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Journal of Materials Science

, Volume 53, Issue 19, pp 13790–13800 | Cite as

Improved extraction of cobalt and lithium by reductive acid from spent lithium-ion batteries via mechanical activation process

  • Yaoguang Guo
  • Yaguang Li
  • Xiaoyi Lou
  • Jie Guan
  • Yingshun Li
  • Xianmin Mai
  • Hu Liu
  • Cindy Xinxin Zhao
  • Ning Wang
  • Chao Yan
  • Guilan Gao
  • Hao Yuan
  • Jue Dai
  • Ruijng Su
  • Zhanhu Guo
Mechanochemical Synthesis

Abstract

Cobalt (Co) and lithium (Li) were extracted from pure LiCoO2 powders and actual cathode material powders from the spent lithium-ion batteries (LIBs) after l-ascorbic acid dissolution via a mechanical activation process. The influences of activation time and rotation speed on the leaching were discussed. The mechanism of the improved leaching yield was proposed based on the characterization analysis including X-ray diffraction, scanning electron microscope, BET-specific surface area and particle size analyzer. The reduced particle size, increased specific surface area of activated samples, destroyed crystal structure and amorphous state of LiCoO2 contributed to the improved leaching efficiencies of Co and Li. With the activated process, about 99% Co and 100% Li were extracted from actual spent LIBs after 60-min grinding at 500 rpm with mild conditions. This effective process would be of great importance for recovering valuable metals from the spent LIBs at room temperature.

Notes

Acknowledgements

We gratefully appreciate the financial support from Shanghai “Chenguang” Program (15CG60), Shanghai Sailing Program (18YF1429900, 15YF1404300), Natural Science Foundation of China (51678353), Shanghai Natural Science Foundation (No. 15ZR1416800), Cultivate discipline fund of Shanghai Polytechnic University (XXKPY1601) and Eastern Scholar Professorship Grant. The authors also acknowledge the Graduate Student Funding Program of Shanghai Polytechnic University (A01GY16F030), Shanghai Polytechnic University Leap Program (EGD18XQD24), and project supported by Shanghai Cooperative Centre for WEEE Recycling (ZF1224).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10853_2018_2229_MOESM1_ESM.docx (4 mb)
Supplementary material 1 (DOCX 4076 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Environmental and Materials EngineeringShanghai Polytechnic UniversityShanghaiPeople’s Republic of China
  2. 2.Shanghai Waigaoqiao Bonded Area Environmental Services Co., Ltd.ShanghaiPeople’s Republic of China
  3. 3.Key Laboratory of Control of Quality and Safety for Aquatic Products, Ministry of Agriculture, East China Sea Fisheries Research InstituteChinese Academy of Fishery SciencesShanghaiPeople’s Republic of China
  4. 4.Shanghai Pudong Shuguang Research Center for High Environmental Treatment TechnologiesShanghaiPeople’s Republic of China
  5. 5.Shanghai Xin Jinqiao Environmental Protection Co., Ltd.ShanghaiPeople’s Republic of China
  6. 6.School of Urban Planning and ArchitectureSouthwest Minzu UniversityChengduPeople’s Republic of China
  7. 7.National Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhouPeople’s Republic of China
  8. 8.Integrated Composites Laboratory (ICL), Department of Chemical and Bimolecular EngineeringUniversity of TennesseeKnoxvilleUSA
  9. 9.State Key Laboratory of Marine Resource Utilization in South China SeaHainan UniversityHaikouPeople’s Republic of China
  10. 10.School of Material Science and EngineeringJiangsu University of Science and TechnologyZhenjiangPeople’s Republic of China

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