Abstract
We hereby report on the role of the surface morphology of various substrates in the enhancement of the superconducting critical temperature of MgB2. MgB2 thin layers were grown by hybrid physical–chemical vapour deposition on silicon carbide SiC substrates/fibers and several other substrates, characterized by diverse surface morphologies. By investigating the structural, morphological and transport properties of MgB2 thin layers, the presented data show that the superconducting critical temperature T c exceeds the bulk value only when the MgB2 films are grown on atomically flat (0001) SiC single crystals and on MgB2 bottom layers. These results further confirm the interpretation of the coalescence-driven tensile strain mechanism behind the enhancement of superconducting properties in MgB2 thin films.
Similar content being viewed by others
References
Brock DK, Track EK, Rowell JM (2000) Superconductor ICs: the 100-GHz second generation. IEEE Spectr 37:40–46
Nagamatsu J, Nakagawa N, Muranaka T, Zenitani Y, Akimitsu J (2001) Superconductivity at 39 K in magnesium diboride. Nature 410:63–64
Rowell J (2002) Magnesium diboride superior thin films. Nat Mater 1:5–6
Xi XX (2009) MgB2 thin films. Supercond Sci Technol 22:043001
Iavarone M, Karapetrov G, Koshelev AE, Kwok WK, Crabtree GW, Hinks DG, Kang WN, Choi EM, Kim HJ, Lee SI (2002) Two-band superconductivity in MgB2. Phys Rev Lett 89:187002
Iavarone M, Karapetrov G, Menzel A, Komanicky V, You H, Kwok WK, Orgiani P, Ferrando V, Xi XX (2005) Characterization of off-axis MgB2 epitaxial thin films for planar junctions. Appl Phys Lett 87:242506
Di Capua R, Aebersold HU, Ferdeghini C, Ferrando V, Orgiani P, Putti M, Salluzzo M, Vaglio R, Xi XX (2007) Role of interband scattering in neutron irradiated MgB2 thin films by scanning tunneling spectroscopy measurements. Phys Rev B 75:014515
Cubitt R, Dewhurst CD, Eskildsen MR, Levett SJ, Matadeen A, Jun J, Kazakov SM, Karpinski J, Bud’ko SL, Anderson NE, Canfield PC (2006) Penetration depth anisotropy in MgB2 single crystals and powders. J Phys Chem Solids 7:493
Eltsev Yu, Nakao K, Lee S, Masui T, Chikumoto N, Tajima S, Koshizuka N , Murakami M (2002) Anisotropic resistivity and hall effect in MgB2 single crystals. Phys Rev B 66:180504R
Putti M, Vaglio R, Rowell JM (2008) Radiation effects on MgB2: a review and a comparison with A15 superconductors. Supercond Sci Technol 21:043001
Chen K, Dai W, Zhuang CG, Li Qi, Carabello S, Lambert JG, Mlack JT, Ramos RC, Xi XX (2012) Momentum-dependent multiple gaps in magnesium diboride probed by electron tunnelling spectroscopy. Nat Commun 3:619
Zeng XH, Pogrebnyakov AV, Kotcharov A, Jones JE, Xi XX, Lysczek EM, Redwing JM, Xu SY, Li Qi, Lettieri J, Schlom DG, Tian W, Pan XQ, Liu ZK (2002) In situ epitaxial MgB2 thin films for superconducting electronics. Nat Mater 1:35–38
Zeng XH, Pogrebnyakov AV, Zhu MH, Jones JE, Xi XX, Xu SY, Wertz E, Li Qi, Redwing JM, Lettieri J, Vaithyanathan V, Schlom DG, Liu ZK, Trithaveesak O, Schubert J (2003) Superconducting MgB2 thin films on silicon carbide substrates by hybrid physical–chemical vapor deposition. Appl Phys Lett 82:2097
Pogrebnyakov AV, Redwing JM, Jones JE, Xi XX, Xu SY, Li Qi, Vaithyanathan V, Schlom DG (2003) Thickness dependence of the properties of epitaxial MgB2 thin films grown by hybrid physical–chemical vapor deposition. Appl Phys Lett 82:4319
