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Cobalt extraction from spent lithium-ion battery cathode material using a sulfuric acid solution containing SO2

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Abstract

To increase the degree of cobalt (Co) extraction, the process of the cathode material leaching was performed in a sulfuric acid (H2SO4) solution containing sulfur dioxide (SO2) as a reducing agent. To provide a high resolution of the obtained results, frequent monitoring of Co concentrations in leached solution was conducted using an ultraviolet–visible spectrophotometer with several specific modifications related to the connection of the reaction vessel with the instrumental cuvette. The maximum degree of Co leaching (99.4%) was achieved with H2SO4 concentration of 3 mol/L, solid phase concentration of 33 g/L, temperature of 85 °C, SO2 volume flow of 2 L/min, and leaching time of 60 min. The results of the performed kinetic analyses indicated that the Avrami equation best describes the investigated leaching process, which later was supported by the results of X-ray diffraction and scanning electron microscopy–energy-dispersive X-ray spectroscopy analyses. Also, the activation energy of 28 ± 3 kJ/mol is in favor of the fact that the process of Co leaching was controlled by the factors, such as diffusion and chemical reaction. The results of this study indicated that SO2 can be used as an effective reducing agent in the investigated process.

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Acknowledgements

The research presented in this paper was done with the financial support of the Ministry of Education, Science and Technological Development of the Republic of Serbia, within the funding of the scientific research work at the University of Belgrade, Technical Faculty in Bor, according to the contract number 451-03-68/2022-14/200131, and within the funding of the scientific research work at the Mining and Metallurgy Institute Bor, according to the contract number 451-03-68/2022-14/200052.

Funding

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja, grant number 451-03-68/2022-14/200131, Dragana Medic, Maja Nujkić, Snežana Milić and Slađana Alagić, grant number 451-03-68/2022-14/200052 Stefan Đorđievski.

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Authors and Affiliations

  1. Technical Faculty in Bor, University of Belgrade, Bor, Serbia

    Dragana V. Medić, Maja M. Nujkić, Snežana M. Milić, Slađana Č. Alagić & Milan M. Antonijević

  2. Institute for Technology of Nuclear and Other Mineral Raw Materials, Belgrade, Serbia

    Miroslav D. Sokić

  3. Mining and Metallurgy Institute Bor, Bor, Serbia

    Stefan S. Đorđievski

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  1. Dragana V. Medić
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Medić, D.V., Sokić, M.D., Nujkić, M.M. et al. Cobalt extraction from spent lithium-ion battery cathode material using a sulfuric acid solution containing SO2. J Mater Cycles Waste Manag 25, 1008–1018 (2023). https://doi.org/10.1007/s10163-022-01580-w

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