Abstract
In this study, stable water-based heat transfer nanofluid containing a kind of three-dimensional porous graphene (3D PG) has been prepared. For dispersion of 3D PG in water, it is hydrophilic treated by an alkaline method, which is a facile and effective approach in preparing water-soluble graphene by introducing the carboxyl groups (–COOH) as a mild oxidation process using potassium persulfate. The stability and thermal conductive performance of the nanofluid have been investigated with different loading at various temperatures. Experimental results show that the nanofluid can remain highly stability and its enhanced thermal conductivity up to 8–34% can be observed even at lower weight fraction of 0.01–0.07 wt% at room temperature.
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References
Branson BT, Beauchamp PS, Beam JC et al (2013) Nanodiamond nanofluids for enhanced thermal conductivity. ACS Nano 7:3183–3189
Kasaeian A, Eshghi AT, Sameti M (2015) A review on the applications of nanofluids in solar energy systems. Renew Sustain Energy Rev 43:584–598
Sarkar J, Ghosh P, Adil A (2015) A review on hybrid nanofluids: recent research, development and applications. Renew Sustain Energy Rev 43:164–177
Shahrul IM, Mahbubul IM, Khaleduzzaman SS et al (2014) A comparative review on the specific heat of nanofluids for energy perspective. Renew Sustain Energy Rev 38:88–98
Ries HE (1970) Microelectrophoresis measurements on polymeric flocculants alone and in excess with model colloids. Nature 226:72–73
Saidur R, Leong KY, Mohammad HA (2011) A review on applications and challenges of nanofluids. Renew Sustain Energy Rev 15:1646–1668
Li C, Shi G (2012) Three-dimensional graphene architectures. Nanoscale 4:5549–5563
Mehrali MM, Sadeghinezhad E, Tahan Latibari S et al (2014) Preparation, characterization, viscosity, and thermal conductivity of nitrogen-doped graphene aqueous nanofluids. J Mater Sci 49:7156–7171. doi:10.1007/s10853-014-8424-8
Sundar LS, Singh MK, Ramana EV et al (2014) Enhanced thermal conductivity and viscosity of nanodiamond-nickel nanocomposite nanofluids. Sci Rep 4:4039
Yu W, Xie H, Bao D (2010) Enhanced thermal conductivities of nanofluids containing graphene oxide nanosheets. Nanotechnology 21:55705
Sidik NAC, Mohammed HA, Alawi OA, Samion S (2014) A review on preparation methods and challenges of nanofluids. Int Commun Heat Mass Transf 54:115–125
Balandin AA (2011) Thermal properties of graphene and nanostructured carbon materials. Nat Mater 10:569
Balandin AA, Ghosh S, Bao W et al (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8:902–907
Kole M, Dey TK (2013) Investigation of thermal conductivity, viscosity, and electrical conductivity of graphene based nanofluids. J Appl Phys 113:084307
Ghozatloo A, Shariaty-Niasar M, Rashidi AM (2013) Preparation of nanofluids from functionalized Graphene by new alkaline method and study on the thermal conductivity and stability. Int Commun Heat Mass Transf 42:89–94
Baby TT, Ramaprabhu S (2011) Enhanced convective heat transfer using graphene dispersed nanofluids. Nanoscale Res Lett 6:289
Li X, Chen Y, Cheng Z et al (2014) Ultrahigh specific surface area of graphene for eliminating subcooling of water. Appl Energy 130:824–829
Nika DL, Pokatilov EP, Askerov AS, Balandin AA (2009) Phonon thermal conduction in graphene: role of Umklapp and edge roughness scattering. Phys Rev B 79:155413
Savin AV, Kivshar YS, Hu B (2010) Suppression of thermal conductivity in graphene nanoribbons with rough edges. Phys Rev B 82:195422
Li Y, Li Z, Shen PK et al (2013) Simultaneous formation of ultrahigh surface area and three-dimensional hierarchical porous graphene-like networks for fast and highly stable supercapacitors. Adv Mater 25:2474–2480
Kaniyoor A, Baby TT, Ramaprabhu S (2010) Graphene synthesis via hydrogen induced low temperature exfoliation of graphite oxide. J Mater Chem 20:8467
Wang G, Yang J, Park J et al (2008) Facile synthesis and characterization of graphene nanosheets. J Phys Chem C 112:8192–8195
Zhang L, Ni QQ, Fu Y, Natsuki T (2009) One-step preparation of water-soluble single-walled carbon nanotubes. Appl Surf Sci 255:7095–7099
Hontoria-Lucas C, López-Peinado AJ, López-González JDD et al (1995) Study of oxygen-containing groups in a series of graphite oxides: physical and Chemical. Carbon 33:1585–1592
Park O, Jeevananda T, Kim H et al (2009) Effects of surface modification on the dispersion and electrical conductivity of carbon nanotube/polyaniline composites. Scr Mater 60:551–554
