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Experimental and theoretical spectral properties of ethyl 2-(7-hydroxy-2-oxo-2H-chromen-4-yl)acetate doped sol-gel materials: new materials with potential optical application

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Abstract

Silica xerogels and monoliths, containing ethyl 2-(7-hydroxy-2-oxo-2H-chromen-4-yl)acetate (K4) or Sm3 +  ions and K4 are prepared by sol-gel technique. NMR investigations, UV/Vis, IR- and luminescence spectral properties of K4 in solution and in monoliths are presented. The IR-spectroscopic properties of the prepared sol-gel materials are examined by applying the reduced-difference procedure to non-polarized IR-spectra. The results show that the sol-gel medium did not interact with K4 as well as in the presence of Sm3+ ions the K4 form a [Sm(L)2(H2O)4] × (NO3)3 complex in the matrix.

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Acknowledgments

G.A. and I.P. thank the Ministry of Education for the Project “Leading University Research Centre for Nanoscience and Knowledge based Materials”. S.G. was supported by a Project BYX 08/05. B.K. thanks Alexander von Humboldt Foundation for supporting scientific research.

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Authors and Affiliations

  1. Department of Organic Chemistry, Organic Photochemistry Group, University of Sofia “St Kliment Ohridski”, 1, James Bauchier Boulevard, 1164, Sofia, Bulgaria

    G. Ahmed & I. Petkov

  2. Department of Analytical Chemistry, University of Sofia “St Kliment Ohridski”, 1, James Bauchier Boulevard, 1164, Sofia, Bulgaria

    B. Koleva

  3. Department of Physical Chemistry, University of Sofia “St Kliment Ohridski”, 1, James Bauchier Boulevard, 1164, Sofia, Bulgaria

    S. Gutzov

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  1. G. Ahmed
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  2. B. Koleva
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Correspondence to G. Ahmed.

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Ahmed, G., Koleva, B., Gutzov, S. et al. Experimental and theoretical spectral properties of ethyl 2-(7-hydroxy-2-oxo-2H-chromen-4-yl)acetate doped sol-gel materials: new materials with potential optical application. J Incl Phenom Macrocycl Chem 59, 167–176 (2007). https://doi.org/10.1007/s10847-007-9309-0

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