Skip to main content
Log in

ZnO-based varistor thick films with high non-linear electrical behavior

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

Thick films of ZnO-based ceramic varistors prepared by tape casting technique typically show a poor electrical response that still limits their application as protective devices. The excessive volatilization of Bi2O3 during sintering at high temperatures, especially dramatic in the film geometry due to its high area–volume ratio, is found to be the origin of this poor electrical behavior. The problem is overcome by sintering the films in a controlled Bi-rich sealed atmosphere, leading to a high reliability and reproducibility in their non-linear response.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. D.R. Clarke, J. Am. Ceram. Soc 82, 485 (1999)

    CAS  Google Scholar 

  2. T.K. Gupta, J. Am. Ceram. Soc 73, 1817 (1990) doi:10.1111/j.1151-2916.1990.tb05232.x

    Article  CAS  Google Scholar 

  3. C.M. Barrado, E.R. Leite, P.R. Bueno, E. Longo, J.A. Varela, Mater. Sci. Eng. A 371, 377 (2004) doi:10.1016/j.msea.2003.09.069

    Article  Google Scholar 

  4. Y.W. Lao, S.T. Kuo, W.H. Tuan, J. Electroceram 19, 187 (2007) doi:10.1007/s10832-007-9187-2

    Article  CAS  Google Scholar 

  5. M.A. Ramírez, A.Z. Simoes, M.A. Márquez, Y. Maniette, A.A. Cavalheiro, J.A. Varela, Mater. Res. Bull 42, 1159 (2007) doi:10.1016/j.materresbull.2006.09.001

    Article  Google Scholar 

  6. R. Lou-Moeller, C.C. Hindrichsen, L.H. Thamdrup, T. Bove, E. Ringgaard, A.F. Pedersen et al., J. Electroceram 19, 333 (2007) doi:10.1007/s10832-007-9055-0

    Article  CAS  Google Scholar 

  7. F. Menil, H. Debeda, C. Lucas, J. Eur. Ceram. Soc 25, 2105 (2005) doi:10.1016/j.jeurceramsoc.2005.03.017

    Article  CAS  Google Scholar 

  8. D. Belavic, M. Hrovat, J. Holc, M.S. Zarnik, M. Kosec, M. Pavlin, J. Electroceram 19, 363 (2007) doi:10.1007/s10832-007-9064-z

    Article  CAS  Google Scholar 

  9. M.A. De la Rubia, M. Peiteado, J. De Frutos, F. Rubio-Marcos, J.F. Fernández, A.C. Caballero, J. Eur. Ceram. Soc 27, 3887 (2007) doi:10.1016/j.jeurceramsoc.2007.02.057

    Article  Google Scholar 

  10. R. Metz, H. Delalu, J.R. Vignalou, N. Achard, M. Elkhatib, Mater. Chem. Phys 63, 157 (2000) doi:10.1016/S0254-0584(99)00227-8

    Article  CAS  Google Scholar 

  11. M. Peiteado, M.A. De la Rubia, M.J. Velasco, F.J. Valle, A.C. Caballero, J. Eur. Ceram. Soc 25, 1675 (2005) doi:10.1016/j.jeurceramsoc.2004.06.006

    Article  CAS  Google Scholar 

  12. F. Greuter, Solid State Ion 75, 67 (1995) doi:10.1016/0167-2738(94)00181-Q

    Article  CAS  Google Scholar 

  13. C. Leach, Acta Mater 53, 237 (2005) doi:10.1016/j.actamat.2004.07.006

    Article  CAS  Google Scholar 

  14. Y. Sato, T. Yamamoto, Y. Ikuhara, J. Am. Ceram. Soc 90, 337 (2007) doi:10.1111/j.1551-2916.2006.01481.x

    Article  CAS  Google Scholar 

  15. E. Olsson, G.L. Dunlop, R. Österlund, J. Am. Ceram. Soc 76, 65 (1993) doi:10.1111/j.1151-2916.1993.tb03690.x

    Article  CAS  Google Scholar 

  16. A.C. Caballero, D. Hevia, J. De Frutos, M. Peiteado, J.F. Fernández, J. Electroceram 13, 759 (2004) doi:10.1007/s10832-004-5188-6

    Article  CAS  Google Scholar 

  17. D. Fernández-Hevia, M. Peiteado, J. De Frutos, A.C. Caballero, J.F. Fernández, J. Eur. Ceram. Soc 24, 1205 (2004) doi:10.1016/S0955-2219(03)00411-4

    Article  Google Scholar 

  18. M.A. De la Rubia, M. Peiteado, J.F. Fernández, A.C. Caballero, J. Eur. Ceram. Soc 24, 1209 (2004) doi:10.1016/S0955-2219(03)00410-2

    Article  Google Scholar 

  19. M.A. De la Rubia, M. Peiteado, J.F. Fernández, A.C. Caballero, J. Holc, S. Drnovsek et al., J. Eur. Ceram. Soc 26, 2985 (2006) doi:10.1016/j.jeurceramsoc.2006.02.016

    Article  Google Scholar 

  20. J.F. Fernández, E. Nieto, C. Moure, P. Durán, R.E. Newnham, J. Mater. Sci 30, 5399 (1995) doi:10.1007/BF00351550

    Article  ADS  Google Scholar 

  21. M. Peiteado, J.F. Fernández, A.C. Caballero, J. Eur. Ceram. Soc 27, 3867 (2007) doi:10.1016/j.jeurceramsoc.2007.02.046

    Article  CAS  Google Scholar 

  22. L. Hozer, Semiconductor Ceramics: Grain Boundary Effects (Polish Scientific Publisher, Warszawa, 1973), p. 44

    Google Scholar 

  23. G.C. Miles, A.R. West, J. Am. Ceram. Soc 89, 1042 (2006) doi:10.1111/j.1551-2916.2005.00799.x

    Article  CAS  Google Scholar 

  24. M. Peiteado, M.A. De la Rubia, J.F. Fernández, A.C. Caballero, J. Mater. Sci 41, 2319 (2006) doi:10.1007/s10853-006-7168-5

    Article  ADS  CAS  Google Scholar 

Download references

Acknowledgements

This work has been conducted within the CICYT MAT 2007-66845-C02-01 project.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Marco Peiteado.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Peiteado, M., De la Rubia, M.A., De Frutos, J. et al. ZnO-based varistor thick films with high non-linear electrical behavior. J Electroceram 23, 62–66 (2009). https://doi.org/10.1007/s10832-008-9535-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-008-9535-x

Keywords

Navigation