Abstract
A SiO2 particle was prepared with different alkali sources, and then lamellar-stacked TS-1 catalysts were hydrothermally synthesized using the SiO2 particle as a silica source. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectra, nitrogen adsorption–desorption and UV–vis absorption spectra were used to characterize the TS-1 catalysts. The effect of the alkali source during the preparation of the SiO2 particle on the textural properties and catalytic performance of the TS-1 catalyst was thoroughly investigated. The TS-1 catalyst that was prepared with a SiO2 particle using tetrapropylammonium hydroxide (TPAOH) as an alkali source (TS-1-TPAOH) possessed more meso- and macro-pores and a higher framework Ti content than the catalyst that was prepared with a SiO2 particle using NH3·H2O as an alkali source (TS-1-NH3·H2O). As a result, the TS-1-TPAOH catalyst had a better catalytic performance for butanone ammoximation with H2O2 than conventional TS-1 and TS-1-NH3·H2O catalysts. Furthermore, the influences of reaction conditions, including reaction temperature, reaction time, the amount of catalyst and the molar ratio between H2O2 and butyl ketone oxime on the catalytic performance of the TS-1-TPAOH catalyst were evaluated. The unique structure of the lamellar-stacked TS-1 catalyst can effectively avoid the diffusing of large reactant molecules into zeolite channels and has potential applications in other oxidation reactions.
Similar content being viewed by others
References
Kong L, Gang L, Wang X (2004) Catal Today 93–95:341–345
Xia QH, Gao Z (1997) Mater Chem Phys 47:225–230
Corma A (2003) J Catal 216:298–312
Cheng W, Wang X, Li G, Guo X, Zhang S (2008) J Catal 255:343–346
Yang G, Wei Y, Xu S, Chen J, Li J, Liu Z, Yu J, Xu R (2013) J Phys Chem C 117:8214–8222
Fan W, Duan RG, Yokoi T, Wu P, Kubota Y, Tatsumi T (2008) J Am Chem Soc 130:10150–10164
Li YG, Lee YM, Porter JF (2002) J Mater Sci 37:1959–1965. https://doi.org/10.1023/A:1015234812360
Serrano DP, Sanz R, Pizarro P, Moreno I, Medina S (2014) Appl Catal B Environ 146:35–42
Zuo Y, Song W, Dai C, He Y, Wang M, Wang X, Guo X (2013) Appl Catal A Gen 453:272–279
Liu C, Huang J, Sun D, Zhou Y, Jing X, Du M, Wang H, Li Q (2013) Appl Catal A Gen 459:1–7
Tosheva L, Valtchev VP (2005) Chem Mater 17:2494–2513
Yip ACK, Hu X (2009) Ind Eng Chem Res 48:8441–8450
Chen L, Wang YM, He MY (2011) Mater Res Bull 46:698–701
Kwon S, Schweitzer NM, Park S, Stair PC, Snurr RQ (2015) J Catal 326:107–115
Huang DG, Zhang X, Liu TW, Huang C, Chen BH, Luo CW, Ruckenstein E, Chao ZS (2013) Ind Eng Chem Res 52:3762–3772
Xia LZ, Li P, Guo XW, Wang XS, Xu SQ (2006) Acta Petrol Sin Petrol Proc Sec 22:72–77
Fang Y, Hu H (2007) Catal Commun 8:817–820
Yue MB, Sun MN, Xie F, Ren DD (2014) Microporous Mesoporous Mater 183:177–184
Moller K, Yilmaz B, Jacubinas RM, Muller U, Bein T (2011) J Am Chem Soc 133:5284–5295
Kustova MY, Hasselriis P, Christensen CH (2004) Catal Lett 96:205–211
Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger RJ, Chmelka BF, Ryoo R (2011) Science 333:328
Wang W, Li G, Liu L, Chen Y (2013) Microporous Mesoporous Mater 179:165–171
Wu M, Liu X, Wang Y, Guo Y, Guo Y, Lu G (2014) J Mater Sci 49:4341–4348. https://doi.org/10.1007/s10853-014-8130-6
Zhang T, Zuo Y, Liu M, Song C, Guo X (2016) ACS Omega 1:1034–1040
Wang Y, Lin M, Tuel A (2007) Microporous Mesoporous Mater 102:80–85
Na K, Jo C, Kim J, Ahn WS, Ryoo R (2011) ACS Catal 1:901–907
Wang J, Xu L, Zhang K, Peng H, Wu H, Jiang JG, Liu Y, Wu P (2012) J Catal 288:16–23
Thangaraj A, Eapen MJ, Sivasanker S, Ratnasamy P (1992) Zeolites 12:943–950
Ke X, Xu L, Zeng C, Zhang L, Xu N (2007) Microporous Mesoporous Mater 106:68–75
Orlov A, Zhai QZ, Klinowski J (2006) J Mater Sci 41:2187–2193. https://doi.org/10.1007/s10853-006-7184-5
Kumar P, Gupta JK, Muralidhar G, Rao TSRP (1998) Stud Surf Sci Catal 113:463–472
Gregg SJ, Sing KSW (1982) Adsorption surface area and porosity. Academic Press, London
Li C, Xiong G, Liu J, Ying P, Xin Q, Feng Z (2001) J Phys Chem B 105:2993–2997
Guo Q, Feng Z, Li G, Fan F, Li C (2013) J Phys Chem C 117:2844–2848
Jorda E, Tuel A, Teissier R, Kervennal J (1997) Zeolites 19:238–245
Geobaldo F, Bordiga S, Zecchina A, Giamello E, Leofanti G, Petrini G (1992) Catal Lett 16:109–115
Thangaraj A, Sivasanker S, Ratnasamy P (1991) J Catal 131:394–400
Zecchina A, Spoto G, Bordiga S, Geobaldo F, Petrini G, Leofanti G, Padovan M, Mantegazza M, Roffia P (1993) Stud Surf Sci Catal 75:719–729
Gao HX, Shu ZB (1998) Chin J Catal 19:329–333
Sirijaraensre J, Limtrakul J (2013) Phys Chem Chem Phys 15:18093–18100
Acknowledgements
This project was financially supported by the Fundamental Research Funds for the Central Universities (222201717003).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, W., Fu, Y., Guo, Y. et al. Preparation of lamellar-stacked TS-1 and its catalytic performance for the ammoximation of butanone with H2O2 . J Mater Sci 53, 4034–4045 (2018). https://doi.org/10.1007/s10853-017-1825-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-017-1825-8