more. Chem Soc Rev 47:2298–2321

    Google Scholar 

  32. Wang A, Wang C, Fu L et al (2017) Recent advances of graphitic carbon nitride-based structures and applications in catalyst, sensing, imaging, and LEDs. Nano-Micro Lett 9:47

    Google Scholar 

  33. Zhu J, Xiao P, Li H, Carabineiro SC (2014) Graphitic carbon nitride: synthesis, properties, and applications in catalysis. ACS Appl Mater Interfaces 6:16449–16465

    Google Scholar 

  34. Thomas A, Fischer A, Goettmann F et al (2008) Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts. J Mater Chem 18:4893

    Google Scholar 

  35. Praus P, Svoboda L, Ritz M et al (2017) Graphitic carbon nitride: synthesis, characterization and photocatalytic decomposition of nitrous oxide. Mater Chem Phys 193:438–446

    Google Scholar 

  36. Dong R, Tian B, Zeng C et al (2012) Ecofriendly synthesis and photocatalytic activity of uniform cubic Ag@AgCl plasmonic photocatalyst. J Phys Chem C 4:213–220

    Google Scholar 

  37. Zheng Y, Liu J, Liang JJ et al (2012) Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy Environ Sci 5:6717–6731

    Google Scholar 

  38. Fanchini G, Tagliaferro A, Conway NMJ, Godet C (2002) Role of lone-pair interactions and local disorder in determining the interdependency of optical constants of a − CN:H thin films. Phys Rev B 66:195415

    Google Scholar 

  39. Lyth SM, Nabae Y, Moriya S et al (2009) Carbon nitride as a nonprecious catalyst for electrochemical oxygen reduction. J Phys Chem C 113:20148–20151

    Google Scholar 

  40. Dong G, Zhang L (2012) Porous structure dependent photoreactivity of graphitic carbon nitride under visible light. J Mater Chem 22:1160–1166

    Google Scholar 

  41. Zhou J, Chen W, Sun C et al (2017) Oxidative polyoxometalates modified graphitic carbon nitride for visible-light CO2 reduction. ACS Appl Mater Interfaces 9:11689–11695

    Google Scholar 

  42. Yu J, Wang K, Xiao W, Cheng B (2014) Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4–Pt nanocomposite photocatalysts. Phys Chem Chem Phys 16:11492

    Google Scholar 

  43. Mao J, Peng T, Zhang X et al (2013) Effect of graphitic carbon nitride microstructures on the activity and selectivity of photocatalytic CO2 reduction under visible light. Catal Sci Technol 3:1253

    Google Scholar 

  44. Xia J, Di J, Yin S et al (2014) Solvothermal synthesis and enhanced visible-light photocatalytic decontamination of bisphenol A (BPA) by g-C3N4/BiOBr heterojunctions. Mater Sci Semicond Process 24:96–103

    Google Scholar 

  45. Wang Y, Zhao S, Zhang Y et al (2018) Facile synthesis of self-assembled g-C3N4 with abundant nitrogen defects for photocatalytic hydrogen evolution. ACS Sustain Chem Eng 6:10200–10210

    Google Scholar 

  46. Hu C, Chu Y, Wang M, Wu X (2017) Rapid synthesis of g-C3N4 spheres using microwave-assisted solvothermal method for enhanced photocatalytic activity. J Photochem Photobiol A Chem 348:8–17

    Google Scholar 

  47. Papailias I, Giannakopoulou T, Todorova N et al (2015) Effect of processing temperature on structure and photocatalytic properties of g-C3N4. Appl Surf Sci 358:278–286

    Google Scholar 

  48. Guo Q, Xie Y, Wang X et al (2003) Characterization of well-crystallized graphitic carbon nitride nanocrystallites via a benzene-thermal route at low temperatures. Chem Phys Lett 380:84–87

    Google Scholar 

  49. Guo Q, Yang Q, Zhu L et al (2004) A facile one-pot solvothermal route to tubular forms of luminescent. Solid State Commun 132:369–374