Zeng Q, Leng X, Wu K-H et al (2015) Electroactive cellulose-supported graphene oxide interlayers for Li–S batteries. Carbon 93:611–619
Kronholm J, Jyske P, Riekkola M-L (2000) Oxidation efficiencies of potassium persulfate and hydrogen peroxide in pressurized hot water with and without preheating. Ind Eng Chem Res 39:2207–2213
Simms RW, Hoidas MD, Cunningham MF (2008) Nitroxide-mediated styrene surfactant-free emulsion polymerization. Macromolecules 41:1076–1079
Erickson K, Erni R, Lee Z et al (2015) Determination of the local chemical structure of graphene oxide and reduced graphene oxide. Adv Mater 22:4467–4472
Gómez-Navarro C, Meyer JC, Sundaram RS et al (2010) Atomic structure of reduced graphene oxide. Nano Lett 10:1144–1148
Klemens PG (2000) Theory of the a-plane thermal conductivity of graphite. J Wide Bandgap Mater 7:332–339
Ghadimi A, Saidur R, Metselaar HSC (2011) A review of nanofluid stability properties and characterization in stationary conditions. Int J Heat Mass Transf 54:4051–4068
Haddad Z, Abid C, Oztop HF, Mataoui A (2014) A review on how the researchers prepare their nanofluids. Int J Therm Sci 76:168–189
Aravind SSJ, Ramaprabhu S (2013) Graphene-multiwalled carbon nanotube-based nanofluids for improved heat dissipation. RSC Adv 3:4199–4206
Rao Y (2010) Nanofluids: stability, phase diagram, rheology and applications. Particuology 8:549–555
Baby TT, Ramaprabhu S (2010) Investigation of thermal and electrical conductivity of graphene based nanofluids. J Appl Phys 108:124308
Jose Jaime TT, Tharangattu Narayanan N, Chandra Sekhar T et al (2014) Nanodiamond-based thermal fluids. ACS Appl Mater Interfaces 6:4778–4785
Taha-Tijerina JJ, Narayanan TN, Tiwary CS et al (2014) Nanodiamond based thermal fluids. ACS Appl Mater Interfaces 6:4778–4785
Shaker M, Birgersson E, Mujumdar AS (2014) Extended Maxwell model for the thermal conductivity of nanofluids that accounts for nonlocal heat transfer. Int J Therm Sci 84:260–266
Buonomo B, Manca O, Marinelli L, Nardini S (2015) Effect of temperature and sonication time on nanofluid thermal conductivity measurements by nano-flash method. Appl Therm Eng 91:181–190
Shi G, Zhang L (2011) Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability. J Phys Chem C 115:17206–17212
Fan Z, Liu Y, Yan J et al (2012) Template-directed synthesis of pillared-porous carbon nanosheet architectures: high-performance electrode materials for supercapacitors. Adv Energy Mater 2:419–424
Sundar LS, Farooky MH, Sarada SN, Singh MK (2013) Experimental thermal conductivity of ethylene glycol and water mixture based low volume concentration of Al2O3 and CuO nanofluids. Int Commun Heat Mass Transf 41:41–46
Mahmoodi M, Esfe MH, Akbari M et al (2015) Experimental study on thermal conductivity of DWCNT-ZnO/water-EG nanofluids. Int Commu Heat Mass 68:248–251
Karimi A, Sadatlu MAA, Saberi B et al (2015) Experimental investigation on thermal conductivity of water based nickel ferrite nanofluids. Adv Powder Technol 26:1529–1536
Hemmat Esfe M, Afrand M, Karimipour A et al (2015) An experimental study on thermal conductivity of MgO nanoparticles suspended in a binary mixture of water and ethylene glycol. Int Commun Heat Mass Transf 67:173–175
Xing M, Yu J, Wang R (2016) Experimental investigation and modelling on the thermal conductivity of CNTs based nanofluids. Int J Therm Sci 104:404–411
Gupta SS, Siva MV, Krishnan S et al (2011) Thermal conductivity enhancement of nanofluids containing graphene nanosheets. J Appl Phys 110:84302
Baby TT, Sundara R (2011) Synthesis and transport properties of metal oxide decorated graphene dispersed nanofluids. J Phys Chem C 115:8527–8533
Acknowledgements
This work is supported by National Natural Science Foundation of China and Guangdong Province (No. U1401246), by National Natural Science Foundation of China (Grant No. 51276044) and by Science and Technology Program of Guangdong Province of China (Grant Nos. 2014B010106005, 2015B010135011, 2015A050502047, 2016A020221031), and by Science and Technology Program of Guangzhou City of China (Grant Nos. 201508030018, 2016201604030040), and by the National Natural Science Foundation of China (Grant No. 51502043).
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Lin, Y., Zhang, H., He, C. et al. A new kind of water-based nanofluid with a low loading of three-dimensional porous graphene. J Mater Sci 52, 10485–10496 (2017). https://doi.org/10.1007/s10853-017-1232-1
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DOI: https://doi.org/10.1007/s10853-017-1232-1