Pogrebnyakov AV, Redwing JM, Raghavan S, Vaithyanathan V, Schlom DG, Xu SY, Li Qi, Tenne DA, Soukiassian A, Xi XX, Johannes MD, Kasinathan D, Pickett WE, Wu JS, Spence JCH (2004) Enhancement of the superconducting transition temperature of MgB2 by a strain-induced bond-stretching mode softening. Phys Rev Lett 93:147006
Cui Y, Jones JE, Beckley A, Donovan R, Lishego D, Maertz E, Pogrebnyakov AV, Orgiani P, Redwing JM, Xi XX (2005) Degradation of MgB2 thin films in water. IEEE Trans Appl Phys 15:224–227
Van der Pauw LJ (1958) A method of measuring specific resistivity and Hall effect of discs of arbitrary shape. Philips Res Rep 13:1–9
Zhuang C, Tan T, Wang Y, Bai S, Ma X, Yang H, Zhang G, He Y, Wen H, Xi XX, Feng Q, Gan Z (2009) Clean MgB2 thin films on different types of single-crystal substrate fabricated by hybrid physical–chemical vapor deposition. Supercond Sci Technol 22:025002
Fen L, Guo T, Zhang K, Chen L, Chen C, Feng Q (2006) Thick polycrystalline MgB2 film on Cu substrate by hybrid physical–chemical vapour deposition. Supercond Sci Technol 19:1196
Chromik Š, Huran J, Štrbík V, Španková M, Vávra I, Bohne W, Röhrich J, Strub E, Kováč P, Stanček S (2006) Nanogranular MgB2 thin films on SiC buffered Si substrates prepared by an in situ method. Supercond Sci Technol 19:577
Regel LL, Wilcox WR (2001) Diamond film deposition by chemical vapor transport. Acta Astronaut 48:129–144
Vaglio R, Attanasio C, Maritato L, Ruosi A (1993) Explanation of the resistance-peak anomaly in nonhomogeneous superconductors. Phys Rev B 47:15302–15303
Bulaevskii LN, Clem JR, Glazman LI, Malozemoff AP (1992) Model for the low-temperature transport of bi-based high-temperature superconducting tapes. Phys Rev B 45:2545–2548
Rowell JM (2003) The widely variable resistivity of MgB2 samples. Supercond Sci Technol 16:R17
Rowell JM, Xu SY, Zeng XH, Pogrebnyakov AV, Li Qi, Xi XX, Redwing JM, Tian W, Pan X (2003) Critical current density and resistivity of MgB2 films. Appl Phys Lett 83:102–104
Ferrando V, Orgiani P, Pogrebnyakov AV, Chen J, Li Q, Redwing JM, Xi XX, Giencke JE, Eom CB, Feng QR, Betts JB, Mielke CH (2005) High upper critical field and irreversibility field in MgB2 coated-conductor fibers. Appl Phys Lett 87:252509
Acknowledgements
This work was supported by ONR under Grant No. N00014-00-1-0294. P.O’s research activity has received funding from the European Community Seventh Framework Programme 2007–2011 under Collaborative Project ‘Integrated Ground and on-Board system for Support of the Aircraft Safe Take-off and Landing-GABRIEL’ Grant agreement No. 284884 and under Grant agreement No. 283141 IRONSEA. R.C’s research activity has received funding from the European Community Seventh Framework Programme 2007–2011 under Grant agreement No. 212348 NFFA and Progetto strategico NFFA (fondi MIUR 2012–2013). The authors wish to acknowledge V. Ferrando and R. Vaglio for stimulating scientific discussion and fruitful collaboration.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Orgiani, P., Ciancio, R., Wolak, M.A. et al. The role of the substrate surface morphology in enhancing the MgB2 superconducting temperature. J Mater Sci 49, 4108–4114 (2014). https://doi.org/10.1007/s10853-014-8104-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-014-8104-8