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Controlled synthesis of carbon nanofibers over electrolessly plated metal foam catalysts on polyurethane for fuel cell applications

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Abstract

Synthesis of carbon nanofibers (CNFs) with different morphologies has attracted great attentions due to their broad energy applications. Chemical vapor deposition (CVD) method is often employed to produce CNFs, and the morphology of the resulting CNFs is largely dependent on the catalysts used in this process. In this work, 3-D ordered polyurethane foam has been electrolessly plated with a layer of nickel catalysts, which are then used to catalytically decompose acetylene to yield CNFs via CVD. Catalysts with different compositions (nickel, cobalt, copper or their alloys) can be made through changes in the electroless plating baths and then used to synthesize CNFs with different morphologies. The as-prepared CNFs synthesized in this work can be used directly as supports for fuel cell electrocatalysts. The method reported in this work offers a general protocol to synthesize a wide variety of carbon filaments with tailored compositions and properties.

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References

  1. Vinayan BP, Nagar R, Ramaprabhu RS (2012) Synthesis and investigation of mechanism of platinum–graphene electrocatalysts by novel co-reduction techniques for proton exchange membrane fuel cell applications. J Mater Chem 22:25325–25334

    Article  Google Scholar 

  2. Şanlı LI, Yarar B, Bayram V, Gürsel SA (2017) Electrosprayed catalyst layers based on graphene–carbon black hybrids for the next-generation fuel cell electrodes. J Mater Sci 52:2091–2102

    Article  Google Scholar 

  3. Li S, Liu H, Wang XuYW, Li L, Liu Y, Guo X, Song Y (2015) Controlled synthesis of high metal-loading, Pt-based electrocatalysts with enhanced activity and durability toward oxygen reduction reaction. RSC Adv 5:8787–8792

    Article  Google Scholar 

  4. Guo L, Jiang WJ, Zhang Y, Hu JS, Wei ZD, Wan LJ (2015) Embedding Pt nanocrystals in N-doped porous carbon/carbon nanotubes toward highly stable electrocatalysts for the oxygen reduction reaction. ACS Catal 5:2903–2909

    Article  Google Scholar 

  5. Li L, Hu L, Li J, Wei Z (2015) Enhanced stability of Pt nanoparticle electrocatalysts for fuel cells. Nano Res 8:418–440

    Article  Google Scholar 

  6. Chu YY, Wang ZB, Jiang ZZ, Gu DM, Yin GP (2012) Facile synthesis of hollow spherical sandwich PtPd/C catalyst by electrostatic self-assembly in polyol solution for methanol electrooxidation. J Power Sources 203:17–25

    Article  Google Scholar 

  7. Kim SH, Lee TK, Jung JH, Park JN, Kim JB, Hur SH (2012) Catalytic performance of acid-treated multi-walled carbon nanotube-supported platinum catalyst for PEM fuel cells. Mater Res Bull 47:2760–2764

    Article  Google Scholar 

  8. Chen J, Siegel JB, Matsuura T, Stefanopoulou AG (2011) Carbon corrosion in PEM fuel cell dead-ended anode operations. J Electrochem Soc 158:B1164–B1174

    Article  Google Scholar 

  9. Linse N, Gubler L, Scherer GG, Wokaun A (2011) The effect of platinum on carbon corrosion behavior in polymer electrolyte fuel cells. Electrochim Acta 56:7541–7549

    Article  Google Scholar 

  10. DaŞ E, Yurtcan AB (2017) PEDOT/C composites used as pem fuel cell catalyst support: role of carbon amount. Energy Technol. doi:10.1002/ente.201600779

    Google Scholar 

  11. Kim SK, Park JY, Hwang SC, Lee DK, Lee SH, Han MH, Rhee YW (2014) Radiolytic preparation of electrocatalysts with Pt–Co and Pt–Sn nanoparticles for a proton exchange membrane fuel cell. J Nanomater 2014:1–8

    Google Scholar 

  12. Chen X, Jiang Y, Sun J, Jin C, Zhang Z (2014) Highly active nanoporous Pt-based alloy as anode and cathode catalyst for direct methanol fuel cells. J Power Sources 267:212–218

    Article  Google Scholar 

  13. Li B, Yan Z, Higgins DC, Yang D, Chen Z, Ma J (2014) Carbon-supported Pt nanowire as novel cathode catalysts for proton exchange membrane fuel cells. J Power Sources 262:488–493

    Article  Google Scholar 

  14. Zheng Y, Zhan H, Fang Y, Zeng J, Liu H, Yang J, Liao S (2017) Uniformly dispersed carbon-supported bimetallic ruthenium–platinum electrocatalysts for the methanol oxidation reaction. J Mater Sci 52:3457–3466

    Article  Google Scholar 

  15. Castanheira L, Dubau L, Mermoux M, Berthomé G, Caqué N, Rossinot E, Chatenet M, Maillard F (2014) Carbon corrosion in proton-exchange membrane fuel cells: from model experiments to real-life operation in membrane electrode assemblies. ACS Catal 4:2258–2267

