Abstract
The trivalent samarium ions doped with different concentrations of ZnO NPs in silicate glasses were prepared by the sol–gel technique. The structural and optical properties were characterized by using X-ray diffraction, Fourier transform infrared, scanning electron microscope, transmission electron microscope, optical absorption, and photoluminescence measurements at room temperature respectively. The structural analysis from X-ray diffraction, scanning electron microscope, and transmission electron microscope results confirmed the hexagonal wurtzite ZnO structure of all the nanoparticle samples. The evaluation has been made for the dependence of various radiative parameters along with the Judd–Ofelt of Sm3+ on the concentration of ZnO NPs. The effective network changing the nature of ZnO NPs has been revealed by the high value of Ω2 obtained in this system matrix. In the current investigation, the silica matrix's emission transition 4G5/2 → 6H9/2 of Sm3+, which corresponds to the red color observed at 653 nm, demonstrated excellent radiative behavior compared to other commonly used glass hosts. These results suggest that Sm3+ ions doped with ZnO NPs in sol–gel silicate glasses can be more efficient luminescent materials in the field of lasers and optical devices in the visible region. CIE Chromaticity diagram observed that these coordinates fall in the bluish-purple to yellowish-orange region.
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H. Takahashi, High performance planar light wave circuit devices for large capacity transmission. Optic Expr. 19, 173–180 (2011)
T. Kakkar, N. Bamiedakis, T.T. Fernandez, Z. Zhao, M. Irannejad, P. Steenson, A. Jha, R. Penty, I. White, G. Jose, Glass–polymer super lattice for integrated optics. Opt. Eng. 53, 071818 (2014). https://doi.org/10.1117/1.OE.53.7.071818
S. Berneschi, A. Chiappini, M. Ferrari, S. Pelli, G.C. Righini, Erbium doped silica-hafnia glass ceramic waveguides. Phys. Status Solidi 8, 2875–2879 (2011). https://doi.org/10.1002/pssc.201084101
N.Q. Vinh, N.N. Ha, T. Gregorkiewicz, Photonic properties of Er-doped crystalline silicon. Proc. IEEE 97, 1269–1282 (2009). https://doi.org/10.1109/JPROC.2009
A. Chiasera, C. Meroni, F. Scotognella, Y.G. Boucher, G. Galzerano, A. Lukowiak, Coherent emission from fully Er3+ doped monolithic 1-D dielectric micro-cavity fabricated by rf-sputtering. Opt. Mater. 87, 107–111 (2019). https://doi.org/10.1016/j.optmat.2018.04.057
B. Meenatchi, V. Sathiya Lakshmi, A. Manikandan, V. Renuga, A. Sharmila, K.R. Nandhine Deve, S.K. Jaganathan, Protic ionic liquid assisted synthesis and characterization of ferromagnetic cobalt oxide nanocatalyst. J. Inorg. Organomet. Polym. 27, 446–454 (2017)
A. Manikandan, M. Durka, K. Seevakan, S. Arul Antony, A novel one-pot combustion synthesis and opto-magnetic properties of magnetically separable spinel MnxMg1-xFe2O4 (0.0≤x≤ 0.5) Nanophotocatalysts. J. Supercond. Nov. Magn. 28, 1405–1416 (2015)
A. Manikandan, M. Durka, S. Arul Antony, A novel synthesis, structural, morphological, and opto-magnetic characterizations of magnetically separable spinel CoxMn1-xFe2O4 (0≤ x≤ 1) nano-catalysts. J. Supercond. Nov. Magn. 27, 2841–2857 (2014)
E. Manikandan, M.K. Moodley, S.S. Ray, B.K. Panigrahi, R. Krishnan, K.G.M. Nair, A.K. Tyagi, Zinc oxide epitaxial thin-film deposited over carbon on various substrates by PLD technique. J. Nanosci. Nanotechnol. 10, 5601–5611 (2010)
