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Synthesis and structural characterization of nickel(II) hexaazamacrotetracyclic complexes with phthalate ligands

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Abstract

The octahedral nickel(II) complexes, [Ni(L)(tp)]·2H2O (1) and [Ni(L)(isoph)2]·2H2O (2) (L = 1,3,10,12,16,19-hexaazatetracyclo[17,3,1,112.16,04.9]tetracosane, tp2− = terephthalate, isoph2− = isophthalate) were obtained by the reaction of [Ni(L)](ClO4)2·2H2O with corresponding ligands. These complexes have been characterized by X-ray crystallography, spectroscopic and magnetic susceptibility. The crystal structure of 1 shows a distorted octahedral coordination geometry with two secondary and two tertiary amines of the macrocycle and two oxygen atoms of the tp2− ligand, which reveals a 1D coordination polymer. Electronic spectra of the complexes in solid state exhibit a high-spin octahedral environment. The magnetic behavior of 1 reveals a very weak antiferromagnetic interaction with J values of −1.19(3) cm−1.

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References

  1. Yaghi, O.M., Li, H., Davis, C., Richardson, D., Groy, T.L.: Synthetic strategies, structure patterns, and emerging properties in the chemistry of modular porous solids. Acc. Chem. Res. 31, 474 (1998)

    Article  CAS  Google Scholar 

  2. Choi, H.J., Lee, T.S., Suh, M.P.: Self-assembly of a molecular floral lace with one-dimensional channels and inclusion of glucose. Angew. Chem. Int. Ed. 38, 1405 (1999)

    Article  CAS  Google Scholar 

  3. Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O’Keeffe, M., Yaghi, O.M.: Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal−organic carboxylate frameworks. Acc. Chem. Res. 34, 319 (2001)

    Article  CAS  Google Scholar 

  4. Eddaoudi, M., Kim, J., Wachter, J.B., Chae, H.K., O’Keeffe, M., Yaghi, O.M.: Porous metal−organic polyhedra:  25 Å cuboctahedron constructed from 12 Cu2(CO2)4 paddle-wheel building blocks. J. Am. Chem. Soc. 123, 4368 (2001)

    Article  CAS  Google Scholar 

  5. Ferey, G.: Microporous solids: from organically templated inorganic skeletons to hybrid frameworks…ecumenism in chemistry. Chem. Mater. 13, 3084 (2001)

    Article  CAS  Google Scholar 

  6. Choi, H.J., Suh, M.P.: Synthesis, crystal structure, and properties of a 3-D network assembled by nickel(II) macrocyclic complex and terephthalato bridge. Inorg. Chem. 38, 6309 (1999)

    Article  CAS  Google Scholar 

  7. Choi, K.-Y., Chun, K.M., Suh, I.-H.: Synthesis and characterization of one-dimensional nickel(II) macrocyclic complexes with bridging organic ligands. Polyhedron 20, 57 (2001)

    Article  CAS  Google Scholar 

  8. Choi, K.-Y., Chun, K.M., Lee, K.-C., Kim, J.: Synthesis and characterization of nickel(II) complexes of hexaazamacrotetracyclic ligand containing organic ligands. Polyhedron 21, 1913 (2002)

    Article  CAS  Google Scholar 

  9. Choi, H.J., Suh, M.P.: Self-assembly of molecular brick wall and molecular honeycomb from nickel(II) macrocycle and 1,3,5-benzenetricarboxylate: guest-dependent host structures. J. Am. Chem. Soc. 120, 10622 (1998)

    Article  CAS  Google Scholar 

  10. Choi, K.-Y., Kim, K.-J.: Self-assembly of 1D coordination polymers from nickel(II) tetraaza macrocycle and carboxylate ligands. Polyhedron 27, 1311 (2008)

    Article  Google Scholar 

  11. Eddaoudi, M., Kim, J., Wachter, J.B., Chae, H.K., O’Keeffe, M., Yaghi, O.M.: Porous metal−organic polyhedra:  25 Å cuboctahedron constructed from 12Cu2(CO2)4 paddle-wheel building blocks. J. Am. Chem. Soc. 123, 4368 (2001)

    Article  CAS  Google Scholar 

  12. Rochon, F.D., Massarweh, G.: Study of the aqueous reactions of metallic ions with benzenetetracarboxylate ions: Part 2. Crystal structures of compounds of the type M(H2O)5(μ-C6H2(COO)4)M(H2O)5 (M=Mn and Co) and a novel mixed-metallic Mn−Co dimeric compound. Inorg. Chim. Acta 314, 163 (2001)

    Article  CAS  Google Scholar 

  13. Choi, K.-Y.: Synthesis, properties and X-ray crystal structures of nickel(II) complexes of a hexaazamacrotetracyclic ligand. J. Coord. Chem. 56, 481 (2003)

