Abstract
Organic–inorganic hybrid nano-particles have been synthesized via a modified Stöber method. Nano-particles have been prepared from silica precursors with different organic functionalities. Methyl, ethyl, vinyl and phenyl modified silicas have been synthesized with a view to using these particles as modifiers for polymers and polymer matrix composites. Nano-composites have been produced using polyester as a matrix. The effect of the nano-particles on the toughness of the polyester has been investigated and it is shown that the incorporation of nano-particles leads to an improvement in toughness. For the methyl, ethyl and vinyl ormosils (organically modified silicas) the improvement is minor. The phenyl ormosil gives a greater improvement. This is attributed to different toughening mechanisms.
Similar content being viewed by others
References
Rowe EH, Siebert AR, Drake RS (1970) Modern Plastics 47:110
Bascom WD, Ting RY, Moulton RJ, Riew CK, Siebert AR (1981) J Mat Sci 16:2657
Spanoudakis J, Young RJ (1984) J Mat Sci 19:473
Spanoudakis J, Young RJ (1984) J Mat Sci 19:487
Kinloch AJ, Maxwell DL, Young RJ (1985) J Mat Sci 20:4169
Nakamura Y, Yamaguchi M, Kitayama A, Okubo M, Matsumoto T (1991) Polymer 32:2221
Nakamura Y, Yamaguchi M, Okubo M, Matsumoto T (1992) Polymer 33:3415
Lee J-J, Ogin SL, Smith PA (1995) In: Martin RH (ed) Composite materials: fatigue and fracture—5th vol, ASTM STP 1230. American Society for Testing and Materials, Philadelphia p 38
Imanaka M, Takeuchi Y, Nakamura Y, Nishimura A, Iida T (2001) Int J Adhes Adhes 21:389
Kinloch AJ, Taylor AC (2002) J Mat Sci 37:433
Bescher E, Mackenzie JD (1998) Mat Sci Eng C6:145
Lebeau B, Sanchez C (1999) Curr Opin Solid State Mater Sci 4:11
Bekiari V (2004) Proceedings of the 11th European conference on composite materials, May 2004, Rhodes, Greece, C020
Arkhireeva A, Hay JN (2003) J Mat Chem 13:3122
Arkhireeva A, Hay JN, Manzano M (2005) Chem Mat 17:875
Jesson DA, Abel M-L, Arkhireeva A, Hay JN, Smith PA, Watts JF (2004) Surf Interface Anal 36:765
Jesson DA, Arkhireeva A, Hay JN, Smith PA, Watts JF (2004) In: Proceedings of the 11th European conference on composite materials, May 2004, Rhodes, Greece, C086
Jesson DA, Abel M-L, Hay JN, Smith PA, Watts JF (2006) Langmuir 22:5144
Rothon RN, Hancock M (1995) In: Particulate-filled composites. Longman Group Ltd., London, pp 1–45
Lange FF (1970) Philos Mag 22:983
Huang Y, Kinloch AJ (1992) J Mat Sci 27:2763
Bagheri R, Pearson RA (2000) Polymer 41:269
Pearson RA, Yee AF (1991) J Mat Sci 26:3828
Shieu FS (1997) Polymer 38:3135
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jesson, D.A., Smith, P.A., Hay, J.N. et al. The effect of ormosil nano-particles on the toughness of a polyester resin. J Mater Sci 42, 3230–3237 (2007). https://doi.org/10.1007/s10853-006-0231-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0231-4