    Google Scholar 

  50. Dai H, Gao X, Liu E et al (2013) Synthesis and characterization of graphitic carbon nitride sub-microspheres using microwave method under mild condition. Diam Relat Mater 38:109–117

    Google Scholar 

  51. Hu C, Chu Y, Wang M, Wu X (2017) Rapid synthesis of g-C3N4 spheres using microwave-assisted solvothermal method for enhanced photocatalytic activity. J Photochem Photobiol A Chem 348:8–17

    Google Scholar 

  52. Wang J, Miller DR, Gillan EG (2002) Photoluminescent carbon nitride films grown by vapor transport of carbon nitride powders. Chem Commun 19:2258–2259

    Google Scholar 

  53. Kang S, Huang W, Zhang L et al (2018) Moderate bacterial etching allows scalable and clean delamination of g-C3N4 with enriched unpaired electrons for highly improved photocatalytic water disinfection. ACS Appl Mater Interfaces 10:13796–13804

    Google Scholar 

  54. Zhou S, Liu Y, Li J et al (2014) Facile in situ synthesis of graphitic carbon nitride (g-C3N4)-N-TiO2 heterojunction as an efficient photocatalyst for the selective photoreduction of CO2 to CO. Appl Catal B Environ 158–159:20–29

    Google Scholar 

  55. Ye L, Wu D, Chu KH et al (2016) Phosphorylation of g-C3N4 for enhanced photocatalytic CO2 reduction. Chem Eng J 304:376–383

    Google Scholar 

  56. Dong F, Zhao Z, Xiong T et al (2013) In situ construction of g-C3N4/g-C3N4 metal-free heterojunction for enhanced visible-light photocatalysis. ACS Appl Mater Interfaces 5:11392–11401

    Google Scholar 

  57. Jing L, Xu Y, Chen Z, He M (2018) Different morphologies SnS2 supported on 2D g-C3N4 for excellent and stable visible light photocatalytic hydrogen generation. ACS Sustain Chem Eng 6:5132–5141

    Google Scholar 

  58. Teng Z, Yang N, Lv H et al (2018) Edge-functionalized g-C3N4 nanosheets as a highly efficient metal-free photocatalyst for safe drinking water. Chem 5:1–17

    Google Scholar 

  59. Liang S, Zhang D, Pu X et al (2019) Separation and purification technology a novel Ag2O/g-C3N4 pn heterojunction photocatalysts with enhanced visible and near-infrared light activity. Sep Purif Technol 210:786–797

    Google Scholar 

  60. Wang XJ, Tian X, Sun YJ, Zhu JY, Li FT, Mu HY, Zhao J (2018) Enhanced Schottky effect of a 2D–2D CoP/gC3N4 interface for boosting photocatalytic H2 evolution. Nanoscale 10(26):12315–12321

    Google Scholar 

  61. Xia K, Chen Z, Yi J et al (2018) Highly efficient visible-light-driven schottky catalyst MoN/2D g-C3N4 for hydrogen production and organic pollutants degradation. Ind Eng Chem Res 57:8863–8870

    Google Scholar 

  62. Shen Y, Zhu Z, Wang X et al (2018) Synthesis of Z-scheme g-C3N4/Ag/Ag3PO4 composite for enhanced photocatalytic degradation of phenol and selective oxidation of gaseous isopropanol. Mater Res Bull 107:407–415

    Google Scholar 

  63. Kroke E, Schwarz M, Horath-bordon E et al (2002) Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structures y. New J Chem 26:508–512

    Google Scholar 

  64. Wen J, Xie J, Chen X, Li X (2017) A review on g-C3N4-based photocatalysts. Appl Surf Sci 391:72–123

    Google Scholar 

  65. Cao S, Low J, Yu J, Jaroniec M (2015) Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater 27:2150–2176

    Google Scholar 

  66. Wang Y, Wang X, Antonietti M (2012) Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry. Angew Chem Int Ed 51:68–89

    Google Scholar 

  67. Li S, Wang Z, Wang X et al (2017) Orientation controlled preparation of nanoporous carbon nitride fibers and related composite for gas sensing under ambient conditions. Nano Res 10:1710–1719

