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Induced Circular Dichroism Spectra of β- and γ-Cyclodextrin Complexes with Indazolinone and Related Compounds

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Abstract

The magnetic circular dichroism (MCD) spectra of indazolinone, isatine, and 3-iminoisoindolinone and the induced circular dichroism (ICD) spectra of the inclusion complexes with β- or γ-cyclodextrins (CDs) have been measured. The spectra are interpreted by results of the ZINDO calculations. In the presence of cyclodextrin, the OH indazolinone tautomer is main structure that is consistent with that in the DMSO solution. The structures of the inclusion complexes are very different because of the scale of the cavity of cyclodextrin or position of quinone in molecules.

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References

  1. P. Ballesteros J. Elguero R.M. Claramunt R. Faure M.C.F. Foces F.H. Cano A. Rousseau (1986) J Chem Soc Perkin Trans 2 1677

    Google Scholar 

  2. K. Harata H. Uedaira (1975) Bull Chem Soc Jpn 48 375

    Google Scholar 

  3. P.E. Schipper A. Rodger (1983) J Am Chem Soc 105 4541

    Google Scholar 

  4. Kodaka M. (1991) J Phys Chem 95:2110; Kodaka M. (1993) J Am Chem Soc 115:3702

    Google Scholar 

  5. Yamaguchi H., Abe S. (1981) J Phys Chem 85:1640; Higashi M., Yamaguchi H., Machiguchi T., Hasegawa T., Baumann H. (1992) Helv Chim Acta 75:1880

    Google Scholar 

  6. N. Kobayashi T. Osa (1991) Bull Chem Soc Jpn 64 1878

    Google Scholar 

  7. A.R. Meier G.H. Wagnière (1987) Chem Phys 113 287

    Google Scholar 

  8. J. Frei H. Yamaguchi J. Tsunetsugu G. Wagnière (1990) J Am Chem Soc 112 1413

    Google Scholar 

  9. S. Ishijima M. Higashi H. Yamaguchi (1994) J Phys Chem 98 10432

    Google Scholar 

  10. N. Kobayashi R. Saito H. Hino Y. Hino A. Ueno T. Osa (1983) J Chem Soc, Perkin Trans 2 1031

    Google Scholar 

  11. H. Yamaguchi M. Higashi (1987) J Inclusion Phenom Mol Recognit Chem 5 725

    Google Scholar 

  12. N. Yoshida H. Yamaguchi T. Iwao M. Higashi (1999) J Chem Soc, Perkin Trans 2 379

    Google Scholar 

  13. N.A. Frolova V.Kh. Kravtsov V.N. Biyushkin Yu.M. Chumakov O.N. Bel’kova T.I. Malinovskii (1988) Zh Strukt Khim 29 155

    Google Scholar 

  14. (a) MOPAC Ver. 6, J. J. P. Stewart, QCPE Bull. 9, 10 (1989); (b) Revised as Ver. 6.01 by T. Hirano, T. University of Tokyo, for HITAC machine, JCPE Newsletter 2, 26 (1991).

  15. (a) ZINDO: CaChe WorkSystem Version 3.8; (b) W.P. Anderson, W. D. Edwards, and M.C. Zerner, Inorg. Chem. 25, 2728 (1986).

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Authors and Affiliations

  1. Materials Science, The Graduate School of Science and Engineering, Ibaraki University, 4-12-1 Nakanarusawa, Hitachi, 316-8511, Japan

    Masahiro Kawamura & Miwako Higashi

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  1. Masahiro Kawamura
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  2. Miwako Higashi
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Correspondence to Miwako Higashi.

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Kawamura, M., Higashi, M. Induced Circular Dichroism Spectra of β- and γ-Cyclodextrin Complexes with Indazolinone and Related Compounds. J Incl Phenom Macrocycl Chem 51, 11–15 (2005). https://doi.org/10.1007/s10847-004-5390-9

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  • DOI: https://doi.org/10.1007/s10847-004-5390-9

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