Abstract
The effects of high energy ball milling (HEBM) on the structure and some key-properties of crosslinked high density polyethylene (PEX) have been thoroughly examined with a combination of X-ray diffraction analysis, IR and Raman spectroscopy, differential scanning calorimetry, gel content measurements, and tensile properties tests. A structure–property relationship, which provides a reasonable explanation for the studied case has been developed based on the experimental results and their analysis. It is proposed that the HEBM provides some of the silane-grafted macromolecular chains, which have a specific orientation, with sufficient energy in order to crosslink and form small crystalline-like areas. The arrangement of chains in the “reformed” domains leads to a total increase of the overall crystallinity, but also a decrease of the crystalline size. The proposed model can also support the fact that by increasing the milling time, the overall crystallinity of PEX and some important mechanical properties are found to increase.
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Gorrasi G, Di Lieto R, Patimo G, De Pasquale S, Sorrentino A (2011) Polymer 52:1124. doi:10.1016/j.polymer.2011.01.008
Terife G, Narh KA (2011) Polym Compos 32:2101
Sorrentino A, Gorrasi G, Tortora M et al (2005) Polymer 46:1601. doi:10.1016/j.polymer.2004.12.018
Gorrasi G, Sarno M, Di Bartolomeo A, Sannino D, Ciambelli P, Vittoria V (2007) J Polym Sci B 45:597. doi:10.1002/polb.21070
Suryanarayana C (2001) Prog Mater Sci 46:1. doi:10.1016/S0079-6425(99)00010-9
Jiang X, Drzal LT (2012) J Appl Polym Sci 124:525
Olmos D, Domínguez C, Castrillo PD, Gonzalez-Benito J (2009) Polymer 50:1732. doi:10.1016/j.polymer.2009.02.011
Ishida T (1994) J Mater Sci Lett 13:623. doi:10.1007/bf00271215
Castricum HL, Yang H, Bakker H, Van Deursen JH (1997) In: Fiorani D, Magini M (eds) Synthesis and properties of mechanically alloyed and nanocrystalline materials, pts 1 and 2 Ismanam-96. Trans Tech Publications Ltd, Stafa-Zurich
Wu H, Liang M, Lu C (2012) Thermochim Acta 545:148. doi:10.1016/j.tca.2012.07.008
Oliveira GL, Costa MF (2010) Mater Sci Eng A 527:4593. doi:10.1016/j.msea.2010.03.102
Wang Z, Hu Y, Gui Z, Zong R (2003) Polym Test 22:533. doi:10.1016/s0142-9418(02)00149-6
Ritums JE, Mattozzi A, Gedde UW, Hedenqvist MS, Bergman G, Palmlöf M (2006) J Polym Sci B 44:641. doi:10.1002/polb.20729
Celina M, George GA (1995) Polym Degrad Stab 48:297. doi:10.1016/0141-3910(95)00053-O
Venkatraman S, Kleiner L (1989) Adv Polym Technol 9:265. doi:10.1002/adv.1989.060090308
Kuan H-C, Kuan J-F, Ma C-CM, Huang J-M (2005) J Appl Polym Sci 96:2383. doi:10.1002/app.21694
Gan Q, Qi R, Zhang J, Yu J, Huang S (2011) J Appl Polym Sci 119:2539. doi:10.1002/app.31639
Atkinson JR, Cicek RZ (1983) Biomaterials 4:267. doi:10.1016/0142-9612(83)90026-1
Narkis M, Raiter I, Shkolnik S, Siegmannz A, Eyerer P (1987) J Macromol Sci B 26:37. doi:10.1080/00222348708248057
Andreopoulos AG, Kampouris EM (1986) J Appl Polym Sci 31:1061. doi:10.1002/app.1986.070310407
Azizi H, Morshedian J, Barikani M, Wagner MH (2011) Adv Polym Technol 30:286. doi:10.1002/adv.20224
Narkis M, Tzur A, Vaxman A, Fritz HG (1985) Polym Eng Sci 25:857. doi:10.1002/pen.760251311
Barzin J, Azizi H, Morshedian J (2006) Polym Plast Technol Eng 45:979. doi:10.1080/03602550600718209
Barzin J, Azizi H, Morshedian J (2007) Polym Plast Technol Eng 46:305. doi:10.1080/03602550601155815
Azizi H, Morshedian J, Barikani M (2009) J Vinyl Add Tech 15:184. doi:10.1002/vnl.20194
Bengtsson M, Gatenholm P, Oksman K (2005) Compos Sci Technol 65:1468. doi:10.1016/j.compscitech.2004.12.050
