Abstract
Sn-doped gallium oxide (Ga2O3:Sn) films were deposited on β-Ga2O3 (100) substrates by metal organic chemical vapor deposition method. The Sn concentration was varied from 1 to 12 % (atomic ratio). The influences of Sn-doping concentration on structure, raman, and photoelectric properties of the films were investigated in detail. The obtained films were monoclinic β-Ga2O3 homoepitaxial films. A decrease of about eight orders of magnitude in the film resistivity could be achieved through Sn doping. The 10 % Sn-doped film exhibited the best electrical properties and the lowest resistivity of about 1.20 × 10−1 Ω cm, with the hall mobility value of 12.03 cm2 V−1 s−1obtained. The average transmittances of the β-Ga2O3: Sn films in the visible and UV wavelength ranges were all over 85 %. The optical band gap of the films with different Sn-doping concentrations could be modulated from 4.16 to 4.69 eV.
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References
Li C, Zhang D, Han S et al (2003) Diameter-controlled growth of single-crystalline In2o3 nanowires and their electronic properties. Adv Mater 15:143–146
Zhang DF, Sun LD, Yin JL et al (2003) Low-temperature fabrication of highly crystalline SnO2 nanorods. Adv Mater 15:1022–1025
Özgür Ü, Alivov YI, Liu C et al (2005) A comprehensive review of ZnO materials and devices. J Appl Phys 98:041301
Sun X, Li Y (2004) Ga2O3 and GaN semiconductor hollow spheres. Angew Chem Int Ed Engl 43:3827–3831
Matsuzaki K, Yanagi H, Kamiya T et al (2006) Field-induced current modulation in epitaxial film of deep-ultraviolet transparent oxide semiconductor Ga2O3. Appl Phys Lett 88:092106
Oshima T, Okuno T, Fujita S (2007) Ga2O3 thin film growth on c-plane sapphire substrates by molecular beam epitaxy for deep-ultraviolet photodetectors. Jpn J Appl Phys 46:7217
Rao R, Rao AM, Xu B et al (2005) Blue shifted Raman scattering and its correlation with the [110] growth direction in gallium oxide nanowires. J Appl Phys 98:094312–094315
Ueda N, Hosono H, Waseda R et al (1997) Synthesis and control of conductivity of ultraviolet transmitting β-Ga2O3 single crystals. Appl Phys Lett 70:3561–3563
Orita M, Ohta H, Hirano M et al (2000) Deep-ultraviolet transparent conductive β-Ga2O3 thin films. Appl Phys Lett 77:4166–4168
Víllora EG, Shimamura K, Yoshikawa Y et al (2008) Electrical conductivity and carrier concentration control in β-Ga2O3 by Si doping. Appl Phys Lett 92:202120
Tian W, Zhi C, Zhai T et al (2012) In-doped Ga2O3 nanobelt based photodetector with high sensitivity and wide-range photo response. J Mater Chem 22:17984–17991
Shannon RD, Prewitt CT (1969) Effective ionic radii in oxides and fluorides. Acta Cryst B 25:925–946
Du XJ, Mi W, Jin M et al (2014) Characterization of homoepitaxial β-Ga2O3 films prepared by metal-organic chemical vapor deposition. J Cryst Growth 404:75–79
Choi YC, Kim WS, Park YS et al (2000) Catalytic growth of β-Ga2O3 nanowires by arc discharge. Adv Mater 12:746–750
Dohy D, Lucazeau G, Revcolevschi A (1982) Raman spectra and valence force field of single-crystalline β-Ga2O3. J Solid State Chem 45:180–192
Xiao HD, Ma HL, Xue CS et al (2007) Synthesis and structural properties of beta-gallium oxide particles from gallium nitride powder. Mater Chem Phys 101:99–102
Xu Q, Zhang S (2008) Fabrication and photoluminescence of β-Ga2O3 nanorods. Superlattices Microstruct 44:715–720
Taylor JA, Lancaster GM, Rabalais JW (1978) Chemical reactions of N2 +ion beams with group IV elements and their oxides. J Electron Spectros Relat Phenom 13:435–444
Yan L, Pan JS, Ong CK (2006) XPS studies of room temperature magnetic Co-doped SnO2 deposited on Si. Mater Sci Eng B128:34–36
Hueso JL, Espinós JP, Caballero A et al (2007) XPS investigation of the reaction of carbon with NO, O2, N2 and H2O plasmas. Carbon 45:89–96
Perron H, Vandenborre J, Domain C et al (2007) Combined investigation of water sorption on TiO2rutile (110) single crystal face: XPS vs. periodic DFT. Surf Sci 601:518–527
Gomez H, Maldonado A, Olvera M et al (2005) Gallium-doped ZnO thin films deposited by chemical spray. Sol Energy Mater Sol Cells 87:107–116
Liu Z, Zhang D, Han S et al (2003) Laser ablation synthesis and electron transport studies of tin oxide nanowires. Adv Mater 15:1754–1757
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This work is financially supported by the National Natural Science Foundation of China (Grant No. 51072102).
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Du, X., Li, Z., Luan, C. et al. Preparation and characterization of Sn-doped β-Ga2O3 homoepitaxial films by MOCVD. J Mater Sci 50, 3252–3257 (2015). https://doi.org/10.1007/s10853-015-8893-4
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DOI: https://doi.org/10.1007/s10853-015-8893-4