    Google Scholar 

  68. Chen P, Wang H, Liu H et al (2018) Directional electron delivery and enhanced reactants activation enable efficient photocatalytic air purification on amorphous carbon nitride Co-functionalized with O/La. Appl Catal B Environ 242:19–30

    Google Scholar 

  69. Cui AW, Li J, Sun Y, Wang H (2018) Enhancing ROS generation and suppressing toxic intermediate production in photocatalytic NO oxidation on O/Ba co-functionalized amorphous carbon nitride. Appl Catal B Environ 237:938–946

    Google Scholar 

  70. Li J, Zhang Z, Cui W, Wang H, Cen W, Johnson G, Jiang G, Zhang S, Dong F (2018) The spatially oriented charge flow and photocatalysis mechanism on internal van der Waals heterostructures enhanced g-C3N4. ACS Catal 8:8376–8385

    Google Scholar 

  71. Xiong T, Wang H, Zhou Y, Sun Y, Cen W, Huang H, Zhang Y, Dong F (2018) KCl-mediated dual electronic channels in layered g-C3N4 for enhanced visible light photocatalytic NO removal. Nanoscale 10:8066–8074

    Google Scholar 

  72. Cui J, Liang S, Wang X, Zhang J (2015) First principle modeling of oxygen-doped monolayer graphitic carbon nitride. Mater Chem Phys 161:194–200

    Google Scholar 

  73. Wang J, Guan Z, Huang J, Li Q, Yang J (2014) Enhanced photocatalytic mechanism for the hybrid g-C3N4/MoS2 nanocomposite. J Mater Chem A 2:7960–7966

    Google Scholar 

  74. Ji Y, Dong H, Lin H, Zhang L, Hou T, Li Y (2016) Heptazine-based graphitic carbon nitride as an effective hydrogen purification membrane. RSC Adv 6:52377–52383

    Google Scholar 

  75. Wirth J, Neumann R, Antonietti M, Saalfrank P (2014) Adsorption and photocatalytic splitting of water on graphitic carbon nitride: a combined first principles and semiempirical study. PhysChemChemPhys 16:15917–15926

    Google Scholar 

  76. Hua E, Liu G, Zhang G, Xu X (2018) In situ fabrication of two-dimensional g-C3N4/Ba5Ta4O15 nanosheet heterostructures with efficient charge separations and photocatalytic hydrogen evolution under visible light illumination. Dalt Trans 47:4360–4367

    Google Scholar 

  77. Adekoya DO, Tahir M, Aishah N, Amin S (2017) g-C3N4/(Cu/TiO2) nanocomposite for enhanced photoreduction of CO2 to CH3 OH and HCOOH under UV/visible light. J CO2 Util 18:261–274

    Google Scholar 

  78. Huang J, Ho W, Wang X (2014) Metal-free disinfection effects induced by graphitic carbon nitride polymers under visible light illumination. Chem Commun 50:4338–4340

    Google Scholar 

  79. Xu J, Wang Z, Zhu Y (2017) Enhanced visible-light-driven photocatalytic disinfection performance and organic pollutant degradation activity of porous g-C3N4 nanosheets. ACS Appl Mater Interfaces 9:27727–27735

    Google Scholar 

  80. Kang S, Huang W, Zhang L et al (2018) Moderate bacterial etching allows scalable and clean delamination of g-C3N4 with enriched unpaired electrons for highly improved photocatalytic water disinfection. Appl Mater Interfaces 10:13796–13804

    Google Scholar 

  81. Zhao H, Yu H, Quan X et al (2014) Fabrication of atomic single layer graphitic-C3N4 and its high performance of photocatalytic disinfection under visible light irradiation. Appl Catal B Environ 152–153:46–50

    Google Scholar 

  82. Li Y, Zhang C, Shuai D et al (2016) Visible-light-driven photocatalytic inactivation of MS2 by metal-free g-C3N4: virucidal performance and mechanism. Water Res 106:249–258

    Google Scholar 

  83. Zhang C, Li Y, Zhang W et al (2018) Metal-free virucidal effects induced by g-C3N4 under visible light irradiation: statistical analysis and parameter optimization. Chemosphere 195:551–558