    Article  Google Scholar 

  16. Han M, Li M, Wu X, Zeng J, Liao S (2015) Highly stable and active Pt electrocatalysts on TiO2–Co3O4–C composite support for polymer exchange membrane fuel cells. Electrochim Acta 154:266–272

    Article  Google Scholar 

  17. Xu J, Aili D, Li Q, Pan C, Christensen E, Jensen JO, Zhang W, Liu G, Wang X, Bjerrum NJ (2013) Antimony doped tin oxide modified carbon nanotubes as catalyst supports for methanol oxidation and oxygen reduction reactions. J Mater Chem A 1:9737–9745

    Article  Google Scholar 

  18. Guo J, Sun G, Wang Q, Wang G, Zhou Z, Tang S, Jiang L, Zhou B, Xin Q (2006) Carbon nanofibers supported Pt–Ru electrocatalysts for direct methanol fuel cells. Carbon 44:152–157

    Article  Google Scholar 

  19. Zhang J, Tang S, Liao L, Yu W, Li J, Seland F, Haarberg GM (2014) Improved catalytic activity of mixed platinum catalysts supported on various carbon nanomaterials. J Power Sources 267:706–713

    Article  Google Scholar 

  20. Tian ZQ, Jiang SP, Liang YM, Shen PK (2006) Synthesis and characterization of platinum catalysts on multiwalled carbon nanotubes by intermittent microwave irradiation for fuel cell applications. J Phys Chem B 110:5343–5350

    Article  Google Scholar 

  21. Wang H, Wang J, Zhong Q, Zhang G, Bu Y (2017) Mesoporous spinel nanofibers and nitrogen-doped carbon nanotubes as high-performance electrocatalyst for oxygen reduction in alkaline and neutral media. Energy Technol 5:283–292

    Article  Google Scholar 

  22. Ghosh S, Mondal S, Retna Raj C (2014) Carbon nanotube-supported dendritic Pt-on-Pd nanostructures: growth mechanism and electrocatalytic activity towards oxygen reduction reaction. J Mater Chem A 2:2233–2239

    Article  Google Scholar 

  23. Liu Z, Shi Q, Zhang R, Wang Q, Kang G, Peng F (2014) Phosphorus-doped carbon nanotubes supported low Pt loading catalyst for the oxygen reduction reaction in acidic fuel cells. J Power Sources 268:171–175

    Article  Google Scholar 

  24. Andersen SM, Borghei M, Lund P, Elina YR, Pasanen A, Kauppinen E, Ruiz V, Kauranen P, Skou EM (2013) Durability of carbon nanofiber (CNF) & carbon nanotube (CNT) as catalyst support for proton exchange membrane fuel cells. Solid State Ionics 231:94–101

    Article  Google Scholar 

  25. Wu X, Liu Z, Zeng J, Hou Z, Zhou W, Liao S (2017) Platinum nanoparticles on interconnected Ni3P/Carbon nanotube-carbon nanofiber hybrid supports with enhanced catalytic activity for fuel cells. ChemElectroChem 4:109–114

    Article  Google Scholar 

  26. Oh H-S, Kim H (2011) Efficient synthesis of Pt nanoparticles supported on hydrophobic graphitized carbon nanofibers for electrocatalysts using noncovalent functionalization. Adv Funct Mater 21:3954–3960

    Article  Google Scholar 

  27. Stamatin SN, Borghei M, Dhiman R, Andersen SM, Ruiz V, Kauppinen E, Skou EM (2015) Activity and stability studies of platinized multi-walled carbon nanotubes as fuel cell electrocatalysts. Appl Catal B 162:289–299

    Article  Google Scholar 

  28. Sebastian D, Suelves I, Moliner R, Lazaro MJ, Stassi A, Baglio V, Arico AS (2013) Optimizing the synthesis of carbon nanofiber based electrocatalysts for fuel cells. Appl Catal B 132:22–27

    Article  Google Scholar 

  29. Endo M, Kim YA, Ezaka M, Osada K, Yanagisawa T, Hayashi T, Terrones M, Dresselhaus MS (2003) Selective and efficient impregnation of metal nanoparticles on cup-stacked-type carbon nanofibers. Nano Lett 3:723–726

    Article  Google Scholar 

  30. Yuen CWM, Jiang SQ, Kan CW, Tung WS (2007) Influence of surface treatment on the electroless nickel plating of textile fabric. Appl Surf Sci 253:5250–5257

    Article  Google Scholar 

  31. Shacham-Diamand Y, Osaka T, Okinaka Y, Sugiyama A, Dubin V (2015) 30 years of electroless plating for semiconductor and polymer micro-systems. Microelectron Eng 132:35–45

    Article  Google Scholar 

  32. Domenech SC, Lima E, Drago V, De Lima JC, Borges NG, Avila AOV, Soldi V (2003) Electroless plating of nickel–phosphorous on surface-modified poly(ethylene terephthalate) films. Appl Surf Sci 220:238–250

    Article  Google Scholar 

  33. Cao M, Wu D, Cao R (2014) Recent advances in the stabilization of platinum electrocatalysts for fuel-cell reactions. ChemCatChem 6:26–45

