Skip to main content
SpringerLink
Log in

Photovoltaic Properties of Polymer Composites Doped with Binuclear Lanthanide Complexes Derived from 3,6-Dipyridin-2-YL-1,2,4,5-Tetrazine With Carbacylamidophosphate Ligands

  • Published:
Journal of Applied Spectroscopy Aims and scope

A study was carried out on the photovoltaic and photoconductive properties of fi lm composites of a styrene copolymer with nonyl methacrylate and polyNepoxypropylcarbazole doped with lanthanide complexes Ln2L6·PS (Ln = Nd, Eu, Gd, Yb), HL is the carbacylamidophosphate ligand, CCl3C(O)N(H)P(O)(NEt2)2, N-[bis(diethylamino) phosphoryl]2,2,2-trichloroacetamide; PS is 3,6-dipyridin-2-yl-1,2,4,5-tetrazine, C5H4N–C2N4–C5H4N). In the visible spectral range, these composites were found to have holetype photoconductivity. The internal photoelectric effect is a function of the photogeneration of charge carriers from the metal complex molecules and the sensitizer. EPR was used to study the kinetics of the formation and relaxation of the photogenerated charge carriers. We conclude that the metal complex molecules in the polymer composite enhance the efficiency of photogeneration of nonequilibrium charge carriers and thereby affect the photovoltaic properties of the composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Mertens, Photovoltaics, Fundamentals, Technology and Practice, Wiley (2014).

  2. O. Malinkiewicz, T. Grancha, A. A. MolinaOntoria, A. Soriano, H. Brine, and H. J. Bolink, Adv. Energy Mater., 3, 472–477 (2013).

    Article  Google Scholar 

  3. F. A. Castro, H. Benmansour, J.E. Moser, C. F. O. Graeff, F. Nüensch, and R. Hany, Phys. Chem. Chem. Phys., 11, 8886–8894 (2009).

    Article  Google Scholar 

  4. A. W. Hains, Z. Liang, M. A. Woodhouse, and B. A. Gregg, Chem. Rev., 110, No. 11, 6689–6735 (2010).

    Article  Google Scholar 

  5. V. A. Milichko, A. S. Shalin, I. S. Mukhin, A. É. Kovrov, A. A. Krasilin, A. V. Vinogradov, P. A. Belov, and K. R. Simovskii, Usp. Fiz. Nauk, 186, No. 8, 801–852 (2016).

    Article  Google Scholar 

  6. E. A. Kiyazeva, and O. A. Rakitin, Usp. Khim., 85, No. 10, 1146–1183 (2016).

    Article  Google Scholar 

  7. V. V. Rakitin and G. F. Novikov, Usp. Khim., 86, No. 2, 99–112 (2017).

    Article  Google Scholar 

  8. E. A. Trush, V. A. Ovchynnikov, and K. V. Domasevitch, Z. Naturforsch., 57b, 746–750 (2002).

    Article  Google Scholar 

  9. E. A. Gubina, O. A. Maslov, E. A. Trush, V. A. Ovchynnikov, S. V. Shishkin, and V. M. Amirkhanov, Polyhedron, 28, 2661–2666 (2009).

    Article  Google Scholar 

  10. K. E. Gubina, V. A. Ovchynnikov, V. M. Amirkhanov, H. Fischer, R. Stumpf, and V. V. Skopenko, Z. Naturforsch, 55b, 576–582 (2000).

    Article  Google Scholar 

  11. V. Amirkhanov, V. Ovchynnikov, V. Trush, P. Gawryszewska, and L. B. Jerzykiewicz, in: P. Gawyyszewska and P. Smolenski (Eds.), Ligands Synthesis, Characterisation, and Role in Biotechnology, Nova Science Publishers, New York (2014), pp. 199–248.

    Google Scholar 

  12. S. M. Ryvkin, Photoelectric Effects in Semiconductors [in Russian], Fizmatgiz, Moscow (1963).

    Google Scholar 

  13. W. Brutting, Physics of Organic Semiconductors, WileyVCH Verlag, Weinheim (2012).

    Book  Google Scholar 

  14. M. Pope and C. E. Swenberg, Electronic Processes in Organic Crystals, Clarendon Press, Oxford (1982).

    Google Scholar 

  15. N. A. Davidenko and N. Kokozei, Teor. Éksperim. Khim., 53, No. 2 69–87 (2017).

    Google Scholar 

  16. N. G. Kuvshinskii, N. A. Davidenko, and V. M. Komko, Physics of Amorphous Molecular Semiconductors [in Russian], Lybid', Kiev (1994).

  17. N. A. Davidenko and A. A. Ishchenko, Teor. Éksperim. Khim., 38, No. 2, 84–102 (2002).

    Google Scholar 

  18. N. A. Davidenko, N. G. Kuvshinskii, Fiz. Tverd. Tela, 39, No. 6, 1020–1023 (1997).

    Google Scholar 

  19. N. A. Davidenko and A. A. Ishchenko, Chem. Phys., 247, 237–243 (1999).

    Article  Google Scholar 

  20. A. L. Buchachenko and V. L. Berdinsky, J. Phys. Chem., 100, No. 47, 18292–18299 (1996).

    Article  Google Scholar 

  21. Ya. B. Zel'dovich, A. L. Buchachenko, and E. L. Frankevich, Usp. Fiz. Nauk, 155, No. 1, 3–45 (1988).

    Article  Google Scholar 

  22. A. Kukhta, N. Davidenko, I. Davidenko, E. Mokrinskaya, N. Chuprina, and L. Tonkopieva, Int. J. Nanoscience (World Scientifi c Publishing Company), 18, Nos. 3–4, 1 940086 (2019).

Download references

Author information

Authors and Affiliations

  1. Taras Shevchenko National University of Kiev, Kiev, 01601, Ukraine

    V. M. Amirkhanov, D. G. Vishnevsky, V. N. Ovdenko, N. G. Chuprina, E. V. Mokrinskaya, V. A. Zozulya, Yu. O. Shatrava, V. A. Ovchinnikov, T. Yu. Sliva, I. I. Davidenko & N. A. Davidenko

  2. Institute of Sorption and Endoecology Problems of the National Academy of Sciences of Ukraine, Kiev, 03164, Ukraine

    A. K. Mel’nik

Authors
  1. V. M. Amirkhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. G. Vishnevsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Ovdenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. G. Chuprina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Mokrinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. A. Zozulya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu. O. Shatrava
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. A. Ovchinnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. T. Yu. Sliva
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. A. K. Mel’nik
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. I. I. Davidenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  12. N. A. Davidenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Davidenko.

Additional information

N. A. Davidenko is deceased

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 6, pp. 1010–1016, November–December, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Amirkhanov, V.M., Vishnevsky, D.G., Ovdenko, V.N. et al. Photovoltaic Properties of Polymer Composites Doped with Binuclear Lanthanide Complexes Derived from 3,6-Dipyridin-2-YL-1,2,4,5-Tetrazine With Carbacylamidophosphate Ligands. J Appl Spectrosc 87, 1135–1140 (2021). https://doi.org/10.1007/s10812-021-01121-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-021-01121-7

Keywords

Search

Navigation