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Research on quantum efficiency and photoemission characteristics of exponential-doping GaN nanowire photocathode

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Abstract

Aimed at improving the actual photoemission performance of nanowire photocathode, an axial exponential-doping GaN nanowire photocathode is proposed. Based on two-dimensional continuity equation and finite difference method, the quantum efficiency of this exponential-doping GaN nanowire photocathode is obtained. The simulation results suggest that this structure of GaN nanowire photocathode can effectively obviate the difficulty in collecting the electrons escaping from side faces because a large part of carriers will escape from top surface under the built-in electric field. Besides, it is discovered that the optimal height of nanowires is 300 nm when the doping concentration of top surface is 1 × 1018 cm−3 and that of back interface is 1 × 1019 cm−3. Then, when the nanowires are arranged as array, the optimal light angle of incidence is approximately 60° by analyzing the electrons flow density of the array. By comparison of collection proportion of photoelectrons, the optimal nanowire spacing is 231 nm. This study demonstrates potential application value of exponential-doping GaN nanowire photocathode. The results can direct the preparation of this kind of photocathode.

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References

  1. Zhao S, Nguyen HPT, Kibria MG, Mi Z (2015) III-Nitride nanowire optoelectronics. Prog Quantum Electron 44:14–68

    Article  Google Scholar 

  2. Zou J, Ge X, Zhang Y, Deng W, Zhu Z, Wang W, Peng X, Chen Z, Chang B (2016) Negative electron affinity GaAs wire-array photocathodes. Opt Express 24:4632–4639

    Article  Google Scholar 

  3. Ding X, Ge X, Zou J, Zhang Y, Peng X, Deng W, Chen Z, Zhao W, Chang B (2016) Photoemission characteristics of graded band-gap AlGaAs/GaAs wire photocathode. Opt Commun 367:149–154

    Article  Google Scholar 

  4. Qian F, Wang G, Li Y (2010) Solar-driven microbial photoelectrochemical cells with a nanowire photocathode. Nano Lett 10:4686–4691

    Article  Google Scholar 

  5. Li S, Zhang P, Song X, Gao L (2015) Photoelectrochemical hydrogen production of TiO2 passivated Pt/Si-nanowire composite photocathode. ACS Appl Mater Interfaces 7:18560–18565

    Article  Google Scholar 

  6. Hou Y, Abrams BL, Vesborg PCK, Bjorketun ME, Herbst K, Bech L, Setti AM, Damsgaard CD, Pedersen T, Hansen O, Rossmeisl J, Dahl S, Nørskov JK, Chorkendorff I (2011) Bio-inspire co-catalysts bonded to a silicon photocathode for solar hydrogen evolution. Nat Mater 10:434–438

    Article  Google Scholar 

  7. Oh I, Kye J, Hwang S (2012) Enhanced photoelectrochemical hydrogen production from silicon nanowire array photocathode. Nano Lett 12:298–302

    Article  Google Scholar 

  8. Vilayurganapathy S, Nandasiri MI, Joly AG, El-Khoury PZ, Varga T, Coffey G, Schwenzer B, Pandey A, Kayani A, Hess WP, Thevuthasan S (2013) Silver nanorod arrays for photocathode applications. Appl Phys Lett 103:161112-1–161112-5

    Article  Google Scholar 

  9. Xia S, Liu L, Kong Y (2016) Research on quantum efficiency and photoemission characteristics of negative-electron-affinity GaN nanowire arrays photocathode. Opt Quant Electron 48:306-1–306-12

    Google Scholar 

  10. Xia S, Liu L, Diao Y, Kong Y (2017) Research on quantum efficiency of GaN wire photocathode. Opt Mater 64:187–192

    Article  Google Scholar 

  11. Ge X, Zou J, Deng W, Peng X, Wang W, Jiang S, Ding X, Chen Z, Zhang Y, Chang B (2015) Theoretical analysis and modeling of photoemission characteristics of GaAs nanowire array photocathodes. Mater Res Express 2(9):095015-1–095015-7

    Article  Google Scholar 

  12. Zou J, Chang B, Yang Z (2007) Theoretical calculation of quantum yield for exponential-doping GaAs photocathodes. Acta Physica Sin 56(5):2992–2996

    Google Scholar 

  13. Feng C, Zhang Y, Qian Y, Xu Y, Liu X, Jiao G (2016) Quantum efficiency of transmission-mode AlxGa1−xAs/GaAs photocathodes with graded-composition and exponential-doping structure. Opt Commun 369:50–55

    Article  Google Scholar 

  14. Feng C, Zhang Y, Qian Y, Chang B, Shi F, Jiao G, Zou J (2015) Photoemission from advanced heterostructured AlxGa1-xAs/GaAs photocathodes under multilevel built-in electric field. Opt Express 23:19478–19488

    Article  Google Scholar 

  15. Sahasrabuddhe K, Schwede JW, Bargatin I, Jean J, Howe RT, Shen Z, Melosh NA (2012) A model for emission yield from planar photocathodes based on photon-enhanced thermionic emission or negative-electron-affinity photoemission. J Appl Phys 112:094907-1–094907-10

    Article  Google Scholar 

  16. Machuca F (2003) A thin film p-type GaN photocathode: prospect for a high performance electron emitter [D]. PhD dissertation, Stanford University

  17. Vergara G, Gomez LJ, Capmany J, Montojo MT (1997) Influence of the dopant concentration on the photoemission in NEA GaAs photocathodes. Vacuum 48:155–160

    Article  Google Scholar 

  18. He Y, Zhao Y, Quan J, Quyang G (2016) Shape engineering for electronic and optoelectronic properties of Si nanostructure solar cells. J Appl Phys 120:144302-1–144302-10

    Google Scholar 

Download references

Acknowledgements

This work is sponsored by Qing Lan Project of Jiangsu Province, China, the Fundamental Research Funds for the Central Universities, China (Grant No. 30916011206), and the Six Talent Peaks Project in Jiangsu Province, China (Grant No. 2015-XCL-008).

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Correspondence to Lei Liu.

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Xia, S., Liu, L., Diao, Y. et al. Research on quantum efficiency and photoemission characteristics of exponential-doping GaN nanowire photocathode. J Mater Sci 52, 12795–12805 (2017). https://doi.org/10.1007/s10853-017-1394-x

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  • DOI: https://doi.org/10.1007/s10853-017-1394-x

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