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Heteroatom Role in the Formation of Spectral-Luminescent Properties of 21-Thia- and 21,23-Dithia-5,10,15,20-Tetraphenylporphyrin in Solutions

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Journal of Applied Spectroscopy Aims and scope

The spectral and luminescent properties of 21-thia- and 21,23-dithia-5,10,15,20-tetraphenylporphyrin were studied in solutions at 293 K. The origin of the spectral shifts of the absorption bands upon heterosubstitution was discussed based on the Gouterman four-orbital model. Fluorescence quenching of the heteroporphyrins was shown to be due to an internal heavy-atom effect of the thiophene-ring heteroatom.

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Authors and Affiliations

  1. Belarusian State Technological University, 220006, Minsk, Belarus

    I. V. Vershilovskaya, L. S. Liulkovich & M. M. Kruk

  2. RUE Belmedpreparaty, 220007, Minsk, Belarus

    L. S. Liulkovich

  3. Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    S. G. Pukhovskaya & A. O. Plotnikova

  4. G. A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    Yu. B. Ivanova

Authors
  1. I. V. Vershilovskaya
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  2. L. S. Liulkovich
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  3. S. G. Pukhovskaya
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  4. Yu. B. Ivanova
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  5. A. O. Plotnikova
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  6. M. M. Kruk
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Correspondence to M. M. Kruk.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 2, pp. 181–188, March–April, 2020.

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Vershilovskaya, I.V., Liulkovich, L.S., Pukhovskaya, S.G. et al. Heteroatom Role in the Formation of Spectral-Luminescent Properties of 21-Thia- and 21,23-Dithia-5,10,15,20-Tetraphenylporphyrin in Solutions. J Appl Spectrosc 87, 201–207 (2020). https://doi.org/10.1007/s10812-020-00984-6

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  • DOI: https://doi.org/10.1007/s10812-020-00984-6

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