The photoconductive and photovoltaic properties of fi lm composites based on poly-N-epoxypropylcarbazole doped with a metal complex (a derivative of nickel dithiolene) were studied. It was found that these composites possess hole-type photoconductivity and that the internal photoeffect is determined by photogeneration of charge carriers from the metal complex and by transport of holes through the donor fragments of the polymer matrix.
Similar content being viewed by others
References
T. Yoshizawa (Ed.), Handbook of Optical Metrology: Principles and Applications, 2nd edn., CRC Press (2017).
K. Leo (Ed.), Elementary Processes in Organic Photovoltaics, Springer (2016).
P. Kumar, Organic Solar Cells: Device Physics, Processing, Degradation, and Prevention, CRC Press (2016).
P. Deng, C. H. Y. Ho, Y. Lu, H.-W. Li, S.-W. Tsang, S. K. Soc, and B. S. Ong, Chem. Commun., 53, 3249–3252 (2017).
V. A. Milichko, A. S. Shalin, I. S. Mukhin, A. E. Kovrov, A. A. Krasilin, A. V. Vinogradov, P. A. Belov, and C. R. Simovskii, Usp. Fiz. Nauk, 186, 801–852 (2016) [V. A. Milichko, A. S. Shalin, I. S. Mukhin, A. E. Kovrov, A. A. Krasilin, A. V. Vinogradov, P. A. Belov, and C. R. Simovskii, Sov. Phys. Usp., 59, No. 8, 727–772 (2016)].
E. A. Knyazeva and O. A. Rakitin, Usp. Khim., 85, No. 10, 1146–1183 (2016) [E. A. Knyazeva and O. A. Rakitin, Russ. Chem. Rev., 85, No. 10, 1146–1183 (2016)].
V. V. Rakitin and G. F. Novikov, Usp. Khim., 86, No. 2, 99–112 (2017) [V. V. Rakitin and G. F. Novikov, Russ. Chem. Rev., 86, No. 2, 99–112 (2017)].
G. Ding, J. Yuan, F. Jin, Y. Zhang, L. Han, X. Ling, H. Zhao, and W. Ma, Nano Energy, 36, 356–365 (2017).
E. V. Mokrinskaya, S. L. Studzinsky, V. A. Pavlov, N. G. Chuprina, V. V. Kravchenko, A. I. Marinin, L. S. Tonkopieva, I. I. Davidenko, and N. A. Davidenko, Khim. Vys. Énergii, 51, No. 4, 278–283 (2017) [E. V. Mokrinskaya, S. L. Studzinsky, V. A. Pavlov, N. G. Chuprina, V. V. Kravchenko, A. I. Marinin, L. S. Tonkopieva, I. I. Davidenko, and N. A. Davidenko, High Energy Chem., 51, No. 4, 263–268 (2017)].
N. A. Davidenko, I. I. Davidenko, S. L. Studzinsky, L. I. Kostenko, A. A. Ishchenko, E. V. Mokrinskaya, and L. S. Tonkopieva, Khim. Vysok. Énergii, 49, No. 6, 463–468 (2015) [N. A. Davidenko, I. I. Davidenko, S. L. Studzinsky, L. I. Kostenko, A. A. Ishchenko, E. V. Mokrinskaya, and L. S. Tonkopieva, High Energy Chemistry, 49, No. 6, 420–425] (2015).
N. A. Davidenko, Yu. P. Getmanchuk, E. V. Mokrinskaya, L. R. Kunitskaya, I. I. Davidenko, V. A. Pavlov, S. L. Studzinsky, and N. G. Chuprina, Appl. Opt., 53, No. 10, B242–B247 (2014).
N. A. Davidenko, I. I. Davidenko, V. A. Pavlov, N. G. Chuprina, V. V. Kravchenko, N. N. Kuranda, E. V. Mokrinskaya, and S. L. Studzinsly, Appl. Opt., 57, No. 8, 1832–1837 (2018).
N. A. Davidenko and A. A. Ishchenko, Theor. Exper. Chem., 38, No. 2, 88–108 (2002).
E. B. Yagubskii, L. A. Kushch, V. V. Gritsenko, O. A. Dyachenko, L. I. Buravov, and A. G. Khomenko, Synth. Metals, 70, Nos. 1–3, 1039–1041 (1995).
A. V. Kukhta, E. E. Kolesnik, I. N. Kukhta, A. E. Pochtenny, V. K. Dolgiy, G. A. Mousdis, and N. Psaroudakis, Synth. Met., 160, 2361–2365 (2010).
L. Valade, J.-P. Legros, M. Bousseau, P. Cassoux, M. Garbauskas, and L. V. Interrante, J. Chem. Soc., Dalton Trans., 4, 783–794 (1985).
N. A. Davidenko, A. A. Ishchenko, and V. A. Pavlov, Zh. Nauch. Prikl. Fotogr., 41, No. 2, 52–56 (1999) [N. A. Davidenko, A. A. Ishchenko, and V. A. Pavlov, Sci. Appl. Photo., 41, No. 2, 169–174 (1999)].
N. A. Davidenko and A. A. Ishchenko, Phys. Solid State, 42, No. 8, 1403–1409 (2000).
M. Nonnenmacher, M. P. O’Boyle, and H. K. Wickramasinghe, Appl. Phys. Lett., 58, 2921–2923 (1991).
Gaussian 09, revision A. 1, Gaussian, Inc, Wallingford (2009)
Jing-Lin Zuo, Tian-Ming Yao, Fei You, Xiao-Zeng You, Hoong-Kun Fun, and Boon-Chuan Yip, J. Mater. Chem., 6, 1633–1637 (1996).
M. Pope and C. E. Swenberg, Electronic Processes in Organic Crystals, Clarendon Press, Oxford (1982).
N. A. Davidenko, N. A. Derevyanko, A. A. Ishchenko, N. G. Kuvshinsky, A. V. Kulinich, O. Ya. Neilands, and M. V. Plotniece, Izv. RAN, Ser. Khim., 53, No. 8, 1611–1617 (2004) [N. A. Davidenko, N. A. Derevyanko, A. A. Ishchenko, N. G. Kuvshinsky, A. V. Kulinich, O. Ya. Neilands, and M. V. Plotniece, Russ. Chem. Bull., Int. Ed., 53, No. 8, 1611–1617 (2004)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 86, No. 3, pp. 461–467, May–June, 2019.
Rights and permissions
About this article
Cite this article
Davidenko, N.A., Davidenko, I.I., Kukhta, A.V. et al. Photophysical Properties of Composite Based on Poly-N-Epoxypropylcarbazole and Nickel Dithiolene. J Appl Spectrosc 86, 493–498 (2019). https://doi.org/10.1007/s10812-019-00846-w
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-019-00846-w