    Google Scholar 

  84. Patra KK, Gopinath CS (2016) Bimetallic and plasmonic Ag–Au on TiO2 for solar water splitting: an active nanocomposite for entire visible-light-region absorption. ChemCatChem 8:1–9

    Google Scholar 

  85. Zhang Q, Gangadharan DT, Liu Y et al (2016) Recent advancements in plasmon-enhanced visible light-driven water splitting. J Materiomics 3:33–34

    Google Scholar 

  86. Li S, Zhang J, Kibria MG, Mi Z, Chaker M, Ma D, Nechache R, Rosei F (2013) Remarkably enhanced photocatalytic activity of laser ablated Au nanoparticle decorated BiFeO3 nanowires under visible-light. Chem Commun 49:5856–5858

    Google Scholar 

  87. Xue J, Ma S, Zhou Y et al (2015) Facile photochemical synthesis of Au/Pt/g-C3N4 with plasmon-enhanced photocatalytic activity for antibiotic degradation. ACS Appl Mater Interfaces 7:9630–9637

    Google Scholar 

  88. Qin J, Huo J et al (2015) Improving photocatalytic hydrogen production of Ag/g-C3N4 nanocomposites by dye-sensitization under visible light irradiation. Nanoscale 8:2249–2259

    Google Scholar 

  89. Bing W, Chen Z, Sun H et al (2015) Visible-light-driven enhanced antibacterial and bio film elimination activity of graphitic carbon nitride by embedded Ag nanoparticles. Nano Res 8:1648–1658

    Google Scholar 

  90. Ma S, Zhan S, Jia Y et al (2016) Enhanced disinfection application of Ag-modified g-C3N4 composite under visible light. Appl Catal B Environ 186:77–87

    Google Scholar 

  91. Xu J, Gao Q, Bai X et al (2019) Enhanced visible-light-induced photocatalytic degradation and disinfection activities of oxidized porous g-C3N4 by loading Ag nanoparticles. Catal Today 332:227–235

    Google Scholar 

  92. Liu C, Wang L, Xu H et al (2016) one pot green synthesis and the antibacterial activity of g-C3N4/Ag nanocomposites. Mater Lett 164:567–570

    Google Scholar 

  93. Muñoz-Batista MJ, Fontelles-Carceller O, Ferrer M et al (2016) Disinfection capability of Ag/g-C3N4 composite photocatalysts under UV and visible light illumination. Appl Catal B Environ 183:86–95

    Google Scholar 

  94. Wang Z, Dong K, Liu Z et al (2016) Activation of biologically relevant levels of reactive oxygen species by Au/g-C3N4 hybrid nanozyme for bacteria killing and wound disinfection. Biomaterials 113:145–157

    Google Scholar 

  95. Wang W, Li G, An T, Chan DKL, Yu JC, Wong PK (2018) Photocatalytic hydrogen evolution and bacterial inactivation utilizing sonochemical-synthesized g-C3N4/red phosphorus hybrid nanosheets as a wide-spectral-responsive photocatalyst: the role of type I band alignment. Appl Catal B Environ 238:126–135

    Google Scholar 

  96. Li G, Nie X, Chen J et al (2015) Enhanced visible-light-driven photocatalytic inactivation of E. coli using g-C3N4/TiO2 hybrid photocatalyst synthesized using a hydrothermal-calcination approach. Water Res 86:17–24

    Google Scholar 

  97. Xu J, Li Y, Zhou X et al (2016) Graphitic C3N4-sensitized TiO2 nanotube layers: a visible-light activated efficient metal-free antimicrobial platform. Chem Eur J 22:3947–3951

    Google Scholar 

  98. Zhang Q, Quan X, Wang H et al (2017) Constructing a visible-light-driven photocatalytic membrane by g-C3N4 quantum dots and TiO2 nanotube array for enhanced water treatment. Sci Rep 7:3128

