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Solvent influence on isomer separation and conformation control of the cyclohexanedicarboxylate ligand toward La(III) coordination polymeric framework

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Abstract

Two novel coordination polymers have been synthesized using 1,4-cyclohexanedicarboxylic acid (chdcH2) by the solvent diffusion method. In the presence of different solvents, cis and trans conformations of chdcH2 were completely separated. The reaction in DMF/glycol resulted in a 1D chain framework La(cis-chdc)(DMF)2(NO3) (1) and the reaction in DMSO resulted in the formation of a novel 3D ReO3 topology La2(trans-chdc)3(DMSO)4 (2). Additionally, the solvent molecules (DMF and DMSO) also acted as coordination ligands in the formation of extended structures.

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Scheme 1
Scheme 2
Fig. 1
Fig. 2
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Acknowledgements

This work was supported by the State Basic Research Project (G2000077507), the National Nature Science Foundation of China (Grant nos. 29873017, 20101004, and 20371020), and the Belgian Federal Government IUAP-PAI program (INANOMAT P6/17) project.

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Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, Jilin University, Changchun, 130012, China

    Ge Tian, Guangshan Zhu & Shilun Qiu

  2. Laboratory of Inorganic Materials Chemistry (CMI), The University of Namur (FUNDP), 61, rue de Bruxelles, 5000, Namur, Belgium

    Ge Tian & Bao-Lian Su

Authors
  1. Ge Tian
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  2. Guangshan Zhu
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  3. Bao-Lian Su
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  4. Shilun Qiu
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Corresponding authors

Correspondence to Guangshan Zhu, Bao-Lian Su or Shilun Qiu.

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Tian, G., Zhu, G., Su, BL. et al. Solvent influence on isomer separation and conformation control of the cyclohexanedicarboxylate ligand toward La(III) coordination polymeric framework. J Mater Sci 44, 6576–6582 (2009). https://doi.org/10.1007/s10853-009-3633-2

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