Abstract
Cobalt-containing MCM-41 and SBA-15 mesoporous materials were prepared by the pH-adjusting of the impregnation solution. The modified materials were investigated by X-ray diffraction, N2 physisorption, temperature-programmed reduction, DR UV–Vis diffuse reflectance, and FT-IR spectroscopy of adsorbed pyridine. The pH of the impregnation solution influences the surface charge of the mesoporous support and therefore determines the strength of interaction between the cobalt precursor and the mesoporous support. The formation of different cobalt oxide species in different ratios, depending on the pH of the impregnation solution, was established for both materials. The modified Co/MCM-41 and Co/SBA-15 materials were active in toluene oxidation. Their catalytic activity is predetermined by the nature, the reducibility, and the dispersion of the obtained cobalt oxide species.
Similar content being viewed by others
References
Yin D, Li W, Yang W, Xiang H, Sun Y, Zhong B, Peng S (2001) Microporous Mesoporous Mater 47:15
Li J, Xu X, Hao Z, Zhao W (2008) J Porous Mater 15:163
Taguchi A, Schüth F (2005) Microporous Mesoporous Mater 77:1
Wu C, Kong Y, Gao F, Wu Y, Lu Y, Wang J, Dong L (2008) Microporous Mesoporous Mater 113:163
Garvalho WA, Varaldo PB, Wallau M, Schuchardt U (1997) Zeolites 18:408
Araujo RS, Azevedo DCS, Rodrıguez-Castellon E, Jimenez-Lopez A, Cavalcante CL Jr (2008) J Mol Catal 281:154
Todorova S, Parvulescu V, Kadinov G, Tenchev K, Somacescu S, Su B-L (2007) Microporous Mesoporous Mater 113:22
Bechara R, Balloy D, Vanhove D (2001) Appl Catal A 207:343
Song D, Li J (2006) J Mol Catal A 247:206
Vrålstad T, Øye G, Rønning M, Glomm WR, Stöcker M, Sjöblom J (2005) Microporous Mesoporous Mater 80:291
Rosynek MP, Sewell CA, Makhothe RA, Micklethwaite C, Manstein H, de Lange M, O’Connor CT (1991) Appl Catal 73:97
Boudjahem G, Monteverdi S, Mercy M, Bettahar MM (2004) J Catal 221:325
Van Steen E, Swell GS, Makhothe RA, Micklethwaite C, Manstein H, de Lange M, O’Connor CT (1996) J Catal 162:220
Khodakov Y, Zholobenko VL, Bechara R, Durand D (2005) Microporous Mesoporous Mater 79:29
Okamoto Y, Nagata K, Adachi T, Imanaka T, Inamura K, Takyu T (1991) J Phys Chem 95:310
Khodakov Y, Bechara R, Griboval-Constant A (2003) Appl Catal A 254:273
Reuel RC, Bartholomew CH (1984) J Catal 85:63
Jasik A, Wojcieszak R, Monteverdi S, Ziolek M, Bettahar MM (2005) J Mol Catal A 242:81
Castner DG, Watson PR, Chan IY (1990) J Phys Chem 94:819
Panpranot J, Goodwin JG Jr, Sayari A (2002) Catal Today 77:269
Iglesia E (1997) Appl Catal A 161:59
Bouriskas K, Kordulis C, Vakros J, Lycourghiotis A (2004) Adv Colloid Interface Sci 110:97
Khodakov AY, Griboval-Constant A, Bechara R, Villian F (2001) J Phys Chem B 105:9805
Spasova I, Ivanov G, Georgescu V, Mehandjiev D (2006) J Univ Chem Technol Metall 41:225
Xu D, Li W, Duan H, Ge Q, Xu H (2005) Catal Lett 102:229
Jablonski JM, Okal J, Potoczna-Petru D, Krajczyk L (2003) J Catal 220:146
Jongsomjit B, Goodwin JG Jr (2002) Catal Today 77:191
Szegedi A, Popova M, Mavrodinova V, Minchev C (2008) Appl Catal 338:44
Kim J, Dunn BC, Cole P, Turpin G, Ernst RD, Pugmire RJ, Kang M, Kim JM, Eyring EM (2005) Chem Commun 1462
Katsoulidis AP, Petrakis DE, Armatas GS, Trikalitis PN, Pomonis PJ (2006) Microporous Mesoporous Mater 92:71
Ming H, Baker BG (1995) Appl Catal 123:36
Chen L, Horiuchi T, Mori T, Maeda K (1999) J Phys Chem B 103:1216
Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548
Ravikovitch PI, Neimark AV (2001) J Phys Chem B 105:6817
Anunziata OA, Beltramone AR, Cussa J (2008) Catal Today 134–135:891
Li H, Wang S, Liang F, Li J (2006) J Mol Catal A 244:33
Suvanto S, Pakkanen TA (2000) J Mol Catal A 164:273
Jentys A, Kleestorfer K, Vinek H (1999) Microporous Mesoporous Mater 27:321
Lou Z, Wang R, Sun H, Chen Y, Yang Y (2008) Microporous Mesoporous Mater 110:347
Cordi EM, O’Neill PJ, Falconer JL (1997) Appl Catal B 14:23
Gaur V, Sharma A, Verma N (2005) Carbon 43:3041
Antunes AP, Ribeiro MF, Silva JM, Ribeiro FR, Magnoux P, Guisnet M (2001) Appl Catal B 33:149
Subrahmanyam Ch, Louis B, Rainone F, Viswanathan B, Renken A, Varadarajan K (2003) Appl Catal 241:205
Acknowledgements
Financial support by the Hungarian Research Fund (OTKA, Project No. F61972), by the project BУ-X-305/07 and the Bulgarian-Hungarian Inter-academic Exchange Agreement are greatly acknowledged. The authors thank to Dr. M. Dimitrov and Dr. N. Kostova for the N2 physisorption and DR UV–Vis measurements, respectively.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Szegedi, Á., Popova, M. & Minchev, C. Catalytic activity of Co/MCM-41 and Co/SBA-15 materials in toluene oxidation. J Mater Sci 44, 6710–6716 (2009). https://doi.org/10.1007/s10853-009-3600-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3600-y