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(Plasticized) Polylactide/clay nanocomposite textile: thermal, mechanical, shrinkage and fire properties

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Abstract

Various quantities of Cloisite® 30B (from 1% to 4% in weight) have been added to a polylactide matrix by melt blending to produce polylactide-based nanocomposites. Then, these blends have been melt-spun to produce multifilaments yarns. It is demonstrated that it is necessary to use a plasticizer to spin a blend with 4% in weight of Cloisite® 30B. The properties of these yarns have been studied (dispersion of the clay, thermal, mechanical and shrinkage properties). A decrease of the tensile properties is observed when the quantity of Cloisite® 30B increases, but an improvement of the thermal and shrinkage properties is highlighted. These multifilaments have been knitted and the flammability studied using cone calorimeter at 35 kW/m2. A strong decrease, up to 38%, of the heat release rate has been measured.

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References

  1. Agrawal AK, Bhalla R (2003) J Macromol Sci Part C Polym Rev C43:479

    Article  CAS  Google Scholar 

  2. Postema AR, Luiten AH, Pennings AJ (1990) J Appl Polym Sci 49:1265

    Article  Google Scholar 

  3. Postema AR, Luiten AH, Oostra H, Pennings AJ (1990) J Appl Polym Sci 49:1275

    Article  Google Scholar 

  4. Tsuji H, Ikada Y, Hyon S-H, Kimura Y, Kitao T (1994) J Appl Polym Sci 51:337

    Article  CAS  Google Scholar 

  5. Horacek I, Kalisek V (1994) J Appl Polym Sci 54:1751

    Article  CAS  Google Scholar 

  6. Horacek I, Kalisek V (1994) J Appl Polym Sci 54:1759

    Article  CAS  Google Scholar 

  7. Eling B, Gogolewski S, Pennings AJ (1982) Polymer 23:1587

    Article  CAS  Google Scholar 

  8. Leenslag JW, Pennings AJ (1987) Polymer 28:1695

    Article  CAS  Google Scholar 

  9. Schmack G, Jehnichen D, Vogel R, Tändler B, Beyreuther R, Jacobsen S, Fritz H-G (2001) J Biotech 86:151

    Article  CAS  Google Scholar 

  10. Schmack G, Tändler B, Optiz G, Vogel R, Komber H, Häuβler L, Voigt D, Weinmann S, Heinemann M, Fritz H-G (2004) J Appl Polym Sci 91:800

    Article  CAS  Google Scholar 

  11. Mezghani K, J.E Spruiell (1998) J Polym Sci Part B Polym Phys 36:1005

    Article  CAS  Google Scholar 

  12. Schmack G, Tändler B, Vogel R, Beyreuther R, Jacobsen S, Fritz H-G (1999) J Appl Polym Sci 73:2785

    Article  CAS  Google Scholar 

  13. Takasaki M, Ito H, Kikutani T (2003) J Macromol Sci Part B Phys 42: 57

    Article  CAS  Google Scholar 

  14. Fambri L, Pegoretti A, Fenner R, Incardona SD, Migliaseri C (1997) Polymer 38:79

    Article  CAS  Google Scholar 

  15. Cicero JA, Dorgan JR, Dec SF, Knauss DM (2002) Polym Degrad Stab 78:95

    Article  CAS  Google Scholar 

  16. Solarski S, Ferreira M, Devaux E (2005) Polymer 46:11187

    Article  CAS  Google Scholar 

  17. Solarski S, Ferreira M, Devaux E (2006) J Textile Instit (accepted)

  18. Alexandre M, Dubois P (2000) Mat Sci Eng 28:1

    Article  Google Scholar 

  19. Sinha Ray S, Okamoto M (2003) Prog Polym Sci 28:1539

    Article  CAS  Google Scholar 

  20. Morgan AB, Gilman JW (2003) J Appl Polym Sci 87:1329

    Article  CAS  Google Scholar 

  21. Bourbigot S, Vanderhart DL, Gilman JW, Awad WH, Davis RD, Morgan AB, Wilkie C, (2003) J Polym Sci Part B Polym Phys 41:3188

