Abstract
The non-radiative transition processes on non-doped Zn2SiO4 and Zn2SiO4:Mn powders with various Mn concentrations were studied by photoacoustic (PA) spectroscopy. Zn2SiO4:Mn x powders were prepared by dry reaction within an evacuated silica glass tube. As the result of photoluminescence (PL) measurement, the increase of PL intensity for green emission on samples doped with Mn between 1% and 6% and the concentration quenching for luminescence on samples doped with Mn between 7% and 12% were confirmed. For the green luminescence on zinc silicate doped with Mn phosphor, the PL decay behavior is assumed to be due to tunneling directly from excited states of electron traps to the excited states of Mn-ion. The Mn content dependence of PL intensity for green emission is well interpreted by tunneling theory and the results of PA spectra, that is, the green emission is assisted by tunneling from non-radiative levels of Mn-ion to luminescencet level as 4T1(4G).
Similar content being viewed by others
References
Yoon C, Kang S (2001) J Mater Res 16:1210
Lee CH, Kang YC, Jung KY, Choi JG (2005) Mater Sci Eng B 117:210
Shon K-S, Cho B, Park HD (1999) Mater Lett 41:303
Kang YC, Park SB (2000) Mater Res Bull 35:1143
Copeland TS, Lee BI, Qi J, Elrod AK (2002) J Lumin 97:168
Cho TH, Chang HJ (2003) Ceramics International 29:611
Wang H, Ma Y, Yi G, Chen D (2003) Mater Chem Phys 82:414
Zhang QY, Pita K, Kam CH (2003) J Phys Chem Solids 64:333
Natarajan V, Murthy KVR, Kumar MLJ (2005) Solid State Commun 134:261
Chang IF, Thioulouse P, Mendez EE, Giess EA, Dove DB, Takamori T (1981) J Lumin 24/25:313
Brownlow JM, Chang IF (1983) IEEE Trans Electron Devices ED-30:479
Chang IF, Brownlow JW, Sun TI, Wilson JS (1989) J Electrochem Soc 136:3532
Barthou C, Benoit J, Benalloul P (1994) J Electrochem Soc 141:525
Li QH, Komarneni S, Roy R (1995) J Mater Sci 30:2358
Sohn K-S, Cho B, Park HD (1999) J Am Ceram Soc 82:2779
Dove DB, Takamori T, Chang IF, Thioulouse P, Mendez EE, Giess EA (1981) J Lumin 24/25:317
Rosencwaig A, Gersho A (1976) J Appl Phys 47:64
Inoue Y, Okamoto M, Kawahara T, Morimoto J (2006) J Alloys Compd 408-412:1234
Inoue Y, Miyauchi Y, Kimura A, Kawahara T, Okamoto Y, Morimoto J (2004) Jpn J Appl Phys 43:2936
. Okamoto M, Inoue Y, Kawahara T, Morimoto J (2005) Jpn J Appl Phys 44:4461
Peters TE, Baglio JA (1972) J Electrochem Soc 119:230
Vanheusden K, Warren WL, Seager CH, Tallant DR, Voigt JA, Gnade BE (1996) J Appl Phys 79:7983
Hess H, Krautz E (1981) J Lumin 24/25:321
Yang ES, Brownlow JM (1981) Appl J Phys 52:4753
Chang IF, Thioulouse (1982) Appl J Phys 53:5873
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Inoue, Y., Toyoda, T. & Morimoto, J. Photoacoustic spectra on Mn-doped zinc silicate powders by evacuated sealed silica tube method. J Mater Sci 43, 378–383 (2008). https://doi.org/10.1007/s10853-006-1243-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-1243-9