J.F. Zhu, Y.J. Zhu, Microwave-assisted one-step synthesis of polyacrylamide-metal (M = Ag, Pt, Cu) nanocomposites in ethylene glycol. J. Phys. Chem. B 110, 8593–8597 (2006)
N.C.S. Selvam, A. Manikandan, L. John Kennedy, J. Judith Vijaya, Comparative investigation of zirconium oxide (ZrO2) nano and microstructures for structural, optical and photocatalytic properties. J. Colloid Inter. Sci. 389, 91–98 (2013)
A.H. Shah, E. Manikandan, M.B. Ahmed, Enhanced bioactivity of Ag/ZnO nanorods-a comparative antibacterial study. J. Nanomed. Nanotech. 4, 6 (2013)
J. Kennedy, P.P. Murmu, J. Leveneur, A. Markwitz, J. Futter, Controlling preferred orientation and electrical conductivity of zinc oxide thin films by post growth annealing treatment. Appl. Surf. Sci. 367, 52–58 (2016)
E. Manikandan, J. Kennedy, G. Kavitha, K. Kaviyarasu, M. Maaza, B.K. Panigrahi, U. Kamachi Mudali, Hybrid nanostructured thin-films by PLD for enhanced field emission performance for radiation micro-nano dosimetry applications. J. Alloys & Comps 647, 141–145 (2015)
J. Kennedy, B. Sundrakannan, R.S. Katiyar, A. Markwitz, Z. Li, W. Gao, Raman scattering investigation of hydrogen and nitrogen ion implanted ZnO thin films. Curr. Appl. Phys. 8, 291–294 (2008)
P.P. Murmu, J. Kennedy, G.V.M. Williams, B.J. Ruck, S. Granville, S.V. Chong, Observation of magnetism, low resistivity, and magnetoresistance in the near-surface region of Gd implanted ZnO. Appl. Phys. Lett. 101, 082408 (2012)
J. Kennedy, G.V.M. Williams, P.P. Murmu, B.J. Ruck, Intrinsic magnetic order and inhomogeneous transport in Gd-implanted zinc oxide. Phys. Rev. B 88, 214423 (2013)
C.P. Reddy, V. Naresh, B.C. Babu, Photoluminescence and energy transfer process in Bi3+ /Sm3+ Co-doped phosphate zinc lithium glasses. Adv. Mater. Phys. Chem. 4, 165–171 (2014)
J.F. Sanchez-Royo, G. Munoz-Matutano, M. Brotons-Gisbert, J.P. Martínez-Pastor, A. Segura, A. Cantarero, R. Mata, J. Canet-Ferrer, G. Tobias, E. Canadell, J. Marqués-Hueso, B.D. Gerardot, Electronic structure, optical properties, and lattice dynamics in atomically thin indium selenide flakes. Nano Res. 7, 1556–1568 (2014)
I.A. Auwalu, M.A.Y. Hotoro, U.H. Jamo, D.G. Diso, Effect of samarium oxide on structural and optical properties of zinc silicate glass ceramics from waste material. Nano Hybrids Compos 22, 35–46 (2018). https://doi.org/10.4028/www.scientific.net/NHC.22.35
K. Bhujel, S.S. Ningthoujam, L.R. Singh, S. Rai, Effect of solution aging on properties of spin coated zinc oxide thin films. Mater Today Proce. 46, 56–61 (2019). https://doi.org/10.1016/j.matpr.2020.07.099
R. John, R. Rajakumari, Synthesis and characterization of rare earth ion doped nano ZnO. Nanomicro Lett 4, 65–72 (2012). https://doi.org/10.3786/nml.v4i2.p65-72
U. Alam, A. Khan, D. Ali, D. Bahnemann, M. Muneer, Comparative photocatalytic activity of sol-gel derived rare earth metal (La, Nd, Sm and Dy)-doped ZnO photocatalysts for degradation of dyes. RSC Adv. 8, 17582–17594 (2018). https://doi.org/10.1039/c8ra01638k
E.E. Campos-Zuniga, I.L. Alonso-Lemus, V. Agarwal, J. Escorcia-Garcia, Sol-gel synthesis for stable green emission in samarium doped borosilicate glasses. Ceram In 45, 24052–24059 (2019). https://doi.org/10.1016/j.ceramint.2019.08.110