    Article  CAS  Google Scholar 

  22. Krikorian V, Pochan DJ (2003) Chem Mater 15:4317

    Article  CAS  Google Scholar 

  23. Wu T, Chiang MF (2005) Polym Eng Sci 45:1615

    Article  CAS  Google Scholar 

  24. Paul MA, Alexandre M, Degée P, Henrist C, Rulmont A, Dubois P (2003) Polymer 44:443

    Article  CAS  Google Scholar 

  25. Pluta M, Galeski A, Alexandre M, Paul M-A, Dubois P (2002) J Appl Polym Sci 86:1497

    Article  CAS  Google Scholar 

  26. Nam PH, Fujimori A, Masuko T (2004) J Appl Polym Sci 93:2711

    Article  CAS  Google Scholar 

  27. Di Y, Iannace S, Di Maio E, Nicolais L (2005) J Polym Sci Part B Polym Phys 43:689

    Article  CAS  Google Scholar 

  28. Pluta M (2004) Polymer 45:8239

    Article  CAS  Google Scholar 

  29. Paul MA, Alexandre M, Degée P, Calberg C, Jérôme R, Dubois P (2003) Macromol Rapid Commun 24:561

    Article  CAS  Google Scholar 

  30. Paul MA, Delcourt C, Alexandre M, Degée P, Monteverde F, Rulmont A, Dubois P (2005) Macromol Chem Phys 206:484

    Article  CAS  Google Scholar 

  31. Martin O, Avérous L (2001) Polymer 42:6209

    Article  CAS  Google Scholar 

  32. Baiardo M, Frisoni G, Scandola M, Rimelen M, Lips D, Ruffieux K, Wintermantel E (2003) J Appl Polym Sci 90:1731

    Article  CAS  Google Scholar 

  33. Ljungberg N, Wesslen B (2002) J Appl Polym Sci 86:1227

    Article  CAS  Google Scholar 

  34. Younes H, Cohn D (1988) Eur Polym J 24:765

    Article  CAS  Google Scholar 

  35. Labrecque LV, Kumar RA, Dave V, Gross RA, Mc-Carthy SP (1997) J Appl Polym Sci 66:1507

    Article  CAS  Google Scholar 

  36. Jacobsen S, Fritz HG (1999) Polym Eng Sci 39:1303

    Article  CAS  Google Scholar 

  37. Bourbigot S, Devaux E, Flambard X (2002) Polym Deg Stab 75:397

    Article  CAS  Google Scholar 

  38. Avrami M (1939) J Chem Phys 7:1103

    Article  CAS  Google Scholar 

  39. Babrauskas V (1982) Development of cone calorimeter-a bench scale, rate of heat release based on oxygen consumption: NBS-IR 82-2611. US Nat Bur Stand, Gaithersburg

  40. Babrauskas V (1984) Fire Mater 8:81

    Article  CAS  Google Scholar 

  41. Sinha S Ray, Okamoto M (2003) Macromol Rapid Commun 24:815

    Article  CAS  Google Scholar 

  42. Kopinke F-D, Remmle M, Mackenzie K, Möder M, Wachsen O (1996) Polym Deg Stab 53:329

    Google Scholar 

  43. Yoon K, Polk MB, Min BG, Schiraldi DA (2004) Polym Intern 53:2072

    Article  CAS  Google Scholar 

  44. Gilman JW (1999) Appl Clay Sci 15:31

    Article  CAS  Google Scholar 

  45. Xiao W, Yu H, Han K, Yu M (2005) J Appl Polym Sci 96:2247

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are very grateful to Interreg III “France-Wallonie”, Région Wallonne, Région Nord Pas de Calais and European Union (FEDER) for the financial support in the frame of interregional project MABIOLAC. SMPC thanks the Belgian Federal Government Office of Science Policy (SSTC-PAI 5/3) for general support and is much indebted to both «Région Wallonne» and the European Commission “FSE and FEDER” for financial support in the frame of Phasing-out Hainaut: Materia Nova.

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Correspondence to Manuela Ferreira.

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Solarski, S., Mahjoubi, F., Ferreira, M. et al. (Plasticized) Polylactide/clay nanocomposite textile: thermal, mechanical, shrinkage and fire properties. J Mater Sci 42, 5105–5117 (2007). https://doi.org/10.1007/s10853-006-0911-0

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  • DOI: https://doi.org/10.1007/s10853-006-0911-0

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