Abstract
The 2-hydroxypropyltrimethyl ammonium chloride chitosan (HACC)-grafted multiwalled carbon nanotubes (MWCNTs) composite (HACC–MWCNTs) was prepared via covalently grafting HACC onto the surfaces of MWCNT. The properties and morphology of the resulting materials were monitored by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The results of FTIR and TGA indicated that the interaction between MWCNT and HACC was grafting through covalent links. TEM and SEM images confirmed MWCNT stained with an extra phase after the grafting process that was presumed to come from HACC. The dispersion of MWCNT in H2O was improved after the grafting of HACC,which was in agreement with the positive charge of HACC–MWCNT at any pH value. The electrochemical properties of HACC–MWCNT were investigated by cyclic voltammetry (CV). The dramatic improvement in the electrostatic interactions between HACC–MWCNT/electrode and anionic complexes was distinguished from the response of chitosan-MWCNT/electrode and non-modified electrode. According to the experimental results, the HACC–MWCNT had a possibility to serve as a novel material for innovative anionic sensor.
Similar content being viewed by others
References
Merkoçi A, Pumera M, Llopis X, Pérez B, Valle M, Alegret S (2005) Trends Anal Chem 24(9):826
Coleman JN, Khan U, Blau WJ, Gun’ko YK (2006) Carbon 44:1624
Carrara S, Shumyantseva VV, Archakov AI, Samor B (2008) Biosens Bioelectron 24:148
Buratti S, Brunetti B, Mannino S (2008) Talanta 76:454
Shobha Jeykumari DR, Ramaprabhu S, Sriman Narayanan S (2007) Carbon 45:1340
Wei C, Srivastava D, Cho K (2004) Nano Lett 4:1949
Wang J, Kawde A-N, Jan MR (2004) Biosens Bioelectron 20:995
Yogeswaran U, Chen S-M (2008) Sens Actuators B 130:739
Guibal E (2005) Prog Polym Sci 30:71
Chiou MS, Li HY (2003) Chemosphere 50:1095
Binsu VV, Nagarale RK, Shahi VK, Ghosh PK (2006) React Funct Polym 66:1619
Tkac J, Whittaker JW, Ruzgas T (2007) Biosens Bioelectron 22:1820
Liu Y, Tang J, Chen X, Xin JH (2005) Carbon 43:3178
Wu Z, Feng W, Feng Y, Liu Q, Xu X, Sekino T et al (2007) Carbon 45:1212
Kong H, Gao C, Yan D (2004) J Am Chem Soc 126(2):412
de Moura MR, Aouada FA, Mattoso LHC (2008) J Colloid Interface Sci 321:477
Anal AK, Tobiassen A, Flanagan J, Singh H (2008) Colloids Surf B 64:104
Jansson-Charrier M, Guibal E, Roussy J, Delanghe B, Le Cloirec P (1996) Water Res 30(2):465
Dzul Erosa MS, Saucedo Medina TI, Avarro Mendoza R, Avila Rodriguez M, Uibal E (2001) Hydrometallurgy 61:157
Loubaki E, Ourevitch M, Sicsic S (1991) Eur Polym J 27(3):311
Shieh Y-T, Yang Y-F (2006) Eur Polym J 42:3162
Shen J, Huang W, Wu L, Hua Y, Ye M (2007) Mater Sci Eng A 464:151
Yao H, Li N, Xu J-Z, Zhu J-J (2007) Talanta 71:550
Huang R, Chen G, Sun M, Hu Y, Gao C (2006) J Membr Sci 286:237
Xiong J, Zheng Z, Qin X (2006) Carbon 44:2701
Miao Z, Yang J, Wang L (2008) Mater Lett 62:3450
Zheng Z, He P-J, Shao L-M (2007) Water Res 41:4696
Oki A, Adams L, Khabashesku V (2008) Mater Lett 62:918
Chen E-C, Wu T-M (2007) Polym Degrad Stab 92:1009
Li J, Tong L, Fang Z (2006) Polym Degrad Stab 91:2046
Bikiaris D, Vassiliou A, Chrissafis K, Paraskevopoulos KM, Jannakoudakis A, Docoslis A (2008) Polym Degrad Stab 93:952
Kweon HY, Um IC, Park YH (2001) Polymer 42:6651
Zohuriaan MJ, Shokrolahi F (2004) Polym Test 23:575
Ko C-J, Lee C-Y, Ko F-H, Chen H-L, Chu T-C (2004) Microelectron Eng 73–74:570
Chen C-M, Chen M, Peng Y-W, Lin C-H, Chang L-W, Chen C-F (2005) Diamond Relat Mater 14:798
Zhang J, Wang Q, Wang L, Wang A (2007) Carbon 45:1911
Liang R, Peng H, Qiu J (2008) J Colloid Interface Sci 320:125
Ojani R, Raoof J-B, Zarei E (2006) Electrochim Acta 52:753
Emery SB, Hubbley JL, Roy D (2005) Electrochim Acta 50:5659
Trasatti S, Petrii OA (1992) J Electroanal Chem 327:353
Xiang C, Zou Y, Suna L-X, Xua F (2006) Electrochim Acta 51:5324
Huang R, Chen G, Yang B, Gao C (2008) Sep Purif Technol 61:424
Zangmeister RA, Park JJ, Rubloff GW, Tarlov MJ (2006) Electrochim Acta 51:5324
Acknowledgement
This work was supported in part by the National Natural Science Foundation of China (30571462).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, W., Xiao, L. & Qin, C. Synthesis and relevant electrochemical properties of 2-hydroxypropyltrimethyl ammonium chloride chitosan-grafted multiwalled carbon nanotubes. J Mater Sci 45, 5915–5922 (2010). https://doi.org/10.1007/s10853-010-4671-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-010-4671-5