Abstract
In this study, ZrP2O7 was synthesized by the solid state reaction of ZrO2 and NH4H2PO4 at 900 °C. Then, in set 1; 10, 5, 1, 0.5, 0.1, 0.05, 0.03% previously prepared Sr2P2O7 were doped into ZrP2O7, and Sr2P2O7 slightly affect the unit cell parameter of cubic ZrP2O7 (a = 8.248(6)–8.233(8) Å). The reverse of this process was also applied to Sr2P2O7 system (set 2). ZrP2O7 changes the unit cell parameters of orthorhombic Sr2P2O7 in between a = 8.909(5)–8.877(5) Å, b = 13.163(3)–13.12(1) Å, and c = 5.403(2)–5.386(4) Å. Analysis of the vibrations of the P2O 4−7 ion and approximate band assignments for IR and Raman spectra are also reported in this work. Some coincidences in infrared and Raman spectra both sets were found and strong P–O–P bands were observed. Surface morphology, EDX analysis, and thermoluminescence properties of both sets were given the first time in this paper.
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Withers RL, Tabira Y, Evans JSO, King IJ, Sleight AW (2001) J Solid State Chem 157:186
Khosrovani N, Korthuis V, Sleight AW (1996) Inorg Chem 35:485
Lisnyak VV, Stus NV, Slobodyanik NS, Belyavina NM, Markiv VYA (2000) J Alloys Compd 309:83
Gover RKB, Withers ND, Allen S, Withers RL, Evans JSO (2002) J Solid State Chem 166:42
Chernaya VV, Mitaev AS, Chizhov PS, Dikarev EV, Shapanchenko RV, Antipov EV, Korolenko MV, Fabritchnyi PB (2005) Chem Mater 17:284
Guler H, Kurtulus F (2005) J Mater Sci 40:6565
Smaalen SV, Dinnebier R, Hanson J, Gollwitzer J, Bullesfeld F, Prokofiev A, Assmus W (2005) J Solid State Chem 178:2225
Kizilyalli M, Darras M (1993) J Solid State Chem 107:373
Kizilyalli M (1987) J Less-Common Metals 127:147
Tie SL, Li YY, Yang YS (1997) J Phys Chem Solids 58(6):957
Ferid M, Horchani-Naifer K (2004) Mater Res Bull 39:2209
Ferid M, Horchani K, Amami J (2004) Mater Res Bull 39:1949
Hamady A, Zid MF, Jouini T (1994) J Solid State Chem 113:120
Trunov VK, Oboznenko YV, Sirotikin SP, Tskhelashvili NB (1990) Inorg Mater 27(9):1993
Trunov VK, Oboznenko YV, Sirotikin SP, Tskhelashvili NB (1991) Inorg Mater 27(11):2370–2374
Ledain S, Leclaire A, Borel MM, Raveau B (1996) Acta Cryst C42:1593
Boutfessi A, Boukhari A, Holt EM (1996) Acta Cryst C42:1594
Boutfessi A, Boukhari A, Holt EM (1996) Acta Cryst C42:1597
Khay N, Ennaciri AA, Harcharras M (2001) Vib Spectrosc 27:119
Khay N, Ennaciri AA (2001) J Alloys Compd 323–324:800
Idrissi MS, Rghioui L, Nejjar R, Benarafa L, Idrissi MS, Lorriaux A, Wallart F (2004) Spectrochim Acta Part A 60:2043
Stock N, Ferey G, Cheetham AK (2000) Solid State Sci 2:307
Assaaoudi H, Butler IS, Kozinski J, Belanger-Gariepy F (2005) J Chem Crystallogr 35(10):809
Varga T, Wilinson AP, Haluska MS, Payzant EA (2005) J Solid State Chem 178:3541
Pelova VA, Grigorov LS (1997) J Luminescence 72–74:241
Kim CH, Yim HS (1999) Solid State Commun 110:137
Marcu IC, Millet JMM, Herrmann JM (2002) Catal Lett 78(1–4):273
Inoue S, Ohtaki N (1993) J Chromatogr 645(1):57
Srilakshmi Ch, Ramesh K, Nagaraju P, Lingaiah N, Prasad PSS (2006) Catal Lett 106(3–4):115
Fukuda K, Moriyama A, Hashimoto S (2004) J Solid State Chem 177:3514
Natarajan V, Bhide MK, Dhobale AR, Godbole SV, Seshagari TK, Page AG, Lu CH (2004) Mater Res Bull 39:2065
Altermatt UD, Brown ID (1987) Acta Cryst A34:125
Pillai VPM, Thomas BR, Nayar VU, Lii KH (1999) Spectrochim Acta Part A 55:1809
Baran EJ, Mercader RC, Massafero A, Kremer E (2004) Spectrochim Acta Part A 60:1001
Acknowledgement
This work was supported by BAP-01-03-DPT-03K-120920/09. The authors also dedicated this paper to the memory of Meral Kızılyallı.
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Seyyidoğlu, S., Özenbaş, M., Yazıcı, N. et al. Investigation of solid solution of ZrP2O7–Sr2P2O7 . J Mater Sci 42, 6453–6463 (2007). https://doi.org/10.1007/s10853-006-0673-8
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DOI: https://doi.org/10.1007/s10853-006-0673-8