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Electroanalytical Method of Acid Blue 120 and its Supramolecular System with Cyclodextrins

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Abstract

In this paper, a simple, rapid, sensitive and accurate electroanalytical method of Acid Blue 120 (AB120) has been established by polarography. In a supporting electrolyte of 0.01 mol l−1 Na2HPO4–KH2PO4 (pH 7.04) solution, a sensitive first derivative reduction peak (ip′) of AB120 was found by Linear Sweep Voltammetry (LSV). The peak potential is −820 mV (versus SCE). The peak current (ip′) is proportional to the concentration over the range 2.0 × 10−7–5.0 × 10−5 mol l−1 (r=0.9961–0.9991) and the limit of detection (LOD) is 1.0 × 10−7 mol l−1. The recovery of AB120 varied from 95.3 to 103.0% and the relative standard deviation (RSD) was 2.2% (n=8). The method has been expected to determination of wastewater in dye industry. In addition, the supramolecular system of AB120 with cyclodextrins has been studied. It can form 1:1 inclusion complex with six CDs. The inclusion constants were calculated and the inclusion ability of different kinds of CDs was compared. Furthermore, the inclusion mechanism was also preliminarily discussed, which provided some valuable information for further application of AB120 and CDs.

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References

  1. Isik M., Sponza D.T.: J. Hazard. Mater. B 114, 29 (2004)

    Article  CAS  Google Scholar 

  2. Robens J.F., Diu G.S., Ward J.M., Joiner J.R., Griesemer R.A., Douglas J.F.: Toxicol. Appl. Pharmacol. 54, 431, (1980)

    Article  PubMed  CAS  Google Scholar 

  3. Chung K.T., Stevens S.E.: Environ. Toxicol. Chem. 12, 2121 (1993)

    CAS  Google Scholar 

  4. Fuh M.R., Chia K.J.: Talanta 56, 663 (2002)

    Article  CAS  Google Scholar 

  5. Diaz C.B., Romero E.G.: J. Chromatogr. A 989, 221 (2003)

    Article  PubMed  CAS  Google Scholar 

  6. Makiko Y., Akihiro K., Mikio N.: Food Adit. Contam. 17, 665 (2000)

    Article  Google Scholar 

  7. Jayasundera B.: J. Chem. Res. Synop. 5, 234 (1998)

    Google Scholar 

  8. Urquiza M.P., Beltran J.L.: J. Chromatogr. A 917, 331 (2001)

    Article  PubMed  Google Scholar 

  9. Kuo K.L., Huang H.Y., Hsieh Y.Z.: Chromatographia 47, 249 (1998)

    Article  CAS  Google Scholar 

  10. Urquiza M.P., Faerrer R., Beltran J.L.: J. Chromatogr. A 883, 277 (2000)

    Article  PubMed  Google Scholar 

  11. Young M.L., Off J.A.: Anal. Chem. 45, 458 (1988)

    Google Scholar 

  12. Long J.J.: Tex. Aux. 20, 31 (2003)

    Google Scholar 

  13. Long J.J., Wang H.Z.: Dyeing Finishing 28, 4 (2002)

    Google Scholar 

  14. Liu Y., Li L., Zhang H.Y., Liang P.: Carbohydr. Res. 338, 1751 (2003)

    Article  PubMed  CAS  Google Scholar 

  15. Buschmann H.J., Schollmeyer E.: J. Incl. Phenom. Mol. Recognit. Chem. 29, 167 (1997)

    Article  CAS  Google Scholar 

  16. Iijima T., Karube Y.: Dyes Pigm. 36, 305 (1998)

    Article  CAS  Google Scholar 

  17. Isaacs N.S., Young D.J.: Tetrahedron Lett. 40, 3953 (1999)

    Article  CAS  Google Scholar 

  18. Dong S.J., Zhang D.B.: Acta Chimi. Sini. 46, 335 (1988)

    CAS  Google Scholar 

  19. W.B. Qi, Z.H. Qi: New Analytical Synergistic Agent, Hangzhou University Press, Hangzhou, China, 152 (1994)

Download references

Acknowledgement

This work was supported by the Natural Science Foundation of Shanxi province of China.

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Authors and Affiliations

  1. Department of Chemistry, Shanxi University, 030006, Taiyuan, P.R. China

    Yu-Jing Guo, Jing-Hao Pan, Xiao-Mei Li, Fei Lu & You-Qin Li

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  1. Yu-Jing Guo
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  2. Jing-Hao Pan
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  3. Xiao-Mei Li
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  4. Fei Lu
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  5. You-Qin Li
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Correspondence to Yu-Jing Guo.

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Guo, YJ., Pan, JH., Li, XM. et al. Electroanalytical Method of Acid Blue 120 and its Supramolecular System with Cyclodextrins. J Incl Phenom Macrocycl Chem 56, 243–246 (2006). https://doi.org/10.1007/s10847-006-9090-5

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  • DOI: https://doi.org/10.1007/s10847-006-9090-5

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