Skip to main content
SpringerLink
Log in

Vapour pressure of guest and thermodynamic stability of inclusion compounds [Ni(DBM)2Py2]*2G (DBM = dibenzoylmethanate anion, G = pyridine, tetrahydrofurane and chloroform)

  • Original Article
  • Published:
Journal of Inclusion Phenomena and Macrocyclic Chemistry Aims and scope Submit manuscript

Abstract

Temperature dependences of the equilibrium vapour pressure of the guest molecules (G) over inclusion compounds [Ni(DBM)2Py2]*2G (DBM = C6H5COCHCOC6H5 −—dibenzoylmethanate anion; Py = pyridine; G = pyridine, tetrahydrofurane and chloroform) were investigated by means of the static membrane procedure. It was established using TGA and DTA methods that both of two guest molecules get detached at the first step of decomposition 1/2[Ni(DBM)2Py2]*2Gs = 1/2[Ni(DBM)2Py2]s + Ggas. The changes of thermodynamic parameters \( (\Updelta {\text{H}}^{0}_{\text{av}} , \Updelta {\text{G}}^{0}_{ 2 9 8} \;{\text{and}}\;\Updelta {\text{S}}^{0}_{\text{av}} ) \) in this process were determined on the basis of the experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1

Similar content being viewed by others

References

  1. Soldatov, D.V., Enright, G.D., Ripmeester, J.A.: Modified metal dibenzoylmethanates and their clathrates. Part I. Clathration ability of dipyridinebis(dibenzoylmethanato)nickel (II), a novel metal-complex host. Supramol. Chem. 11, 35–47 (1999)

    Article  CAS  Google Scholar 

  2. Soldatov, D.V., Ukraintseva, E.A., Logvinenko, V.A.: Structure and stability of the dipyridinebis(dibenzoylmethanato)nickel(II) clathrate with acetone. J. Struct. Chem. 48 (2007) (translated from Russian Zh. Struct. Khim. 48, 995–1005, 2007)

    Google Scholar 

  3. Ukraintseva, E.A., Dyadin, Y.A., Kislykh, N.V., Logvinenko, V.A., Soldatov, D.V.: Vapour pressure of 4-methylpyridine (MePy) over [Ni(MePy)4(NCS)2]*yMePy and [Cu(MePy)4(NCS)2]*2/3(MePy) clathrates during their dissociation. J. Incl. Phenom. 23, 23–33 (1995)

    Article  CAS  Google Scholar 

  4. Soldatov, D.V., Ukraintseva, E.A., Logvinenko, V.A., Dyadin, Y.A., Grachev, E.V., Manakov, A.Y.: Thermodynamic dissociation constants for [MPy4(NO3)2]*2Py clathrates (M = Mn, Co, Ni, Cu). Supramol. Chem. 12, 237–246 (2000)

    Article  CAS  Google Scholar 

  5. Ogienko, A.G., Ukraintseva, E.A., Chingina, T.A., Komarov, V.Y., Manakov, A.Y.: The formation and stability of the [FePy3Cl3)]*py clathrate in the pyridine—iron(III) chloride system: phase diagram and solid—gas equilibria study. J. Incl. Phenom. Mol. Rec. Chem. 53, 231–236 (2005)

    Article  CAS  Google Scholar 

  6. Komarov, V.Y., Ukraintseva, E.A., Soldatov, D.V., Enright, G.D., Galkin, P.S., Luboradzki, R., Lipkowski, J.: Crystal structure and thermodynamic stability of the [Hg(Pyridine)4(NO3)2]*2(Pyridine) inclusion compound. J. Incl. Phenom. Mol. Rec. Chem. 50, 227–233 (2004)

    Article  CAS  Google Scholar 

  7. Paulik, F., Paulik, J.: Investigation under quasi-isothermal and quasi-isobaric condition by means of the derivatograph. J. Therm. Anal. 5, 253–270 (1973)

    Article  CAS  Google Scholar 

  8. Logvinenko, V.A., Paulic, I., Paulic, F.: Quasi-equilibrium thermogravimetry in the up-to-date inorganic chemistry. Novosibirsk, Nauka, 1989 (in Russian)

  9. Ukraintseva, E.A., Logvinenko, V.A., Soldatov, D.V., Chingina, T.A.: Thermal dissociation processes for clathrates [CuPy4(NO3)2]*2G(G = tetrahydrofurane, chloroform). J. Therm. Anal. Calorim. 75, 337–345 (2004)

    Article  CAS  Google Scholar 

  10. Ukraintseva, E.A., Soldatov, D.V., Dyadin, Y.A.: Thermodynamic stability of the [M(Pyridine)4X2]*2G clathrates as a function of the host components (M, X) and included guest (G). J. Incl. Phenom. 48, 19–23 (2004)

    Article  CAS  Google Scholar 

  11. Ukraintseva, E.A., Soldatov, D.V., Dyadin, Y.A.: Vapour pressure of pyridine and thermodynamic characteristics of clathrate- and complex formation in the pyridine–zinc nitrate system. J. Inorg. Chem. 42, 229–232(1997) (translated from Russian Zh. Neorg. Khim. 42, 283–286, 1997)

    Google Scholar 

  12. Gordon, A., Ford, R.: The Chemist’s companion. Wiley and Sons, New York (1972)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, 3, Lavrentyeva Avenue, Novosibirsk, 630090, Russia

    E. A. Ukraintseva

  2. Department of Chemistry, University of Guelph, 50 Stone Road, Guelph, Canada

    D. V. Soldatov

Authors
  1. E. A. Ukraintseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. V. Soldatov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Ukraintseva.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ukraintseva, E.A., Soldatov, D.V. Vapour pressure of guest and thermodynamic stability of inclusion compounds [Ni(DBM)2Py2]*2G (DBM = dibenzoylmethanate anion, G = pyridine, tetrahydrofurane and chloroform). J Incl Phenom Macrocycl Chem 66, 219–222 (2010). https://doi.org/10.1007/s10847-009-9599-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10847-009-9599-5

Keywords

Search

Navigation