Abstract
The effects of heat treatment temperature on crystallisation behaviour, precipitated phases and thermo-mechanical properties of some MgO–Al2O3–SiO2 (MAS) glass-ceramics were investigated. Crystallisation behaviour of MgO–Al2O3–SiO2 glasses in the presence of TiO2 as a nucleation agent was studied. The crystalline phases present in the heat treated samples were identified by X-ray diffraction (XRD). It was observed from XRD studies that magnesium aluminium titanate initially precipitated and when the heat treatment temperature was increased to 1140 °C, depending on the thermal history, either magnesium silicate, aluminium titanate and quartz or magnesium aluminium titanate, magnesium aluminate and quartz were precipitated. SEM observation revealed that the heat treatment led to phase separation of droplet-shaped crystals before the needle-shaped crystals formed at 1140 °C. The effect of annealing temperature on the density and mechanical properties of these glass-ceramic were characterised by nanoindentation and the results revealed a significant increase in hardness of the fully crystallised system.
Similar content being viewed by others
References
Lawrence CW, Briggs GAD (1993) J Mater Sci 28:3645. doi:https://doi.org/10.1007/BF01159848
Reich CH, Brückner R (1997) Compos Sci Technol 57:533
Yilmaz R, Taylor R (2007) J Mater Sci 42:4115. doi:https://doi.org/10.1007/s10853-007-1656-0
Ahn JM, Mall S (2009) Int J Appl Ceram Technol 6(1):45
Shao H, Liang K, Zhou F, Wang G, Hu A (2005) Mater Res Bull 40:499
Wange P, Höche T, Rüssel C, Schnapp JD (2002) J Non-Cryst Solids 298:137
Owate IO, Freer R (1990) J Mater Sci 25:5291. doi:https://doi.org/10.1007/BF00580163
Gupta PK (1988) In: Bunsell AR (ed) Fibre reinforcements for composite materials, Elsevier, Amsterdam
McMillan PW (1979) Glass-ceramic. Academic, London
Strand Z (1986) Glass-ceramic materials. Elsevier, Amsterdam
Hwang SP, Wu JM (2001) J Am Ceram Soc 84:1108
Gregory AG, Veasay TJ (1973) J Mater Sci 8(3):324. doi:https://doi.org/10.1007/BF00550151
Rawson H (1988) Properties and applications of glass. Elsevier, New York
Ashbee KHG (1973) J Mater Sci 10:911. doi:https://doi.org/10.1007/BF00823206
Onishi M, Kyoto M, Watanabe M (1991) J Appl Phys 30(6A):988
Sakamoto A, Yamamoto S (2003) J Mater Sci 38:2305. doi:https://doi.org/10.1023/A:1023920110755
Goswami M, Mirza T, Sarkar A, Manikandan S, Sangeeta SL, Verma KR, Gurumurthy VK, Shrikhande Kothiyal GP (2001) Bull Mater Sci 23(5):377
Halváč J (1983) The technology of glass and ceramic: an introduction. Elsevier, Amsterdam
Zdaniewski W (1973) J Mater Sci 8:192. doi:https://doi.org/10.1007/BF00550667
Goel A, Shaaban ER, Melo FCL, Ribeiro MJ, Ferreira JMF (2007) J Non-Cryst Solids 353:2383
Shao H, Liang K, Peng F (2004) Ceram Int 30:927
Weaver DT, Van Aken DC, Smith JD (2004) J Mater Sci 39:51. doi:https://doi.org/10.1023/B:JMSC.0000007727.10682.b6
Quyang XQ, Xiao ZH, Lu AX (2009) Advc Appl 108:178
Oliver WC, Pharr GM (1992) J Mater Res 7(6):1564
Doerner MF, Nix WD (1986) J Mater Res 1:601
Amista P, Cesari M, Montena A, Gnappi G, Lan L (1995) J Non-Cryst Solids 192&193:529
Shyu JJ, Wu JM (1991) J Mater Sci Lett 10:1056
Minsheng M, Wen N, Yali W, Zhongjie W, Fengmei L (2008) J Non-Cryst Solids 354:5395
Acknowledgements
The authors wish to express their thanks to Mr Dean Haylock, Miss Bev Lane, Mr Philip Staton and Mr Pete Bailey for their technical assistance with glass melting, thermal analysis, sample preparation and technical advice. ZS would like to thank Universiti Teknikal Malaysia Melaka for granting her concession and study leave to undertake her PhD degree. The authors also wish to acknowledge Alstom (Areva) for the use of DTA.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Shamsudin, Z., Hodzic, A., Soutis, C. et al. Characterisation of thermo-mechanical properties of MgO–Al2O3–SiO2 glass ceramic with different heat treatment temperatures. J Mater Sci 46, 5822–5829 (2011). https://doi.org/10.1007/s10853-011-5538-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-011-5538-0