D.A. Wheeler, J.Z. Zhang, Exciton dynamics in semiconductor nanocrystals. Adv. Mater. 25, 2878–2896 (2013). https://doi.org/10.1002/adma.201300362
M. Novotny, E. Maresova, P. Fitl, J. Vlcek, M. Bergmann, M. Vondracek, R. Yatskiv, J. Bulr, P. Hubk, P. Hruska, Drahokoupil, N. Abdellaoui, M. Vrnata, J. Lancok, The properties of samarium-doped zinc oxide/phthalocyanine structure for optoelectronics prepared by pulsed laser deposition and organic molecular evaporation. Appl. Phys. A 122, 1–8 (2016). https://doi.org/10.1007/s00339-016-9759-6
M. Vishwas, B.R. Nagabushana, D. Joseph, K.V.A. Gowda, S.B. Gandla, Low temperature combustion synthesis and characterization of undoped and samarium doped zinc oxide nanoparticles. J. Adv. Sci. Res. 13, 37–40 (2022). https://doi.org/10.55218/jasr.202213406
J. Nath Mirdda, S. Mukhopadhyay, K. Ranjan Sahu, M. Nanda Goswami, C. Author, Enhancement of optical properties and dielectric nature of Sm3+ doped Na2O-ZnO-TeO2 Glass materials. J. Phys. Chem. Solids 167, 110776 (2022). https://doi.org/10.1016/j.jpcs.2022.110776
K. Badreddine, A. Srour, R. Awad, A.I. Abou-Aly, The investigation of mechanical and dielectric properties of Samarium doped ZnO nanoparticles. Mater Res Express 7, 78–85 (2020). https://doi.org/10.1088/2053-1591/ab7064
I.A. Auwalu, M.A.Y. Hotoro, U.H. Jamo, D.G. Diso, Effect of samarium oxide on structural and optical properties of zinc silicate glass ceramics from waste material. Nano Hybrids and Composites 22, 35–46 (2018). https://doi.org/10.4028/www.scientific.net/nhc.22.35
N.F. Andrade Neto, R.G. Carvalho, L.M. Garcia, R.M. Nascimento, C.A. Paskocimas, E. Longo, M.R. Delmonte, F.V. Motta, Influence of doping with Sm3+ on photocatalytic reuse of ZnO thin films obtained by spin coating. Revista Materia 24, 678–684 (2019). https://doi.org/10.1590/s1517-707620190004.0814
M. Faraz, F.K. Naqvi, M. Shakir, N. Khare, Synthesis of samarium-doped zinc oxide nanoparticles with improved photocatalytic performance and recyclability under visible light irradiation. New J. Chem. 42, 2295–2305 (2018). https://doi.org/10.1039/c7nj03927a
Y. Hanifehpour, B. Soltani, A.R. Amani-Ghadim, B. Hedayati, B. Khomami, S.W. Joo, Synthesis and characterization of samarium-doped ZnS nanoparticles: a novel visible light responsive photocatalyst. Mater. Res. Bull. 76, 411–421 (2016). https://doi.org/10.1016/j.materresbull.2015.12.035
R. Mondal, D. Biswas, A.S. Das, R.N. Ningthemcha, D. Deb, S. Bhattacharya, S. Kabi, Influence of samarium content on structural, thermal, linear and non-linear optical properties of ZnO–TeO2–P2O5 glasses. Mater. Chem. Phys. 255, 932–938 (2020). https://doi.org/10.1016/j.matchemphys.2020.123561
I. Pal, A. Agarwal, S. Sanghi, M.P. Aggarwal, Investigation of spectroscopic properties, structure and luminescence spectra of Sm3+ doped zinc bismuth silicate glasses. Spectro. Acta A. Mol. Biol. Spectrosc 101, 74–81 (2013). https://doi.org/10.1016/j.saa.2012.09.047
Nguyen Minh Ty, Dacheng Zhou, Jianbei Qiu, Ho Kim Dan, Broadband flat near/mid-infrared emissions of Tm3+–Ho3+ co-doped, and Tm3+–Ho3+–Yb3+ tri-doped zinc silicate glasses under 808 and 980 nm laser diode excitations. Infrared Phys. Technol. 111, 103483 (2020). https://doi.org/10.1016/j.infrared.2020.103483
M. GuguHlengiwe, Luminescence Investigation of Trivalent Rare Earth Ions in Sol- Gel Derived SiO2 and ZnO co-doped Sio2:Pr3+, University of Free State, 2011.
