Abstract
Vanadium carbide (VC) nanoparticles were synthesized by a novel refluxing-derived precursor. The organic/inorganic hybrid precursor was prepared by a two-step refluxing method using hydrous V2O5 as vanadium source and n-dodecane as carbon source. The reaction process, phase composition, microstructure, and element composition of VC were investigated by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy (XPS). The results showed that VC nanoparticles could be obtained at 900 °C for 1 h in flowing Argon (Ar), which was much lower than those of conventional synthesis methods. XRD pattern indicated that the product was face-centered cubic VC with a lattice constant a = 4.1626 Å and average crystallite size of 22.3 nm. Raman spectra indicated that long time refluxing resulted in alkane dehydrogenation and the formation of coke on V2O5 nanoparticles. XPS investigations confirmed oxygen presence in VC lattice. Electron microscopy photographs showed the particle size ranged from 20 to 50 nm. All these results confirmed that the two-step refluxing method was a novel and feasible method to synthesize VC nanoparticles.
Similar content being viewed by others
References
Reichl W, Hayek K (2004) J Catal 222:53
Yazawa Y, Furuhara T, Maki T (2004) Acta Mater 52:3727
Wiesenberger H, Lengauer W, Ettmayer P (1998) Acta Mater 46:651
Misra RDK (1996) Acta Mater 44:4367
Lee J, Sohn K, Hyeon T (2001) J Am Chem Soc 123:5146
Yoon SB, Sohn K, Kim JY, Shin CH, Yu JS, Hyeon T (2002) Adv Mater 14:19
Zhang B, Li ZQ (2005) J Alloys Compd 392:183
Zhang B, Li ZQ (2005) J Alloys Compd 392:183
Kapoor R, Oyama ST (1995) J Solid State Chem 120:320
Lee JS, Oyama ST, Boudart M (1987) J Catal 106:125
Ribeiro FH, Dalla Betta RA, Boudart M, Baumgartner J, Iglesia E (1991) J Catal 130:86
Iglesia E, Baumgartner J, Ribeiro FH, Boudart M (1991) J Catal 131:523
Neylon MK, Choi S, Kwon H, Curry KE, Thompson LT (1999) Appl Catal A Gen 183:253
Lee JS, Locatelli S, Oyama ST, Boudart M (1990) J Catal 125:157
Oyama ST, Schlatter JC, Metcalfe JE III, Lambert JM (1988) Ind Eng Chem Res 27:1639
Lee JS, Volpe L, Ribeiro FH, Boudart M (1988) J Catal 112:44
Lemonidou AA (2001) Appl Catal A Gen 216:277
Lopez Nieto JM, Concepcion P, Dejoz A et al (2000) J Catal 189:147
Wachs IE, Weckhuysen BM (1997) Appl Catal A Gen 157:67
Li J, Xiong G, Feng Z et al (2000) Microporous Mesoporous Mater 39:275
Atamas NA, Yaremko AM, Seeger T et al (1997) J Mol Struct 708:189
Chua YT, Stair PC (2003) J Catal 213:39
Veres M, Fule M, Toth S, Koos M, Pocsik I (2004) Diamond Relat Mater 13:1412
Liao SJ, Huang DG, Yu DH (2004) J Photochem Photobiol A Chem 168:7
Ye JW, Liu Y, Zhao ZW, Jiang ZT, Tang ZH (2010) J Alloys Compd 496:278
Choi JG (1999) Appl Surf Sci 148:64
Acknowledgements
The support of Sichuan Province through a Key Technologies Research and Development Program of Sichuan Province, the New Preparative Technique of Nano Carbides (2006Z02-17) is acknowledged with gratitude. We thank Southwest University of Science and Technology for providing the Raman spectra tests.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, F., Yao, Y., Zhang, H. et al. Synthesis and characterization of vanadium carbide nanoparticles by thermal refluxing-derived precursors. J Mater Sci 46, 3693–3697 (2011). https://doi.org/10.1007/s10853-010-5123-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-010-5123-y