    Google Scholar 

  99. Liu Y, Zeng X, Hu X et al (2018) Two-dimensional g-C3N4/TiO2 nanocomposites as vertical Z-scheme heterojunction for improved photocatalytic water disinfection. Catal Today. https://doi.org/10.1016/j.cattod.2018.11.053

    Google Scholar 

  100. Li J, Yin Y, Liu E et al (2017) In situ growing Bi2MoO6 on g-C3N4 nanosheets with enhanced photocatalytic hydrogen evolution and disinfection of bacteria under visible light irradiation. J Hazard Mater 321:183–192

    Google Scholar 

  101. Xia D, Wang W, Yin R et al (2017) Enhanced photocatalytic inactivation of Escherichia coli by a novel Z-scheme g-C3N4/m-Bi2O4 hybrid photocatalyst under visible light: the role of reactive oxygen species. Appl Catal B Environ 214:23–33

    Google Scholar 

  102. Deng J, Liang J, Li M, Tong M (2017) Enhanced visible-light-driven photocatalytic bacteria disinfection by g-C3N4-AgBr. Colloids Surf B Biointerfaces 152:49–57

    Google Scholar 

  103. Li Y, Li Y, Ma S et al (2017) Efficient water disinfection with Ag2WO4-doped mesoporous g-C3N4 under visible light. J Hazard Mater 338:33–46

    Google Scholar 

  104. Wang R, Kong X, Zhang W et al (2018) Mechanism insight into rapid photocatalytic disinfection of Salmonella based on vanadate QDs-interspersed g-C3N4 heterostructures. Appl Catal B Environ 225:228–237

    Google Scholar 

  105. Wang AW, An T, Li G, Xia D (2017) Earth-abundant Ni2P/g-C3N4 lamellar nanohydrids for enhanced photocatalytic hydrogen evolution and bacterial inactivation under visible light irradiation. Appl Catal B Environ 217:570–580

    Google Scholar 

  106. Vidyasagar D, Ghugal SG, Kulkarni A, Shende AG, Umare SS, Sasikala R (2018) Microwave assisted in situ decoration of g-C3N4 surface with CdCO3 nanoparticles for visible light driven photocatalysis. New J Chem 42:6322–6331

    Google Scholar 

  107. Sundaram IM, Kalimuthu S, Ponniah GP (2017) Highly active ZnO modified g-C3N4 nanocomposite for dye degradation under UV and visible light with enhanced stability and antimicrobial activity. Compos Commun 5:64–71

    Google Scholar 

  108. Ong W (2017) 2D/2D graphitic carbon nitride nanocomposites for photocatalysis: why does face-to-face interface. Front Mater 4:1–10

    Google Scholar 

  109. Sun L, Du T, Hu C et al (2017) Antibacterial activity of graphene oxide/g-C3N4 composite through photocatalytic disinfection under visible light. ACS Sustain Chem Eng 5:8693–8701

    Google Scholar 

  110. Wang W, Yu JC, Xia D et al (2013) Graphene and g-C3N4 nanosheets cowrapped elemental α-sulfur as a novel metal-free heterojunction photocatalyst for bacterial inactivation under visible-light. Environ Sci Technol 47:8724–8732

    Google Scholar 

  111. Ouyang K, Dai K, Chen H et al (2017) Metal-free inactivation of E. coli O157:H7 by fullerene/C3N4 hybrid under visible light irradiation. Ecotoxicol Environ Saf 136:40–45

    Google Scholar 

  112. Zhang C, Li Y, Shuai D et al (2018) Visible-light-driven, water-surface-floating antimicrobials developed from graphitic carbon nitride and expanded perlite for water disinfection. Chemosphere 208:84–92

    Google Scholar 

  113. Adhikari SPAGP, Lee J, Park CH, Kim CS (2016) Synthesis, characterization, organic compound degradation activity and antimicrobial performance of g-C3N4 sheets customized with metal nanoparticle-decorated TiO2 nanofibers. RSC Adv 6:55079–55091

    Google Scholar 

  114. Joo H, Chan K, Park H, Sang C (2015) One pot synthesis and characterization of Ag-ZnO/g-C3N4 photocatalyst with improved photoactivity and antibacterial properties. Colloids Surf A 482:477–484