K. Kajihara, Recent advances in sol-gel synthesis of monolithic silica and silica-based glasses. J. Asian Ceram. Soc. 1, 121–133 (2013). https://doi.org/10.1016/j.jascer.2013.04.002
V. Kumar, O.M. Ntwaeaborwa, T. Soga, V. Dutta, H.C. Swart, Rare earth doped zinc oxide nanophosphor powder : a future material for solid state lighting and solar cells. ACS Photonics 4, 2613–2637 (2017). https://doi.org/10.1021/acsphotonics.7b00777
H. Kozuka, Handbook of sol-gel science and technology: processing, characterization, and applications (Kluwer Academic Publisher, New York, 2005). https://doi.org/10.5860/choice.42-5885
L.T.T. Hiena, N. Van Dub, N.N. Hab, N.D. Hoab, T.N. Khiemb, N.D. Chiena, Optical Materials Photoluminescence enhancement OF Er3+-doped ZnO/SiO2 nanocomposites fabricated through two-step synthesis. Opt. Mater. 92, 262–266 (2019). https://doi.org/10.1016/j.optmat.2019.04.043
M. Xiaoqi, L. Lianqiang, Z. Kaishun, L. Juncheng, The effect of SiO2 on TiO2 up-conversion photoluminescence film. Opt. Mater. 37, 367–370 (2014). https://doi.org/10.1016/j.optmat.2014.06.027
D.S.C. Halin, M.M.A.B. Abdullah, N. Mahmed, S.N.A. Abdul Malek, P. Vizureanu, A.W. Azhari, Synthesis and characterization of TiO2/SiO2 thin film via sol-gel method. IOP Conf. Ser. Mater. Sci. Eng. 209, 87–96 (2017). https://doi.org/10.1088/1757-899X/209/1/012002
C. Agustín-Saenz, J.A. Sanchez-García, M. Machado, M. Brizuela, O. Zubillaga, A. Tercjak, Broadband antireflective coating stack based on mesoporous silica by acid-catalyzed sol-gel method for concentrated photovoltaic application. Sol. Energy Mater. Sol. Cells 186, 154–164 (2018). https://doi.org/10.1016/j.solmat.2018.06.040
T.T.V. Tran, T.M.D. Cao, Q.V. Lam, V.H. Le, Emission of Eu3+ in SiO2-ZnO glass and SiO2-SnO2 glass-ceramic: correlation between structure and optical properties of Eu3+ ions. J. Non Cryst. Solids 459, 57–62 (2017). https://doi.org/10.1016/j.jnoncrysol.2016.12.040
X. Sun et al., Preparation of MgF2/SiO2 coating with broadband antireflective coating by using sol–gel combined with electron beam evaporation. Opt. Mater. 101, 2–10 (2020). https://doi.org/10.1016/j.optmat.2020.109739
C.S. Lee, K.A. Matori, S.H. Ab Aziz, H.M. Kamari, I. Ismail, M.H.M. Zaid, Fabrication and characterization of glass and glass-ceramic from rice husk ash as a potent material for optoelectronic applications. J. Mater. Sci. Mater. Electron. 28, 17611–17621 (2017). https://doi.org/10.1007/s10854-017-7699-3
F. Xiao et al., Efficient energy transfer and enhanced infrared emission in Er-doped ZnO-SiO2 composites. J. Phys. Chem. C 116(24), 13458–13462 (2012). https://doi.org/10.1021/jp304075g
K.M.S. Dawngliana, A.L. Fanai, S. Rai, Structural and optical studies of Sm3+-doped silica glass along with TiO2 nanoparticles for photonic applications. J. Non-Cryst. Solids 607, 122226 (2023)