Bullen DJ, Capaccio G, Frye CJ, Brock T (1989) Br Polym J 21:117. doi:10.1002/pi.4980210205
Rizzo P, Baione F, Guerra G, Martinotto L, Albizzati E (2001) Macromolecules 34:5175. doi:10.1021/ma010121z
Bunn CW (1939) Trans Faraday Soc 35:482
Langford JI, Wilson AJC (1978) J Appl Crystallogr 11:102. doi:10.1107/S0021889878012844
Clements J, Jakeways R, Ward IM (1978) Polymer 19:639. doi:10.1016/0032-3861(78)90116-7
Akovali G, Atalay A (1997) Polym Test 16:165. doi:10.1016/S0142-9418(96)00037-2
Boerio FJ, Koenig JL (1970) J Chem Phys 52:3425
Strobl GR, Hagedorn W (1978) J Polym Sci 16:1181. doi:10.1002/pol.1978.180160704
Koglin E, Meier RJ (1999) Comput Theor Polym Sci 9:327. doi:10.1016/S1089-3156(99)00022-7
Kurelec L, Rastogi S, Meier RJ, Lemstra PJ (2000) Macromolecules 33:5593. doi:10.1021/ma9911187
Masetti G, Abbate S, Gussoni M, Zerbi G (1980) J Chem Phys 73:4671
Abbate S, Gussoni M, Zerbi G (1980) J Chem Phys 73:4680
Hagemann H, Snyder RG, Peacock AJ, Mandelkern L (1989) Macromolecules 22:3600. doi:10.1021/ma00199a017
Painter PC, Runt J, Coleman MM, Harrison IR (1977) J Polym Sci 15:1647. doi:10.1002/pol.1977.180150912
Mutter R, Stille W, Strobl G (1993) J Polym Sci B 31:99. doi:10.1002/polb.1993.090310113
Taddei P, Affatato S, Fagnano C, Bordini B, Tinti A, Toni A (2002) J Mol Struct 613:121. doi:10.1016/S0022-2860(02)00141-2
Naylor CC, Meier RJ, Kip BJ et al (1995) Macromolecules 28:2969. doi:10.1021/ma00112a050
Glotin M, Mandelkern L (1982) Colloid Polym Sci 260:182. doi:10.1007/bf01465438
Svoboda R, Málek J (2013) J Therm Anal Calorim 111:1045. doi:10.1007/s10973-012-2445-9
Fraser RDB, Suzuki E (1966) Anal Chem 38:1770. doi:10.1021/ac60244a038
Fraser RDB, Suzuki E (1969) Anal Chem 41:37. doi:10.1021/ac60270a007
Perejón A, Sánchez-Jiménez PE, Criado JM, Pérez-Maqueda LA (2011) J Phys Chem B 115:1780. doi:10.1021/jp110895z
Koch CC, Cavin OB, McKamey CG, Scarbrough JO (1983) Appl Phys Lett 43:1017
Schwarz RB, Johnson WL (1983) Phys Rev Lett 51:415
Fan GJ, Guo FQ, Hu ZQ, Quan MX, Lu K (1997) Phys Rev B 55:11010
Smith AP, Spontak RJ, Ade H, Smith SD, Koch CC (1999) Adv Mater 11:1277. doi:10.1002/(sici)1521-4095(199910)11:15<1277:aid-adma1277>3.0.co;2-9
Bai C, Spontak RJ, Koch CC, Saw CK, Balik CM (2000) Polymer 41:7147. doi:10.1016/S0032-3861(00)00048-3
Smith AP, Shay JS, Spontak RJ et al (2000) Polymer 41:6271. doi:10.1016/S0032-3861(99)00830-7
Cavalieri F, Padella F, Bourbonneux S (2002) Polymer 43:1155. doi:10.1016/S0032-3861(01)00721-2
Pan J, Shaw WJD (1994) J Appl Polym Sci 52:507. doi:10.1002/app.1994.070520405
Smith AP, Bai C, Ade H, Spontak RJ, Balik CM, Koch CC (1998) Macromol Rapid Commun 19:557. doi:10.1002/(sici)1521-3927(19981101)19:11<557:aid-marc557>3.0.co;2-x
Beyer MK, Clausen-Schaumann H (2005) Chem Rev 105:2921. doi:10.1021/cr030697h
Acknowledgements
The authors would like to thank Prof. Aldo Boccaccini of the University of Erlangen-Nurnberg for allowing the use of the Raman spectroscopy facilities available at Biometerials Department, and Mr. C. Dolle for performing these measurements. This study was financially supported by the Greek General Secretariat of Research and Development (09SYN-33-484).
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Roumeli, E., Paraskevopoulos, K.M., Bikiaris, D. et al. Effect of high energy ball milling on the structure and mechanical properties of cross-linked high density polyethylene. J Mater Sci 48, 6753–6761 (2013). https://doi.org/10.1007/s10853-013-7480-9
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DOI: https://doi.org/10.1007/s10853-013-7480-9