    Article  CAS  Google Scholar 

  14. North, A.C.T., Phillips, D.C., Mathews, F.S.: A semi-empirical method of absorption correction. Acta Cryst. A24, 351 (1968)

    Google Scholar 

  15. Sheldrick, G.M.: A short history of SHELX. Acta Cryst. A64, 112 (2008)

    Google Scholar 

  16. Farrugia, L.J.: ORTEP-3 for windows—a version of ORTEP-III with a graphical user interface (GUI). J. Appl. Crystallogr. 30, 565 (1997)

    Article  CAS  Google Scholar 

  17. Suh, M.P., Shin, W., Kang, S.-G., Lah, M.S., Chung, T.-M.: Template condensation of formaldehyde with triamines. Synthesis and characterization of nickel(II) complexes with the novel hexaaza macrotricyclic ligands 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]octadecane and 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane. Inorg. Chem. 28, 1602 (1989)

    Article  CAS  Google Scholar 

  18. Suh, M.P., Kang, S.-G., Goedken, V.L., Park, S.-H.: Template condensation reactions of formaldehyde with tetraamines and ethylenediamine: preparation, properties, and structures of nickel(II) and copper(II) complexes of hexaaza macrotricyclic ligands 1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11]octadecane and 1,3,6,8,12,15-hexaazatricyclo[13.3.1.18,12]eicosane. Inorg. Chem. 30, 365 (1991)

    Article  CAS  Google Scholar 

  19. Kang, S.-G., Ryu, K., Suh, M.P., Jeong, J.H.: Template synthesis and crystal structure of a novel mononuclear nickel(II) complex with a face-to-face bis(macrocyclic) ligand. Inorg. Chem. 36, 2478 (1997)

    Article  CAS  Google Scholar 

  20. Deacon, B., Phillips, R.J.: Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coord. Chem. Rev. 33, 227 (1980)

    Article  CAS  Google Scholar 

  21. Bakalbassis, E.G., Mrozinski, J., Tsipis, C.A.: Experimental and quantum-chemical investigation of the magnetic exchange mechanism in a series of (μ-terephthalato)bis[(polyamine)copper(II)] complexes. Inorg. Chem. 25, 3684 (1986)

    Article  CAS  Google Scholar 

  22. Cao, R., Shi, Q., Sun, D., Hong, M., Bi, W., Zhao, Y.: Syntheses and characterizations of copper(II) polymeric complexes constructed from 1,2,4,5-benzenetetracarboxylic acid. Inorg. Chem. 41, 6161 (2002)

    Article  CAS  Google Scholar 

  23. Mochizuki, K., Kondo, T.: Isolation and vis-absorption spectrum of trans-[Ni(OH2)2(cyclam)]Cl2·4H2O. Inorg. Chem. 34, 6241 (1995)

    Article  CAS  Google Scholar 

  24. Martin, L.Y., Sperati, C.R., Busch, D.H.: The spectrochemical properties of tetragonal complexes of high spin nickel(II) containing macrocyclic ligands. J. Am. Chem. Soc. 99, 2968 (1977)

    Article  CAS  Google Scholar 

  25. Fisher, M.E.: Magnetism in one-dimensional systems—the Heisenberg model for infinite spin. Am. J. Phys. 32, 343 (1964)

    Article  Google Scholar 

  26. Oshio, H., Okamoto, H., Kikuchi, T., Ito, T.: The ferromagnetic chain system catena-(μ-CrO4-O,O’)[NiII(cyclam)]·2H2O. Inorg. Chem. 36, 3201 (1997)

    Article  CAS  Google Scholar 

  27. Kahn, O.: Molecular Magnetism, Chap. 2, pp. 9–29. VCH Publisher, Weinheim (1993)

  28. Choi, K.-Y., Ryu, H., Lim, Y.-M., Sung, N.-D., Shin, U.-S., Suh, M.: Self-assembly of one-dimensional coordination polymer from nickel(II) macrocyclic complex and 2,6-pyridinedicarboxylate ligand. Inorg. Chem. Commun. 6, 412 (2003)

    Article  CAS  Google Scholar 

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  1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi, In-Tack Lim & Chul-Kang Kim

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  1. Ki-Young Choi
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  2. In-Tack Lim
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Correspondence to Ki-Young Choi.

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Choi, KY., Lim, IT. & Kim, CK. Synthesis and structural characterization of nickel(II) hexaazamacrotetracyclic complexes with phthalate ligands. J Incl Phenom Macrocycl Chem 76, 263–268 (2013). https://doi.org/10.1007/s10847-012-0195-8

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