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Dielectric response features and oxygen migration on rare earth modified lead titanate ferroelectric ceramics

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Abstract

Rare earth (RE) and manganese-modified lead titanate ceramics were studied concerning the presence of two peaks in the temperature dependence of the dielectric permittivity. An eventual incorporation of the RE into A-site and/or B-site in the perovskite structure and the oxygen migration were considered as causes of the observed phenomenon. The structural analysis showed that at least a small amount of Ti4+ could be substituted by the RE ions. It was considered from the pyroelectric and electrical conductivity results that, even when an eventual incorporation of the RE into the A-site and/or B-site of the structure could be possible, both peaks could not be associated with paraelectric–ferroelectric (PE-FE) phase transitions. The observed peak at lower temperatures has been associated with the PE-FE phase transitions, whereas the hopping of oxygen vacancies has been considered as the cause for the dielectric anomaly observed at higher temperatures.

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Acknowledgements

The authors wish to thank the Third World Academy of Sciences (RG/PHYS/LA No. 99-050, No. 02-225, No. 05-043) and FAPESP Brazilian agency (Proc. No. 06/60013-5) for financial support, and ICTP for financial support of Latin-American Network of Ferroelectric Materials (NET-43). Dr. Peláiz-Barranco wishes to thank Universidad Autónoma de Madrid for financial support. Dr. Calderón-Piñar wishes to thank the ICTP program for Training and Research in Italian laboratories.

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Authors and Affiliations

  1. Facultad de Física-Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana. San Lázaro y L, Vedado, La Habana, 10400, Cuba

    A. Peláiz-Barranco, F. Calderón-Piñar & O. García-Zaldívar

  2. Departamento de Física e Química, Universidade Estadual Paulista, 15385-000, Ilha Solteira, SP, Brazil

    J. D. S. Guerra

  3. Departamento de Física de Materiales, Facultad de Ciencias, Universidad Autónoma de Madrid, 28049, Madrid, Spain

    C. Aragó & J. A. Gonzalo

  4. Departamento de Física Aplicada, ICIMAF, CITMA 15 # 551, Vedado, La Habana, 10400, Cuba

    R. López-Noda

  5. Departamento de Física, Universidade Federal de São Carlos, Rod. Wash. Luis, km. 235, 13.565-905, Sao Carlos, SP, Brazil

    J. A. Eiras

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  1. A. Peláiz-Barranco
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  2. J. D. S. Guerra
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  3. F. Calderón-Piñar
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  4. C. Aragó
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  5. O. García-Zaldívar
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  6. R. López-Noda
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  7. J. A. Gonzalo
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  8. J. A. Eiras
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Correspondence to A. Peláiz-Barranco.

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Peláiz-Barranco, A., Guerra, J.D.S., Calderón-Piñar, F. et al. Dielectric response features and oxygen migration on rare earth modified lead titanate ferroelectric ceramics. J Mater Sci 44, 204–211 (2009). https://doi.org/10.1007/s10853-008-3100-5

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  • DOI: https://doi.org/10.1007/s10853-008-3100-5

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