Skip to main content
Log in

Magnetoelectric laminated composites of lead-free BSZT and magnetostrictive materials

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

A magnetostrictive-piezoelectric laminated composite has been developed by sandwiching a lead-free Sr modified BZT piezoelectric ceramic plate between two magnetostrictive materials plates polarized in the thickness direction. Two different magnetostrictive materials, Terfenol-D continuous fiber composite (TD-FC) and cobalt ferrite (CFO), were used to fabricate the ME composite laminates. The quasistatic magnetostrictive properties of the magnetostrictive samples were measured and the quasistatic (differential) strain coefficient (\( d_{33}^{QS } \)) can be found. Lead-free magnetoelectric (ME) laminated composite has a good ME voltage sensitivity (ME v ) under a low magnetic bias field (H Bias ). The BSZT/TDFC laminate has ME v  = 0.888 V/Oe at the resonance frequency of 119 kHz under a H Bias of 0.6 kOe. The BSZT/CFO laminate has ME v  = 0.155 V/Oe at the resonance frequency of 204 kHz under a H Bias of 0.4 kOe. A prototype magnetic field sensor was fabricated and characterized under different frequency and different field strength. This work shows the potential of BSZT lead-free ceramics in magnetic field sensing application.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. J. Wang, J.B. Neaton, H. Zheng, V. Nagarajan, S.B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D.G. Schlom, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, M. Wuttig, R. Ramesh, Science 299, 1719 (2003)

    Article  CAS  Google Scholar 

  2. F. Manfred, J. Phys. D Appl. Phys. 38, R123 (2005)

    Article  Google Scholar 

  3. T. Lottermoser, T. Lonkai, U. Amann, D. Hohlwein, J. Ihringer, M. Fiebig, Nature 430, 541 (2004)

    Article  CAS  Google Scholar 

  4. K. Ebnabbasi, C. Vittoria, A. Widom, Phys Rev. B 86, 024430 (2012)

    Article  Google Scholar 

  5. K. Ebnabbasi, M. Mohebbi, C. Vittoria, J. Appl. Phys. 113, 17C707 (2013)

    Article  Google Scholar 

  6. E. Hristoforou, A. Ktena, J. Magn. Magn. Mater. 316, 372 (2007)

    Article  CAS  Google Scholar 

  7. S. Priya, R. Islam, S. Dong, D. Viehland, J. Electroceram. 19, 149 (2007)

    Article  Google Scholar 

  8. E. Quandt, S. Stein, and M. Wuttig, Magnetic vector field sensor using magnetoelectric thin film composites, presented at Magnetics Conference, 2005. INTERMAG Asia 2005. Digests of the IEEE International, (2005)

  9. T. Ueno, T. Higuchi, IEEE Trans. Magn. 41, 3670 (2005)

    Article  Google Scholar 

  10. G. Srinivasan, E.T. Rasmussen, J. Gallegos, R. Srinivasan, Y.I. Bokhan, V.M. Laletin, Phys. Rev. B 64, 214408 (2001)

    Article  Google Scholar 

  11. G. Srinivasan, E.T. Rasmussen, B.J. Levin, R. Hayes, Phys Rev B 65, 134402 (2002)

    Article  Google Scholar 

  12. A.L. Geiler, S.M. Gillette, Y. Chen, J. Wang, Z. Chen, S.D. Yoon, P. He, J. Gao, C. Vittoria, V.G. Harris, Appl. Phys. Lett. 96, 053508 (2010)

    Google Scholar 

  13. S.H. Choy, X.X. Wang, H.L.W. Chan, C.L. Choy, Appl. Phys. A: Mater. Sci. Process. 82, 715 (2006)

    Article  CAS  Google Scholar 

  14. S.H. Choy, X.X. Wang, C.P. Chong, H.L.W. Chan, P.C.K. Liu, C.L. Choy, Appl. Phys. A: Mater. Sci. Process. 84, 313 (2006)

    Article  CAS  Google Scholar 

  15. S.H. Choy, X.X. Wang, H.L.W. Chan, C.L. Choy, Appl. Phys. A: Mater. Sci. Process. 89, 775 (2007)

    Article  CAS  Google Scholar 

  16. G.C. Edwards, S.H. Choy, H.L.W. Chan, D.A. Scott, A. Batten, Appl. Phys. A: Mater. Sci. Process. 88, 209 (2007)

    Article  CAS  Google Scholar 

  17. W.C. Xu, K.H. Lam, S.H. Choy, H.L.W. Chan, Integr. Ferroelectr. 89, 87 (2007)

    Article  CAS  Google Scholar 

  18. H.L.W. Chan, S.H. Choy, C.P. Chong, H.K. Li, P.C.K. Liu, Ceram. Int. 34, 773 (2008)

    Article  CAS  Google Scholar 

  19. S.T. Lau, C.H. Cheng, S.H. Choy, D.M. Lin, H.L.W. Chan, J. Appl. Phys. 103, 104105 (2008)

    Article  Google Scholar 

  20. X.S. Xu, T.V. Brinzari, S. Lee, Y.H. Chu, L.W. Martin, A. Kumar, S. McGill, R.C. Rai, R. Ramesh, V. Gopalan, S.W. Cheong, J.L. Musfeldt, Phys. Rev. B 79, 134425 (2009)

    Article  Google Scholar 

  21. J. Zhai, Z. Xing, S. Dong, J. Li, D. Viehland, J. Am. Ceram. Soc. 91, 351 (2008)

    Article  CAS  Google Scholar 

  22. J.Y. Zhai, Magnetoelectric laminated composites and devices, in Materials Science and Engineering, vol. Doctor of Philosopy (Virginina Polytechnic Institute and State University, Blacksburg, Virginia, 2009)

    Google Scholar 

Download references

Acknowledgments

This project was supported by PolyU internal Grant (Project No. PolyU 1-ZV9B). The Centre for Smart Material of The Hong Kong Polytechnic University is acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. H. Choy.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Choy, S.H., Chan, N.Y., Lo, C.Y. et al. Magnetoelectric laminated composites of lead-free BSZT and magnetostrictive materials. J Electroceram 31, 102–108 (2013). https://doi.org/10.1007/s10832-013-9823-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-013-9823-y

Keywords

Navigation