K.R. Kandula, A. Sarkar, B.S. Bhaktha, Sol-gel fabrication and characterization of ZnO and Zn2SiO4 nanoparticles embedded silica glass-ceramic waveguides. Opt. Mater. Expr. 3, 2078–2085 (2013)
Z. Fu, B. Yang, L. Li, W. Dong, C. Jia, W. Wu, An intense ultraviolet photoluminescence in sol–gel ZnO–SiO2 nanocomposites. J. Phys. Condens. Matter 15(17), 2867–2873 (2003)
N.M. Shamhari, B.S. Wee, S.F. Chin, K.Y. Kok, Synthesis and characterization of zinc oxide nanoparticles with small particle size distribution. Acta Chim. Slov. 65, 578–585 (2018)
S. Talam, S.R. Karumuri, N. Gunnam, Synthesis characterization, and spectroscopic properties of ZnO nanoparticles. ISRN Nanotechnol. 2012, 1–6 (2012)
K.M.S. Dawngliana, S. Rai, Linear and nonlinear and optical properties of Sm3+ co-doped alumino-silicate glass prepared by sol-gel method. J. Non-Cryst. Solids 598, 121929 (2022)
W.T. Carnall, P.R. Fields, K. Rajnak, Electronic energy levels in the trivalent lanthanide aquo ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, Tm3+. J. Chem. Phys. 49, 4424–4442 (1968). https://doi.org/10.1063/1.1669893
W.T. Carnall, H. Cross white and H.M. Cross white, Energy level structure and transition probabilities in the spectra of the trivalent lanthanides in LaF3, Argonne National Laboratory, Report no. ANL-78-XX-95, 1978.
N. Dehingia, P. Gogoi, D. Kakoti, N. Rajkonwar, A. Boruah, P. Dutta, Effect of Ag nanoparticles on the Judd-Ofelt and radiative parameters of Sm3+ ions in sol–gel silica matrix. J. Lumin. 226, 117414 (2020)
K.M.S. Dawnglianaa, A.L. Fanai, S. Rai, Structural and spectroscopic properties of Eu3+ ions in alumino-silicate glass. Indian J. Pure Appl. Phys. 61, 182–189 (2023). https://doi.org/10.56042/ijpap.v61i3.71028
K.M.S. Dawngliana, A.L. Lalruatpuia, S. Fanai, Rai, Optical basicity and electronic polarizability of Sm3+-doped silica glass prepared by sol–gel process. Mat. Today Proce. 65, 2572–2577 (2022). https://doi.org/10.1016/j.matpr.2022.04.784
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The authors are thankful to the Department of Science and Technology New Delhi (India) for financial support (No. SR/S2/LOP-0039/2010).
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KMS Dawngliana: investigation, data curation, visualization, conceptualization, methodology, writing review, editing. Kamal Bhujel: investigation, data curation. S. Rai: investigation, visualization, review, data curation, editing, supervision.
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Dawngliana, K.M.S., Bhujel, K. & Rai, S. Effect of ZnO nanoparticles on the Judd–Ofelt and radiative parameters of Sm3+ ions in sol–gel silica matrix. Appl. Phys. A 130, 268 (2024). https://doi.org/10.1007/s00339-024-07435-5
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DOI: https://doi.org/10.1007/s00339-024-07435-5