    Google Scholar 

  115. Pant B, Park M, Lee JH et al (2017) Novel magnetically separable silver-iron oxide nanoparticles decorated graphitic carbon nitride nano-sheets: a multifunctional photocatalyst via one-step hydrothermal process. J Colloid Interface Sci 496:343–352

    Google Scholar 

  116. Vidyasagar D, Ghugal SG, Kulkarni A et al (2018) Silver/Silver(II) oxide (Ag/AgO) loaded graphitic carbon nitride microspheres: an effective visible light active photocatalyst for degradation of acidic dyes and bacterial inactivation. Appl Catal B Environ 221:339–348

    Google Scholar 

  117. Zhang M, Liu Z, Gao Y, Shu L (2017) Ag modified g-C3N4 composite entrapped PES UF membrane with visible-light-driven photocatalytic antifouling performance. RSC Adv 7:42919–42928

    Google Scholar 

  118. Zeng X, Lan S, Lo IMC (2019) Rapid disinfection of E. coli by ternary BiVO4/Ag/g-C3N4 composite under visible light: photocatalysis mechanism and performance investigation in authentic sewage. Environ Sci 6:610–623

    Google Scholar 

  119. Lin AT, Son Z, Wu Y et al (2018) Boron- and phenyl-codoped graphitic carbon nitride with greatly enhanced light responsive range for photocatalytic disinfection. J Hazard Mater 358:62–68

    Google Scholar 

  120. Liu B, Han X, Wang Y et al (2018) Synthesis of g-C3N4/BiOI/BiOBr heterostructures for efficient visible-light-induced photocatalytic and antibacterial activity. J Mater Sci Mater Electron 29:14300–14310

    Google Scholar 

  121. Younis SA, Abd-Elaziz A, Hashem A (2016) Utilization of a pyrrole derivative based antimicrobial functionality impregnated onto CaO/g-C3N4 for dyes adsorption. RSC Adv 6:89367–89379

    Google Scholar 

  122. Zhao H, Chen S, Quan X et al (2016) Environmental integration of microfiltration and visible-light-driven photocatalysis on g-C3N4 nanosheet/reduced graphene oxide membrane for enhanced water treatment. Appl Catal B Environ 194:134–140

    Google Scholar 

  123. Tian Y, Zhou F, Zhan S et al (2018) Mechanisms on the enhanced sterilization performance of fluorocarbon resin composite coatings modi fi ed by −C3N4/Bi2MoO6 under the visible-light. J Photochem Photobiol A Chem 350:10–16

    Google Scholar 

  124. Faraji M, Mohaghegh N, Abedini A (2017) Ternary composite of TiO2 nanotubes/Ti plates modified by g-C3N4 and SnO2 with enhanced photocatalytic activity for enhancing antibacterial and photocatalytic activity. J Photochem Photobiol B Biol 178:124–132

    Google Scholar 

  125. Li C, Sun Z, Zhang W et al (2017) Highly efficient g-C3N4/TiO2/kaolinite composite with novel three-dimensional structure and enhanced visible light responding ability towards ciprofloxacin and S. aureus. Appl Catal B Environ 220:272–282

    Google Scholar 

  126. Song AJ, Wang X, Ma J (2017) Visible-light-driven in situ inactivation of Microcystis aeruginosa with the use of floating g-C3N4 heterojunction photocatalyst: performance, mechanisms and implications. Appl Catal B Environ 226:83–92

    Google Scholar 

  127. Song J, Wang X, Ma J et al (2018) Removal of microcystis aeruginosa and microcystin-LR using a graphitic-C3N4/TiO2 floating photocatalyst under visible light irradiation. Chem Eng J 348:380–388

    Google Scholar 

  128. Wang X, Wang X, Zhao J et al (2018) Adsorption-photocatalysis functional expanded graphite C/C composite for in situ photocatalytic inactivation of Microcystis aeruginosa. Chem Eng J 341:516–525