    Article  Google Scholar 

  34. Jarrah NA, Li F, Ommen JGV, Lefferts L (2005) Immobilization of a layer of carbon nanofibres (CNFs) on Ni foam: a new structured catalyst support. J Mater Chem 15:1946–1953

    Article  Google Scholar 

  35. Huang W, Zhang XB, Tu J, Kong F, Ning Y, Xu J, Tendeloo GV (2002) Synthesis and characterization of graphite nanofibers deposited on nickel foams. Phys Chem Chem Phys 4:5325–5329

    Article  Google Scholar 

  36. Chinthaginjala JK, Lefferts L (2009) Influence of hydrogen on the formation of a thin layer of carbon nanofibers on Ni foam. Carbon 47:3175–3183

    Article  Google Scholar 

  37. Li M, Wu X, Zeng J, Hou Z, Liao S (2015) Heteroatom doped carbon nanofibers synthesized by chemical vapor deposition as platinum electrocatalyst supports for polymer electrolyte membrane fuel cells. Electrochim Acta 182:351–360

    Article  Google Scholar 

  38. Chang J, Feng L, Liu C, Xing W, Hu X (2014) An effective Pd–Ni2P/C anode catalyst for direct formic acid fuel cells. Angew Chem Int Ed 53:122–126

    Article  Google Scholar 

  39. Yang G, Chen Y, Zhou Y, Tang Y, Lu T (2010) Preparation of carbon supported Pd–P catalyst with high content of element phosphorus and its electrocatalytic performance for formic acid oxidation. Electrochem Commun 12:492–495

    Article  Google Scholar 

  40. Hou Z, Li M, Han M, Zeng J, Liao S (2014) Aqueous phase synthesis and characterizations of Pt nanoparticles by a modified citrate reduction method assisted by inorganic salt stabilization for PEMFCs. Electrochim Acta 134:187–192

    Article  Google Scholar 

  41. Yang W, Luo S, Zhang B, Huang Z, Tang X (2008) Electroless preparation and characterization of magnetic Ni–P plating on polyurethane foam. Appl Surf Sci 254:7427–7430

    Article  Google Scholar 

  42. Jeong N, Lee J (2008) Growth of filamentous carbon by decomposition of ethanol on nickel foam: Influence of synthesis conditions and catalytic nanoparticles on growth yield and mechanism. J Catal 260:217–226

    Article  Google Scholar 

  43. Liu T, Zhao L, Wang D, Zhu J, Wang B, Guo C (2013) Corrosion resistance of nickel foam modified with electroless Ni–P alloy as positive current collector in a lithium ion battery. RSC Adv 3:25648–25651

    Article  Google Scholar 

  44. Huang M, Mi R, Liu H, Li F, Zhao XL, Zhang W, He SX, Zhang YX (2014) Layered manganese oxides-decorated and nickel foam-supported carbon nanotubes as advanced binder-free supercapacitor electrodes. J Power Sources 269:760–767

    Article  Google Scholar 

  45. Xiang JY, Tu JP, Wang XL, Huang XH, Yuan YF, Xia XH, Zeng ZY (2008) Electrochemical performances of nanostructured Ni3P–Ni films electrodeposited on nickel foam substrate. J Power Sources 185:519–525

    Article  Google Scholar 

  46. Kolla P, Lai C, Mishra S, Fong H, Rhine W, Smirnova A (2014) CVD grown CNTs within iron modified and graphitized carbon aerogel as durable oxygen reduction catalysts in acidic medium. Carbon 79:518–528

    Article  Google Scholar 

  47. Veziri CM, Pilatos G, Karanikolos GN, Labropoulos A, Kordatos K, Kasselouri-Rigopoulou V, Kanellopoulos NK (2008) Growth and optimization of carbon nanotubes in activated carbon by catalytic chemical vapor deposition. Microporous Mesoporous Mater 110:41–50

    Article  Google Scholar 

  48. Sebastián D, Alegre C, Gálvez ME, Moliner R, Lázaro MJ, Aricò AS, Baglio V (2014) Towards new generation fuel cell electrocatalysts based on xerogel-nanofiber carbon composites. J Mater Chem A 2:13713–13722

    Article  Google Scholar 

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Acknowledgements

This work was supported by the China Scholarship Council, National Natural Science Foundation (51572090) and Natural Science Foundation of Guangdong Province (2016A030313484).

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Authors and Affiliations

  1. North University of China, Shuozhou, 036000, China

    Yuexia Li & Dazhao Li

  2. School of Chemistry and Chemical Engineering, Guangdong Key Lab for Fuel Cell Technology, South China University of Technology, Guangzhou, 510641, China

    Zhen Liu, Yangcheng Jiang & Jianhuang Zeng

  3. School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA, 30332-0245, USA

    Ben deGlee

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  1. Yuexia Li
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Correspondence to Jianhuang Zeng.

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Li, Y., Liu, Z., Jiang, Y. et al. Controlled synthesis of carbon nanofibers over electrolessly plated metal foam catalysts on polyurethane for fuel cell applications. J Mater Sci 53, 479–491 (2018). https://doi.org/10.1007/s10853-017-1530-7

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  • DOI: https://doi.org/10.1007/s10853-017-1530-7

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