Skip to main content
Log in

The effect of ormosil nano-particles on the toughness of a polyester resin

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Organic–inorganic hybrid nano-particles have been synthesized via a modified Stöber method. Nano-particles have been prepared from silica precursors with different organic functionalities. Methyl, ethyl, vinyl and phenyl modified silicas have been synthesized with a view to using these particles as modifiers for polymers and polymer matrix composites. Nano-composites have been produced using polyester as a matrix. The effect of the nano-particles on the toughness of the polyester has been investigated and it is shown that the incorporation of nano-particles leads to an improvement in toughness. For the methyl, ethyl and vinyl ormosils (organically modified silicas) the improvement is minor. The phenyl ormosil gives a greater improvement. This is attributed to different toughening mechanisms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Rowe EH, Siebert AR, Drake RS (1970) Modern Plastics 47:110

    CAS  Google Scholar 

  2. Bascom WD, Ting RY, Moulton RJ, Riew CK, Siebert AR (1981) J Mat Sci 16:2657

    Article  CAS  Google Scholar 

  3. Spanoudakis J, Young RJ (1984) J Mat Sci 19:473

    Article  CAS  Google Scholar 

  4. Spanoudakis J, Young RJ (1984) J Mat Sci 19:487

    Article  CAS  Google Scholar 

  5. Kinloch AJ, Maxwell DL, Young RJ (1985) J Mat Sci 20:4169

    Article  CAS  Google Scholar 

  6. Nakamura Y, Yamaguchi M, Kitayama A, Okubo M, Matsumoto T (1991) Polymer 32:2221

    Article  CAS  Google Scholar 

  7. Nakamura Y, Yamaguchi M, Okubo M, Matsumoto T (1992) Polymer 33:3415

    Article  CAS  Google Scholar 

  8. Lee J-J, Ogin SL, Smith PA (1995) In: Martin RH (ed) Composite materials: fatigue and fracture—5th vol, ASTM STP 1230. American Society for Testing and Materials, Philadelphia p 38

  9. Imanaka M, Takeuchi Y, Nakamura Y, Nishimura A, Iida T (2001) Int J Adhes Adhes 21:389

    Article  CAS  Google Scholar 

  10. Kinloch AJ, Taylor AC (2002) J Mat Sci 37:433

    Article  CAS  Google Scholar 

  11. Bescher E, Mackenzie JD (1998) Mat Sci Eng C6:145

    CAS  Google Scholar 

  12. Lebeau B, Sanchez C (1999) Curr Opin Solid State Mater Sci 4:11

    Article  CAS  Google Scholar 

  13. Bekiari V (2004) Proceedings of the 11th European conference on composite materials, May 2004, Rhodes, Greece, C020

  14. Arkhireeva A, Hay JN (2003) J Mat Chem 13:3122

    Article  CAS  Google Scholar 

  15. Arkhireeva A, Hay JN, Manzano M (2005) Chem Mat 17:875

    Article  CAS  Google Scholar 

  16. Jesson DA, Abel M-L, Arkhireeva A, Hay JN, Smith PA, Watts JF (2004) Surf Interface Anal 36:765

    Article  CAS  Google Scholar 

  17. Jesson DA, Arkhireeva A, Hay JN, Smith PA, Watts JF (2004) In: Proceedings of the 11th European conference on composite materials, May 2004, Rhodes, Greece, C086

  18. Jesson DA, Abel M-L, Hay JN, Smith PA, Watts JF (2006) Langmuir 22:5144

    Article  CAS  Google Scholar 

  19. Rothon RN, Hancock M (1995) In: Particulate-filled composites. Longman Group Ltd., London, pp 1–45

  20. Lange FF (1970) Philos Mag 22:983

    CAS  Google Scholar 

  21. Huang Y, Kinloch AJ (1992) J Mat Sci 27:2763

    Article  CAS  Google Scholar 

  22. Bagheri R, Pearson RA (2000) Polymer 41:269

    Article  CAS  Google Scholar 

  23. Pearson RA, Yee AF (1991) J Mat Sci 26:3828

    Article  CAS  Google Scholar 

  24. Shieu FS (1997) Polymer 38:3135

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to David A. Jesson.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jesson, D.A., Smith, P.A., Hay, J.N. et al. The effect of ormosil nano-particles on the toughness of a polyester resin. J Mater Sci 42, 3230–3237 (2007). https://doi.org/10.1007/s10853-006-0231-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-0231-4

Keywords

Navigation