    Google Scholar 

  129. Niu P, Yang Y, Yu JC et al (2014) Switching the selectivity of the photoreduction reaction of carbon dioxide by controlling the band structure of a g-C3N4 photocatalyst. Chem Commun 50:10837

    Google Scholar 

  130. Su Q, Sun J, Wang J et al (2014) Urea-derived graphitic carbon nitride as an efficient heterogeneous catalyst for CO2 conversion into cyclic carbonates. Catal Sci Technol 4:1556

    Google Scholar 

  131. Wang H, Sun Z, Li Q et al (2016) Surprisingly advanced CO2 photocatalytic conversion over thiourea derived g-C3N4with water vapor while introducing 200–420 nm UV light. J CO2 Util 14:143–151

    Google Scholar 

  132. Tahir B, Tahir M, Amin NAS (2017) Photo-induced CO2 reduction by CH4/H2O to fuels over Cu-modified g-C3N4 nanorods under simulated solar energy. Appl Surf Sci 419:875–885

    Google Scholar 

  133. Tang JY, Zhou WG, Guo RT, Huang CY, Pan WG (2018) Enhancement of photocatalytic performance in CO2 reduction over Mg/g-C3N4 catalysts under visible light irradiation. Catal Commun 10(107):92–95

    Google Scholar 

  134. Wang Y, Xu Y, Wang Y et al (2016) Synthesis of Mo-doped graphitic carbon nitride catalysts and their photocatalytic activity in the reduction of CO2 with H2O. Catal Commun 74:75–79

    Google Scholar 

  135. Wang K, Li Q, Liu B et al (2015) Sulfur-doped g-C3N4 with enhanced photocatalytic CO2-reduction performance. Appl Catal B Environ 176–177:44–52

    Google Scholar 

  136. Yuan YP, Cao SW, Sen LY et al (2013) Red phosphor/g-C3N4 heterojunction with enhanced photocatalytic activities for solar fuels production. Appl Catal B Environ 140–141:164–168

    Google Scholar 

  137. Kuriki R, Sekizawa K, Ishitani O, Maeda K (2015) Visible-light-driven CO2 reduction with carbon nitride: enhancing the activity of ruthenium catalysts. Angew Chem Int Ed 54:1–5

    Google Scholar 

  138. Ong W, Putri LK, Tan Y et al (2017) Unravelling charge carrier dynamics in protonated g-C3N4 interfaced with carbon nanodots as co-catalysts toward enhanced photocatalytic CO2 reduction: a combined experimental and first-principles DFT study. Nano Res 10:1673–1696

    Google Scholar 

  139. Photocatalysis L (2018) g-C3N4-based nanomaterials for visible light-driven photocatalysis. Catalyst 8:74

    Google Scholar 

  140. Sun Z, Wang H, Wu Z, Wang L (2018) g-C3N4 based composite photocatalysts for photocatalytic CO2 reduction. Catal Today 300:160–172

    Google Scholar 

  141. Zeng D, Zhou T, Ong W et al (2019) Sub-5 nm ultra-fine FeP nanodots as efficient co-catalysts modified porous g-C3N4 for precious-metal-free photocatalytic hydrogen evolution under visible light. ACS Appl Mater Interfaces 11:5651–5660

    Google Scholar 

  142. Zeng D, Ong W, Chen Y et al (2018) Co2P nanorods as an efficient cocatalyst decorated porous g-C3N4 Nanosheets for photocatalytic hydrogen production under visible light irradiation. Part Part Syst Charact 35:1700251

    Google Scholar 

  143. Zeng D, Wu P, Ong W et al (2018) Construction of network-like and flower-like 2H-MoSe2 nanostructures coupled with porous g-C3N4 for noble-metal-free photocatalytic H2 evolution under visible light. Appl Catal B Environ 233:26–34

    Google Scholar 

  144. Ye S, Wang R, Wu M, Yuan Y (2015) A review on g-C3N4 for photocatalytic water splitting and CO2 reduction. Appl Surf Sci 358:15–27

    Google Scholar 

  145. Liu J, Jia Q, Long J et al (2017) Amorphous NiO as co-catalyst for enhanced visible-light-driven hydrogen generation over g-C3N4 photocatalyst. Appl Catal B Environ 222:35–43

    Google Scholar 

  146. Zhou X, Luo Z, Tao P et al (2014) Facile preparation and enhanced photocatalytic H2-production activity of Cu(OH)2 nanospheres modified porous g-C3N4. Mater Chem Phys 143:1462–1468

    Google Scholar 

  147. Li F, Liu S, Xue Y et al (2015) Structure Modification Function of g-C3N4 for Al2O3 in the in situ hydrothermal process for enhanced photocatalytic activity. Chem Eur J 21:10149–10159

    Google Scholar 

  148. Ji C, Du C, Steinkruger JD et al (2019) In-situ hydrothermal fabrication of CdS/g-C3N4 nanocomposites for enhanced photocatalytic water splitting. Mater Lett 240:128–131

    Google Scholar 

  149. Naseri A, Samadi M, Pourjavadi A et al (2017) Recent advances and future development directions. J Mater Chem A Mater energy Sustain 5:23406–23433

    Google Scholar 

  150. Cui W, Li J, Dong F et al (2017) Highly efficient performance and conversion pathway of photocatalytic NO oxidation on SrO-clusters @ amorphous carbon nitride highly efficient performance and conversion pathway of photocatalytic NO oxidation on SrO-clusters @ amorphous carbon nitride. Environ Sci Technol 51:10682–10690

    Google Scholar 

  151. Li AJ, Dong X, Sun Y (2018) Tailoring the rate-determining step in photocatalysis via localized excess electrons for efficient and safe air cleaning. Appl Catal B Environ 239:187–195

    Google Scholar 

  152. Li J, Dong X, Sun Y, Jiang G, Chu Y, Lee SC, Dong F (2018) Tailoring the rate-determining step in photocatalysis via localized excess electrons for efficient and safe air cleaning. Appl Catal B Environ 232:69–76

    Google Scholar 

  153. Chen P, Dong F, Ran M, Li J (2018) Synergistic photo-thermal catalytic NO purification of MnOx/g-C3N4: enhanced performance and reaction mechanism. Chin J Catal 39:619–629

    Google Scholar 

  154. Chen X, Zhao X, Kong Z, Ong WJ, Li N (2018) Unravelling the electrochemical mechanisms for nitrogen fixation on single transition metal atom embedded in defective graphitic carbon nitride. J Mater Chem A 6:21941–21948

    Google Scholar 

  155. Xu Y, Niu X, Zhang H et al (2015) Switch-on fluorescence sensing of glutathione in food samples based on a g-CNQDs-Hg2 + chemosensor. J Agric Food Chem 1(63):1747–1755

    Google Scholar 

  156. Zhan Y, Liu Z, Liu Q, Huang D, Wei Y, Hu Y, Lian X, Hu C (2017) A facile and one-pot synthesis of fluorescent graphitic carbon nitride quantum dots for bio-imaging application. New J Chem 41:3930–3938

    Google Scholar 

  157. Ong W, Tan L, Ng YH et al (2016) Graphitic carbon nitride (g-C3N4)-based photocatalysts for artificial photosynthesis and environmental remediation: are we a step closer to achieving sustainability? Chem Rev 116:7159–7329

    Google Scholar 

  158. Zhu B, Zhang L, Cheng B, Yu J (2017) First-principle calculation study of tri-s-triazine-based g-C3N4: a review. Appl Catal B Environ 224:983–999

    Google Scholar 

  159. Xu Y, Gao S (2012) Band gap of C3N4 in the GW approximation. Int J Hydrogen Energy 37:11072–11080

    Google Scholar 

  160. Teter DM, Hemley RJ (2019) Low-compressibility carbon nitrides. Science (80-) 271:53–55

    Google Scholar 

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Murugesan, P., Moses, J.A. & Anandharamakrishnan, C. Photocatalytic disinfection efficiency of 2D structure graphitic carbon nitride-based nanocomposites: a review. J Mater Sci 54, 12206–12235 (2019). https://doi.org/10.1007/s10853-019-03695-2

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